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a)b)c)d) mBaCl2=150.16,64%=24,96g
=>nBaCl2=0,12 mol
mH2SO4=100.14,7%=14,7g=>nH2SO4=0,15mol
BaCl2 + H2SO4 =>BaSO4 +2HCl
Bđ: 0,12 mol; 0,15 mol
Pứ: 0,12 mol=>0,12 mol=>0,12 mol=>0,24 mol
Dư: 0,03 mol
Dd ban đầu chứa BaCl2 0,12 mol và H2SO4 0,15 mol
Dd A sau phản ứng chứa HCl 0,24 mol và H2SO4 dư 0,03 mol
mHCl=0,24.36,5=8,76g
mH2SO4=0,03.98=2,94g
Kết tủa B là BaSO4 0,12 mol=>mBaSO4=0,12.233=27,96g
mddA=mddBaCl2+mddH2SO4-mBaSO4
=150+100-27,96=222,04g
C%dd HCl=8,76/222,04.100%=3,945%
C% dd H2SO4=2,94/222,04.100%=1,324%
e) HCl +NaOH =>NaCl +H2O
0,24 mol=>0,24 mol
H2SO4 +2NaOH =>Na2SO4 + 2H2O
0,03 mol=>0,06 mol
TÔNG nNaOH=0,3 mol
=>V dd NaOH=0,3/2=0,15 lit
a/
\(n_{Na_2O}=\dfrac{9,3}{62}=0,15\left(mol\right)\)
\(Na_2O+H_2O\rightarrow2NaOH\)
0,15 0,3 (mol)
\(m_{NaOH}=0,3.40=12\left(g\right)\)
\(m_A=90,7+9,3=100\left(g\right)\)
\(C\%_{NaOH}=\dfrac{12}{100}.100\%=12\%\)
b/
m\(_{FeSO_4}=\dfrac{16.200}{100}=32\left(g\right)\)
\(\rightarrow m_{FeSO_4}=\dfrac{32}{152}=\dfrac{4}{19}\left(mol\right)\)
\(2NaOH+FeSO_4\rightarrow Na_2SO_4+Fe\left(OH\right)_2\downarrow\)
bđ: 0,3 \(\dfrac{4}{19}\) 0 0 (mol)
pư: 0,3 0,15 0,15 0,15 (mol)
dư: 0 \(\dfrac{23}{380}\) (mol)
\(m_{Fe\left(OH\right)_2}=0,15.90=13,5\left(g\right)\)
\(m_C=100+200-13,5=286,5\left(g\right)\)
\(m_{Na_2SO_4}=0,15.142=21,3\left(g\right)\)
\(\rightarrow C\%_{Na_2SO_4}=\dfrac{21,3}{286,5}.100\%\approx7,4\%\)
\(m_{FeSO_4\left(dư\right)}=\dfrac{23}{380}.152=9,2\left(g\right)\)
\(\rightarrow C\%_{FeSO_4\left(dư\right)}=\dfrac{9,2}{286,5}.100\%\approx3,2\%\)
PTHH: \(Na_2SO_4+CaCl_2\rightarrow2NaCl+CaSO_4\downarrow\)
Ta có: \(\left\{{}\begin{matrix}n_{Na_2SO_4}=0,1\cdot0,5=0,05\left(mol\right)\\n_{CaCl_2}=0,1\cdot0,4=0,04\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Na2SO4 dư
\(\Rightarrow\left\{{}\begin{matrix}n_{CaSO_4}=0,04\left(mol\right)\\n_{NaCl}=0,08\left(mol\right)\\n_{Na_2SO_4\left(dư\right)}=0,01\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{CaSO_4}=0,04\cdot136=5,44\left(g\right)\\C_{M_{NaCl}}=\dfrac{0,08}{0,1+0,1}=0,4\left(M\right)\\C_{M_{Na_2SO_4\left(dư\right)}}=\dfrac{0,01}{0,2}=0,05\left(M\right)\end{matrix}\right.\)
Bài 19 :
\(a) n_{Al} = \dfrac{10,8}{27} = 0,4(mol)\\ 2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2\\ n_{H_2} = \dfrac{3}{2}n_{Al} = 0,6(mol)\\ V_{H_2} = 0,6.22,4 = 13,44(lít)\\ b) \text{Chất tan : }Al_2(SO_4)_3\\ n_{Al_2(SO_4)_3} = \dfrac{1}{2}n_{Al} = 0,2(mol)\\ m_{Al_2(SO_4)_3} = 0,2.342 = 68,4(gam)\)
Bài 18 :
\(a) n_{HCl} = \dfrac{250.7,3\%}{36,5 } = 0,5(mol)\\ Zn + 2HCl \to ZnCl_2 + H_2\\ n_{H_2} = \dfrac{1}{2}n_{HCl} = 0,25(mol) \Rightarrow V_{H_2} = 0,25.22,4 = 5,6(lít)\\ b) \text{Chất tan : } ZnCl_2\\ n_{ZnCl_2} = n_{H_2} = 0,25(mol)\\ m_{ZnCl_2} = 0,25.136 = 34(gam)\)
\(a,n_{H_2SO_4}=0,3.0,75+0,3.0,25=0,3\left(mol\right)\\ V_{ddH_2SO_4}=300+300=600\left(ml\right)=0,6\left(l\right)\\ \rightarrow C_{M\left(H_2SO_4\right)}=\dfrac{0,3}{0,6}=0,5M\\ m_{H_2SO_4}=0,3.98=29,4\left(g\right)\\ m_{ddH_2SO_4}=600.1,02=612\left(g\right)\\ \rightarrow C\%_{H_2SO_4}=\dfrac{29,4}{612}.100\%=4,8\%\)
\(b,\) Đặt kim loại M có hoá trị n (n ∈ N*)
PTHH: \(2M+nH_2SO_4\rightarrow M_2\left(SO_4\right)_n+nH_2\uparrow\)
\(\dfrac{0,6}{n}\)<---0,3--------------------------->0,3
\(\rightarrow M_M=\dfrac{5,4}{\dfrac{0,6}{n}}=9n\left(g\text{/}mol\right)\)
Vì n là hoá trị của M nên ta xét bảng
| \(n\) | \(1\) | \(2\) | \(3\) |
| \(M_M\) | \(9\) | \(18\) | \(27\) |
| \(Loại\) | \(Loại\) | \(Al\) |
Vậy M là Al
\(c,n_{KClO_3}=\dfrac{15,3125}{122,5}=0,125\left(mol\right)\)
PTHH:
\(2H_2+O_2\xrightarrow[]{t^o}2H_2O\)
0,3-->0,15
\(2KClO_3\xrightarrow[]{t^o}2KCl+3O_2\uparrow\)
0,1<---------------------0,15
\(\rightarrow H=\dfrac{0,1}{0,125}.100\%=80\%\)
nNa = 6.9 : 23 = 0.3 mol
4Na + O2 ->2 Na2O
mol : 0.3 -> 0.15
Na2O + H2O -> 2NaOH
mol : 0.15 -> 0.3
mdd = 0.15 x 62 + 140.7 = 150g
C% NaOH = 0.3x40: 150 x 100% = 8%
mCuSO4= 12,8(g) ->nCuSO4=0,2(mol)
nNa=0,04(mol)
pthh: Na + H2O -> NaOH + 1/2 H2
-> nNaOH= 0,04(mol); nH2=0,02(mol)
=> V(A,đktc)=V(H2,đktc)=0,02.22,4=0,448(l)
2 NaOH + CuSO4 -> Cu(OH)2 + Na2SO4
Ta có: 0,04/2 < 0,2/1
=> CuSO4 dư, NaOH hết, tính theo nNaOH
=> nCu(OH)2=nCuSO4(p.ứ)=nNa2SO4=nNaOH/2=0,02(mol)
=> m(B)=mCu(OH)2=0,02.98=1,96(g)
b) mddC=mddCuSO4 + mNaOH - mCu(OH)2= 400+ 0,04.40- 1,96= 399,64(g)
mCuSO4(dư)= 0,18 x 160=28,8(g)
mNa2SO4=0,02.142= 2,84(g)
=> C%ddCuSO4(dư)= (28,8/399,64).100=7,206%
C%ddNa2SO4=(2,84/399,64).100=0,711%
nAl = \(\dfrac{5,4}{27}=0,2\) mol
mH2SO4 = \(\dfrac{4,9\times480}{100}=23,52\left(g\right)\)
=> nH2SO4 = \(\dfrac{23,52}{98}=0,24\) mol
Pt: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
0,16 mol<-0,24 mol-> 0,08 mol---> 0,24 mol
Xét tỉ lệ nol giữa Al và H2SO4:
\(\dfrac{0,2}{2}>\dfrac{0,24}{3}\)
Vậy Al dư
mAl dư = (0,2 - 0,16) . 27 = 1,08 (g)
mAl2(SO4)3 = 0,08 . 342 = 27,36 (g)
mdd sau pứ = mAl + mdd H2SO4 - mAl dư - mH2
...................= 5,4 + 480 - 1,08 - 0,24 . 2 = 483,84 (g)
C% dd Al2(SO4)3 = \(\dfrac{27,36}{483,84}.100\%=5,65\%\)
Pt: Al2(SO4)3 + 6NaOH --> 3Na2SO4 + 2Al(OH)3
0,08 mol-------> 0,48 mol
VNaOH cần = \(\dfrac{0,48}{1,25}=0,384\left(l\right)\)