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\(\left\{{}\begin{matrix}Zn\\Fe\\Mg\end{matrix}\right.+H_2SO_4\rightarrow\left\{{}\begin{matrix}ZnSO_4\\FeSO_4\\MgSO_4\end{matrix}\right.+H_2\uparrow\)
Ta có: \(m_{SO_4}=8,25-2,49=5,76\left(g\right)\)
\(\Rightarrow n_{H_2SO_4}=n_{H_2}=n_{SO_4}=\dfrac{5,76}{96}=0,06\left(mol\right)\)
a, \(m_{H_2SO_4}=0,06.98=5,88\left(g\right)\)
b, \(V_{H_2}=0,06.22,4=1,344\)
\(n_{H_2SO_4}=n_{H_2}=a(mol)\\ BTKL:\\ m_{hh}+m_{H_2SO_4}=m_Y+m_{H_2}\\ 2,49+98.a= 8,25+2.a\\ \to a=0,06(mol)\\ a/ m_{H_2SO_4}=0,06.98=5,88(g)\\ b/ V_{H_2}=0,06.22,4=1,334(l)\)
a) Ta có : \(m_{KL}+m_{SO^{2-}_4}=m_{muối}\)
=> \(m_{SO_4^{2-}}=8,25-2,49=5,76\left(g\right)\)
=> \(n_{SO_4^{2-}}=\dfrac{5,76}{96}=0,06\left(mol\right)\)
Mặc khác : \(2H^++SO_4^{2-}\rightarrow H_2SO_4\)
=>\(n_{SO_4^{2-}}=n_{H_2SO_4}=0,06\left(mol\right)\)
=> \(m_{H_2SO_4}=0,06.98=5,88\left(g\right)\)
b) Bảo toàn nguyên tố H : \(n_{H_2}=n_{H_2SO_4}=0,06\left(mol\right)\)
=> VH2 = 0,06.22,4 = 1,344(lít )
\(n_{H_2}=0,6\left(mol\right)\\ Đặt:a=n_{Mg}\left(mol\right);b=n_{Zn}\left(mol\right)\left(a,b>0\right)\\ PTHH:Mg+H_2SO_4\rightarrow MgSO_4+H_2\\ Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\ \Rightarrow\left\{{}\begin{matrix}24a+65b=18,5\\a+b=0,6\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,5\\b=0,1\end{matrix}\right.\\ a,\Rightarrow m_{Mg}=0,5.24=12\left(g\right);m_{Zn}=0,1.65=6,5\left(g\right)\\ b,\%,m_{Mg}=\dfrac{12}{18,5}.100\approx64,865\%\Rightarrow\%m_{Zn}\approx35,135\%\\ c,n_{H_2SO_4}=n_{H_2}=0,6\left(mol\right)\\ \Rightarrow C_{MddH_2SO_4}=\dfrac{0,6}{0,245}=\dfrac{120}{49}\left(M\right)\\ d,m_{MgSO_4}=120a=120.0,5=60\left(g\right)\\ m_{ZnSO_4}=161b=161.0,1=16,1\left(g\right)\)
e) Câu e cho thêm cái D nữa nha em!
\(n_{Zn} = a(mol) ; n_{Al} = b(mol) ; n_{Mg} = c(mol)\\ \Rightarrow 65a + 27b + 24c = 44,1(1)\\ Zn + 2HCl \to ZnCl_2 + H_2\\ 2Al + 6HCl \to 2AlCl_3 + 3 H_2\\ Mg + 2HCl \to MgCl_2 + H_2\\ n_{H_2} = a + 1,5b + c = \dfrac{31,36}{22,4} = 1,4(2)\\ Mà : 2a = 3b(3)\\ (1)(2)(3) \Rightarrow a = 0,3 ; b = 0,2 ; c = 0,8\\ \%m_{Zn} = \dfrac{0,3.65}{44,1}.100\% = 44,22\%\\ \%m_{Al} = \dfrac{0,2.27}{44,1}.100\% = 12,24\%\)
\(\%m_{Mg} = 100\% -44,22\% -12,24\% = 43,54\%\)
\(a)n_{H_2}=\dfrac{7,55}{22,4}=\dfrac{151}{448}mol\\ n_{Mg}=n_{Zn}=a;n_{Fe}=c\\ Mg+H_2SO_4\rightarrow MgSO_4+H_2\\ a.....a\\ Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\ a.....a\\ Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ b.....b\\ \Rightarrow\left\{{}\begin{matrix}24a+65a+56b=16\\2a+b=\dfrac{151}{448}\end{matrix}\right.\\ \Rightarrow a=0,125;b=\dfrac{39}{448}\\ \%m_{Mg}=\dfrac{24.0,125}{16}\cdot100=18,75\%\\ \%m_{Zn}=\dfrac{65.0,125}{16}\cdot100=50,78\%\\ \%m_{Fe}=100-18,75-50,78=30,47\%\\ b)V_{ddH_2SO_4}=\dfrac{0,125.2+\dfrac{39}{448}}{1}\approx0,337l\)