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\(Đặt.kim.loại.kiềm:A\\ 2A+2HCl\rightarrow2ACl+H_2\\ m_{muối}-m_{kl}=m_{Cl^-}\\ \Leftrightarrow m_{Cl^-}=7,45-3,9=3,55\left(g\right)\\ \Rightarrow n_{HCl}=n_{Cl^-}=\dfrac{3,55}{35,5}=0,1\left(mol\right)\\ \Rightarrow n_A=n_{ACl}=n_{HCl}=0,1\left(mol\right)\\ a,M_A=\dfrac{3,9}{0,1}=39\left(\dfrac{g}{mol}\right)\\ \Rightarrow A\left(I\right):Kali\left(K=39\right)\\ b,n_{H_2}=\dfrac{n_{HCl}}{2}=\dfrac{0,1}{2}=0,05\left(mol\right)\\ \Rightarrow V_{H_2\left(đktc\right)}=0,05.22,4=1,12\left(l\right)\\ c,m_{ddHCl}=\dfrac{0,1.36,5.100}{31,7}=\dfrac{3650}{317}\left(g\right)\\ \Rightarrow V_{ddHCl}=\dfrac{\dfrac{3650}{317}}{1,15}\approx10,012\left(g\right)\)
a) Gọi kim loại cần tìm là R
\(n_R=\dfrac{7,56}{M_R}\left(mol\right)\)
PTHH: 2R + 2nHCl --> 2RCln + nH2
\(\dfrac{7,56}{M_R}\)------------>\(\dfrac{7,56}{M_R}\)
=> \(M_{RCl_n}=M_R+35,5n=\dfrac{37,38}{\dfrac{7,56}{M_R}}\)
=> \(M_R=9n\left(g/mol\right)\)
Xét n = 1 => MR = 9(Loại)
Xét n = 2 => MR = 18 (Loại)
Xét n = 3 => MR = 27(g/mol) => R là Al (Nhôm)
b)
\(n_{Al}=\dfrac{7,56}{27}=0,28\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
0,28-->0,84--->0,28--->0,42
=> \(V_{H_2}=0,42.22,4=9,408\left(l\right)\)
\(m_{HCl}=0,84.36,5=30,66\left(g\right)\)
=> \(m_{ddHCl}=\dfrac{30,66.100}{12}=255,5\left(g\right)\)
c) mdd sau pư = 7,56 + 255,5 - 0,42.2 = 262,22 (g)
=> \(C\%_{AlCl_3}=\dfrac{37,38}{262,22}.100\%=14,255\%\)
PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
Ta có: \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
Theo PT: \(\left\{{}\begin{matrix}n_{H_2}=n_{FeCl_2}=n_{Fe}=0,2\left(mol\right)\\n_{HCl}=2n_{Fe}=0,4\left(mol\right)\end{matrix}\right.\)
a, Ta có: \(V_{H_2}=0,2.22,4=4,48\left(l\right)\)
b, \(V_{ddHCl}=\dfrac{0,4}{1,5}\approx0,267\left(l\right)\)
c, \(m_{FeCl_2}=0,2.127=25,4\left(g\right)\)
Bạn tham khảo nhé!
a) $n_{Fe} = \dfrac{11,2}{56} = 0,2(mol)$
$Fe^0 \to Fe^{+3} + 3e$
$N^{+5} + 3e \to N^{+2}$
Bảo toàn electron : $3n_{Fe} = 3n_{NO}$
$\Rightarrow n_{NO} = 0,2(mol)$
$\Rightarrow V = 0,2.22,4 = 4,48(lít)$
b) $n_{Fe(NO_3)_3} = n_{Fe} = 0,2(mol)$
$\Rightarrow m = 0,2.242 = 48,4(gam)$
1)
a)
$CaO + 2HCl \to CaCl_2 + H_2O$
$CaCO_3 + 2HCl \to CaCl_2 + CO_2 + H_2O$
$n_{CaCO_3} = n_{CO_2} = 0,2(mol)$
$n_{CaCl_2} = 0,3(mol)$
Suy ra:
$n_{CaO} = 0,3 - 0,2 = 0,1(mol)$
$\%m_{CaO} = \dfrac{0,1.56}{0,1.56 + 0,2.100}.100\% = 21,875\%$
$\%m_{CaCO_3} = 78,125\%$
b)
$m_{dd} = 0,1.56 + 0,2.100 + 50 - 0,2.44 = 66,8(gam)$
$C\%_{CaCl_2} = \dfrac{33,3}{66,8}.100\% = 49,85\%$
Câu 4 :
a)
Gọi $n_{Fe} = a(mol) ; n_{MgO} = b(mol)$
Suy ra: $56a + 40b = 19,2(1)$
$Fe + 2HCl \to FeCl_2 + H_2$
$MgO + 2HCl \to MgCl_2 + H_2O$
Theo PTHH : $n_{HCl} = 2a + 2b = 0,4.2 = 0,8(2)$
Từ (1)(2) suy ra a = b = 0,2
$\%m_{Fe} = \dfrac{0,2.56}{19,2}.100\% = 58,33\%$
$\%m_{MgO} = 100\% -58,33\% = 41,67\%$
b)
$n_{FeCl_2} = a = 0,2(mol)$
$n_{MgCl_2} = b = 0,2(mol)$
$m_{muối} = 0,2.127 + 0,2.95 = 44,4(gam)$
Ta có: \(\left\{{}\begin{matrix}n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\n_{CaCl_2}=\dfrac{33,3}{111}=0,3\left(mol\right)\end{matrix}\right.\)
PTHH: \(CaCO_3+2HCl\rightarrow CaCl_2+CO_2\uparrow+H_2O\)
0,2_____0,4_____0,2____0,2_____0,2 (mol)
\(CaO+2HCl\rightarrow CaCl_2+H_2O\)
0,1_____0,2_____0,1____0,1 (mol)
Ta có: \(\left\{{}\begin{matrix}m_{CaO}=0,1\cdot56=5,6\left(g\right)\\m_{CaCO_3}=0,2\cdot100=20\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{CaO}=\dfrac{5,6}{5,6+20}\cdot100\%=21,875\%\\\%m_{CaCO_3}=78,125\%\end{matrix}\right.\)
Mặt khác: \(m_{CO_2}=0,2\cdot44=8,8\left(g\right)\)
\(\Rightarrow m_{dd\left(sau.p/ứ\right)}=m_{CaO}+m_{CaCO_3}+m_{ddHCl}-m_{CO_2}=66,8\left(g\right)\)
\(\Rightarrow C\%_{CaCl_2}=\dfrac{33,3}{66,8}\cdot100\%\approx49,85\%\)
nCO2=\(\dfrac{4,48}{22,4}=0,2\) mol
nCaCl2=\(\dfrac{33,3}{111}=0,3\)
CaCO2 + 2HCl → CaCl2 + CO2 + H2O
0,2 ← 0,2 ← 0,2
CaO + 2HCl → CaCl2 + H2O
0,1 ← 0,1
a) % CaO=\(\dfrac{0,1.56}{0,1.56+0,2.100}.100\%=21,875\%\)
% CaCO3 =100% - 21,875%= 78,125%
b) a = mCaO+mCaCO3 =0,1.56+0,2.100=25,6g
mdd sau pư= a + mddHCl - mCO2
= 25,6 + 50 - 0,2.44=66,8g
C%CaCl2=\(\dfrac{33,3}{66,8}.100\%\simeq49,85\%\)
nMg = 0,1(mol)
PTHH: Mg + 2HCl --> MgCl2 +H2
nMg = nMgCl2= nH2 = 0,1(mol)
=> mmuối = 9,5(g)
VH2 = 2,24(l)
b) CMHCl = 0,2/0,1=2(M)
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