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a) \(n_{Al}=\dfrac{8,64}{27}=0,32\left(mol\right)\)
\(n_{HCl}=\dfrac{365.10\%}{36,5}=1\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
Xét tỉ lệ \(\dfrac{0,32}{2}< \dfrac{1}{6}\) => Al hết, HCl dư
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
0,32-->0,96---->0,32--->0,48
=> \(V_{H_2}=0,48.22,4=10,752\left(l\right)\)
b) Trong Y chứa AlCl3 và HCl dư
\(m_{AlCl_3}=0,32.133,5=42,72\left(g\right)\)
c) mdd sau pư = 8,64 + 365 - 0,48.2 = 372,68 (g)
\(\left\{{}\begin{matrix}C\%\left(AlCl_3\right)=\dfrac{42,72}{372,68}.100\%=11,463\%\\C\%\left(HCldư\right)=\dfrac{\left(1-0,96\right).36,5}{372,68}.100\%=0,392\%\end{matrix}\right.\)
a) \(n_{H_2}=\dfrac{2,688}{22,4}=0,12\left(mol\right)\)
PTHH: R + 2HCl --> RCl2 + H2
0,12<-0,24<---------0,12
=> \(M_R=\dfrac{7,8}{0,12}=65\left(Zn\right)\)
=> Kim loại cần tìm là Kẽm
b) nNaOH = 0,08.2 = 0,16 (mol)
PTHH: NaOH + HCl --> NaCl + H2O
0,16--->0,16
=> nHCl = 0,16 + 0,24 = 0,4 (mol)
=> \(C_{M\left(ddHCl\right)}=\dfrac{0,4}{0,4}=1M\)
\(a,n_{H_2}=\dfrac{2,576}{22,4}=0,115\left(mol\right)\\ Đặt:n_{Mg}=a\left(mol\right);n_{Al}=b\left(mol\right)\left(a,b>0\right)\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ 2Al+6HCl\rightarrow2AlCl_3+3H_2\\ \Rightarrow\left\{{}\begin{matrix}95a+133,5b=10,475\\a+1,5b=0,115\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,04\\b=0,05\end{matrix}\right.\\ \%m_{Mg}=\dfrac{0,04.24}{0,04.24+0,05.27}.100\approx41,558\%\Rightarrow\%m_{Al}\approx58,442\%\\ b,n_{HCl}=2.n_{H_2}=2.0,115=0,23\left(mol\right)\\ \Rightarrow x=C\%_{ddHCl}=\dfrac{0,23.36,5}{100}.100=8,395\%\)
a) \(n_{AlCl_3}=\dfrac{6,675}{133,5}=0,05\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
0,05<-----------0,05---->0,075
=> \(\%Al=\dfrac{0,05.27}{14,15}.100\%=9,54\%\)
=> \(\%Cu=\dfrac{14,15-0,05.27}{14,15}.100\%=90,46\%\)
b) \(V_{H_2}=0,075.22,4=1,68\left(l\right)\)
c) \(n_{Cu}=\dfrac{14,15-0,05.27}{64}=0,2\left(mol\right)\)
PTHH: 4Al + 3O2 --to--> 2Al2O3
0,05->0,0375
2Cu + O2 --to--> 2CuO
0,2-->0,1
=> \(V_{O_2}=\left(0,1+0,0375\right).22,4=3,08\left(l\right)\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\\ m_{AlCl_3}=6,675\left(mol\right)\\ n_{AlCl_3}=\dfrac{6,675}{133,5}=0,05\left(mol\right)\\ \Rightarrow n_{Al}=n_{AlCl_3}=0,05\left(mol\right)\\ \Rightarrow m_A=0,05.27=1,35\left(g\right);m_{Cu}=14,15-1,35=12,8\left(g\right)\\ \%m_{Cu}=\dfrac{12,8}{14,15}.100\approx90,459\%\\ \Rightarrow\%m_{Al}\approx9,541\%\\ b,n_{Cu}=\dfrac{12,8}{64}=0,2\left(mol\right)\\ n_{H_2}=\dfrac{3}{2}.n_{Al}=\dfrac{3}{2}.0,05=0,075\left(mol\right)\\ \Rightarrow V=V_{H_2\left(đktc\right)}=0,075.22,4=1,68\left(l\right)\\ 4Al+3O_2\rightarrow\left(t^o\right)2Al_2O_3\\ 2Cu+O_2\rightarrow\left(t^o\right)2CuO\\ n_{O_2}=\dfrac{3}{4}.n_{Al}+\dfrac{1}{2}.n_{Cu}=\dfrac{3}{4}.0,05+\dfrac{1}{2}.0,2=0,0875\left(mol\right)\)
\(\Rightarrow V_{O_2\left(đktc\right)}=0,0875.22,4=1,96\left(l\right)\)
\(Đặt.kim.loại.kiềm:A\\ 2A+2HCl\rightarrow2ACl+H_2\\ m_{muối}-m_{kl}=m_{Cl^-}\\ \Leftrightarrow m_{Cl^-}=7,45-3,9=3,55\left(g\right)\\ \Rightarrow n_{HCl}=n_{Cl^-}=\dfrac{3,55}{35,5}=0,1\left(mol\right)\\ \Rightarrow n_A=n_{ACl}=n_{HCl}=0,1\left(mol\right)\\ a,M_A=\dfrac{3,9}{0,1}=39\left(\dfrac{g}{mol}\right)\\ \Rightarrow A\left(I\right):Kali\left(K=39\right)\\ b,n_{H_2}=\dfrac{n_{HCl}}{2}=\dfrac{0,1}{2}=0,05\left(mol\right)\\ \Rightarrow V_{H_2\left(đktc\right)}=0,05.22,4=1,12\left(l\right)\\ c,m_{ddHCl}=\dfrac{0,1.36,5.100}{31,7}=\dfrac{3650}{317}\left(g\right)\\ \Rightarrow V_{ddHCl}=\dfrac{\dfrac{3650}{317}}{1,15}\approx10,012\left(g\right)\)
a) Ta có \(m_{muôi}=m_{KL}+m_{Cl^-}\\ \Leftrightarrow m_{Cl^-}=m_{muôi}-m_{KL}=14,25-3,6=10,65g\\ \Rightarrow n_{Cl^-}=\dfrac{10,65}{35,5}=0,3mol\)
Theo bảo toàn nguyên tố Cl: \(n_{HCl}=n_{Cl^-}=0,3mol\)
Theo bảo toàn nguyên tố H: \(n_{H_2}=\dfrac{1}{2}\cdot n_{HCl}=\dfrac{1}{2}\cdot0,3=0,15mol\\ \Rightarrow V=0,15\cdot22,4=3,36l\)
Ta có PTHH: \(M+2HCl\rightarrow MCl_2+H_2\uparrow\)
----------------0,15-------------------------0,15---(mol)
\(\Rightarrow M=\dfrac{3,6}{0,15}=24\)(g/mol) => M là Magie (Mg)
b) \(n_{CuO}=\dfrac{16}{80}=0,2mol\)
Ta có quá trình phản ứng:
\(CuO+H_2\rightarrow Cu+H_2O\)
-0,15---0,15-----0,15----------(mol)
\(\Rightarrow a=m_{CuO\left(dư\right)}+m_{Cu}=\left(16-0,15\cdot80\right)+64\cdot0,15=13,6g\)
a) Gọi số mol Mg, Fe là a, b (mol)
=> 24a + 56b = 11,84
\(n_{HCl}=\dfrac{146.14\%}{36,5}=0,56\left(mol\right)\)
PTHH: Mg + 2HCl --> MgCl2 + H2
a--->2a--------->a----->a
Fe + 2HCl --> FeCl2 + H2
b-->2b-------->b------>b
=> 2a + 2b = 0,56
=> a = 0,12; b = 0,16
=> \(\left\{{}\begin{matrix}\%Mg=\dfrac{0,12.24}{11,84}.100\%=24,324\%\\\%Fe=\dfrac{0,16.56}{11,84}.100\%=75,676\%\end{matrix}\right.\)
b) \(n_{H_2}=a+b=0,28\left(mol\right)\)
=> \(V_{H_2}=0,28.22,4=6,272\left(l\right)\)
c) mdd sau pư = 11,84 + 146 - 0,28.2 = 157,28 (g)
=> \(\left\{{}\begin{matrix}C\%_{MgCl_2}=\dfrac{0,12.95}{157,28}.100\%=7,25\%\\C\%_{FeCl_2}=\dfrac{0,16.127}{157,28}.100\%=12,92\%\end{matrix}\right.\)
a) \(n_{FeCl_3}=\dfrac{16,25}{162,5}=0,1\left(mol\right)\)
PTHH: Fe2O3 + 6HCl --> 2FeCl3 + 3H2O
0,05<----0,3<-----0,1
=> \(m_{Fe_2O_3}=0,05.160=8\left(g\right)\)
b)
\(m_{HCl\left(bd\right)}=91,25.16\%=14,6\left(g\right)\)
mdd sau pư = 8 + 91,25 = 99,25 (g)
\(\left\{{}\begin{matrix}C\%\left(FeCl_3\right)=\dfrac{16,25}{99,25}.100\%=16,373\%\\C\%\left(HCldư\right)=\dfrac{14,6-0,3.36,5}{99,25}.100\%=3,678\%\end{matrix}\right.\)
a) Gọi kim loại cần tìm là R
\(n_R=\dfrac{7,56}{M_R}\left(mol\right)\)
PTHH: 2R + 2nHCl --> 2RCln + nH2
\(\dfrac{7,56}{M_R}\)------------>\(\dfrac{7,56}{M_R}\)
=> \(M_{RCl_n}=M_R+35,5n=\dfrac{37,38}{\dfrac{7,56}{M_R}}\)
=> \(M_R=9n\left(g/mol\right)\)
Xét n = 1 => MR = 9(Loại)
Xét n = 2 => MR = 18 (Loại)
Xét n = 3 => MR = 27(g/mol) => R là Al (Nhôm)
b)
\(n_{Al}=\dfrac{7,56}{27}=0,28\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
0,28-->0,84--->0,28--->0,42
=> \(V_{H_2}=0,42.22,4=9,408\left(l\right)\)
\(m_{HCl}=0,84.36,5=30,66\left(g\right)\)
=> \(m_{ddHCl}=\dfrac{30,66.100}{12}=255,5\left(g\right)\)
c) mdd sau pư = 7,56 + 255,5 - 0,42.2 = 262,22 (g)
=> \(C\%_{AlCl_3}=\dfrac{37,38}{262,22}.100\%=14,255\%\)