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a: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
0,2 0,4 0,2 0,2
\(n_{Mg}=\dfrac{4.8}{24}=0.2\left(mol\right)\)
=>\(n_{H_2}=0.2\left(mol\right)\)
\(V_{H_2}=0.2\cdot22.4=4.48\left(lít\right)\)
b:
\(n_{MgCl_2}=n_{Mg}=0.2\left(mol\right)\)
\(m_{MgCl_2}=0.2\left(24+35.5\cdot2\right)=19\left(g\right)\)
c: \(C\%\left(HCl\right)=\dfrac{0.4\cdot36.5}{100}=14.6\%\)
Ta có: \(n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\)
PT: \(CuO+2HCl\rightarrow CuCl_2+H_2O\)
a, Theo PT: \(n_{CuCl_2}=n_{CuO}=0,1\left(mol\right)\Rightarrow m_{CuCl_2}=0,1.135=13,5\left(g\right)\)
b, \(n_{HCl}=2n_{CuO}=0,2\left(mol\right)\Rightarrow C_{M_{HCl}}=\dfrac{0,2}{0,2}=1\left(M\right)\)
\(a,PTHH:CuCl_2+2KOH\rightarrow Cu\left(OH\right)_2+2KCl\\ ...0,2......0,4.......0,2........0,4\left(mol\right)\\ b,n_{CuCl_2}=\dfrac{27}{135}=0,2\left(mol\right)\\ m_{Cu\left(OH\right)_2}=0,2\cdot98=19,6\left(g\right)\\ c,m_{KOH}=0,4\cdot56=22,4\left(g\right)\\ m_{dd_{KOH}}=\dfrac{22,4\cdot100\%}{20\%}=112\left(g\right)\\ m_{dd_{KCl}}=m_{CuCl_2}+m_{dd_{KOH}}-m_{Cu\left(OH\right)_2}=27+112-19,6=119,4\left(g\right)\)
\(d,C\%_{dd_{KCl}}=\dfrac{74,5\cdot0,4}{119,4}\cdot100\%\approx24,96\%\)
\(n_{Fe_2O_3}=\dfrac{8}{160}=0,05\left(mol\right)\)
PTHH: Fe2O3 + 3H2SO4 --> Fe2(SO4)3 + 3H2O
______0,05------>0,15--------->0,05
=> mH2SO4 = 0,15.98 = 14,7(g)
=> \(C\%\left(H_2SO_4\right)=\dfrac{14,7}{100}.100\%=14,7\%\)
\(C\%\left(Fe_2\left(SO_4\right)_3\right)=\dfrac{0,05.400}{8+100}.100\%=18,52\%\)
PTHH: Fe2(SO4)3 + 6NaOH --> 2Fe(OH)3\(\downarrow\) + 3Na2SO4
________0,05----------------------->0,1
=> mFe(OH)3 = 0,1.107=10,7(g)
\(Pt: 2Al+3H_2SO_4 \rightarrow Al_2(SO_4)_3 + 3H_2\)
\(a.n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
Theo pt: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,2\left(mol\right)\)
\(\Rightarrow m_{Al}=a=0,2.27=5,4\left(g\right)\)
\(b.n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{3}n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow m_{Al_2\left(SO_4\right)_3}=0,1.342=34,2g\)
\(c.\)Theo pt: \(n_{H_2SO_4}=n_{H_2}=0,3\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4}=0,3.98=29,4g\)
\(C_{\%}H_2SO_4=\dfrac{29,4}{100}.100\%=29,4\%\)
\(n_{CuCl_2}=\dfrac{60,75}{135}=0,45mol\\ a)CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl\)
0,45 0,9 0,45 0,9
\(b)m_X=m_{Cu\left(OH\right)_2}=0,45.81=36,45g\\
c)m_{ddNaOH}=\dfrac{0,9.40}{15\%}\cdot100\%=240g\\
d)m_{ddNaCl}=60,75+240-36,45=264,3g\\
C_{\%NaCl}=\dfrac{0,9.58,5}{264,3}\cdot100\%=19,92\%\\
e)n_{H_2SO_4}=\dfrac{245.20\%}{100\%.98}=0,5mol\\
H_2SO_4+Cu\left(OH\right)_2\rightarrow CuSO_4+2H_2O\\
\Rightarrow\dfrac{0,5}{1}>\dfrac{0,45}{1}\Rightarrow H_2SO_4.dư\)
\(\Rightarrow\)Dung dịch acid \(H_2SO_4\) làm tan hết chất X\(\left(Cu\left(OH\right)_2\right)\)
\(2Al+3H_2SO_4 \to Al_2(SO_4)_3+3H_2\\ n_{Al}=0,4(mol)\\ a/\\ n_{H_2}=\frac{3}{2}.0,4=0,6(mol)\\ V_{H_2}=0,6.22,4=13,44(l)\\ b/\\ n_{H_2SO_4}=n_{H_2}=0,6(mol)\\ n_{ddH_2SO_4}=\frac{0,6.98.100}{20}=294(g)\\ c/\\ n_{Al_2(SO_4)_3}=0,2(mol)\\ C\%_{Al_2(SO_4)_3}=\frac{0,2.342}{10,8+294-0,6.2}.100\%=22,52\%\)
Câu 3 :
\(m_{ct}=\dfrac{10.80}{100}=8\left(g\right)\)
\(n_{NaOH}=\dfrac{8}{40}=0,2\left(mol\right)\)
a) Hiện tượng : Xuất hiện kết tủa trắng
Pt : \(2NaOH+MgSO_4\rightarrow Na_2SO_4+Mg\left(OH\right)_2|\)
2 1 1 1
0,2 0,1 0,1 0,1
\(n_{Mg\left(OH\right)2}=\dfrac{0,2.1}{2}=0,1\left(mol\right)\)
⇒ \(m_{Mg\left(OH\right)2}=0,1.58=5,8\left(g\right)\)
b) \(n_{MgSO4}=\dfrac{0,2.1}{2}=0,1\left(mol\right)\)
\(m_{MgSO4}=0,1.120=12\left(g\right)\)
\(m_{ddMgSO}=\dfrac{12.100}{10}=120\left(g\right)\)
c) \(n_{Na2SO4}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
⇒ \(m_{Na2SO4}=0,1.142=14,2\left(g\right)\)
\(m_{ddspu}=80+120-5,8=194,2\left(g\right)\)
\(C_{Na2SO4}=\dfrac{14,2.100}{194,2}=7,31\)0/0
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Câu 4 :
\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
Pt : \(Fe+H_2SO_4\rightarrow FeSO_4+H_2|\)
1 1 1 1
0,2 0,2
\(n_{H2SO4}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
\(m_{H2SO4}=0,2.98=19,6\left(g\right)\)
\(m_{ddH2SO4}=\dfrac{19,6.100}{20}=98\left(g\right)\)
\(V_{ddH2SO4}=\dfrac{98}{1,2}\simeq81,67\left(ml\right)\)
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