Bài 18. Tính khối lượng khí oxi cần dùng để đốt cháy hết hỗn hợp:
a) Hỗn hợp A: 0,25 mol sắt; 0,25 mol nhôm; 0,5 mol kẽm.
b) Hỗn hợp B: 6,2 gam P; 3,2 gam S; 2,4 gam C.
c) Hỗn hợp C: 2,8 gam C2H4; 1,4 gam CO; 0,58 gam C4H10.
Hãy nhập câu hỏi của bạn vào đây, nếu là tài khoản VIP, bạn sẽ được ưu tiên trả lời.
Bài 14
\(n_{O_2}=\dfrac{1.4}{22,4}=0,0625\left(mol\right)\)
\(n_P=\dfrac{2.5}{31}=0,0806451\left(mol\right)\)
4P + 5O2 ----to--->2P2O5
Xét tỉ lệ : \(\dfrac{0.0625}{5}< \dfrac{0.0806451}{4}\)
=> P ko cháy hết
bài 15
\(n_{O_2}=\dfrac{3.36}{22,4}=0,15\left(mol\right)\)
Gọi nFe = a ( mol ) và nS = b (mol )
PTHH :
S + O2 ---to---> SO2
3Fe + 2O2 ----to----> Fe3O4
Ta có 32b + 56a= 100
Theo PT : nS = nO2 = b (mol)
Theo PT : nO2 = 2/3 nFe = 2/3a ( mol)
=> 2/3a + b = 1,5
Từ những điều trên \(\left[{}\begin{matrix}56a+32b=100\\\dfrac{2}{3}a+b=1,5\end{matrix}\right.\Leftrightarrow\left[{}\begin{matrix}a=1,5\left(mol\right)\\b=0,5\left(mol\right)\end{matrix}\right.\)
\(m_{Fe}=1,5.56=84\left(g\right)\)
\(m_S=0,5.32=16\left(g\right)\)
a) PTHH: \(2CO+O_2\underrightarrow{t^o}2CO_2\) (1)
\(4H_2+O_2\underrightarrow{t^o}2H_2O\) (2)
b) Ta có: \(\left\{{}\begin{matrix}\Sigma n_{O_2}=\dfrac{9,6}{32}=0,3\left(mol\right)\\n_{CO_2}=\dfrac{8,8}{44}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{O_2\left(1\right)}=0,1mol\\n_{O_2\left(2\right)}=0,2mol\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{CO}=0,1\cdot28=2,8\left(g\right)\\m_{H_2}=0,2\cdot2=0,4\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{CO}=\dfrac{2,8}{2,8+0,4}\cdot100\%=87,5\%\\\%m_{H_2}=12,5\%\end{matrix}\right.\)
c) PTHH: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
Theo PTHH: \(n_{KMnO_4}=2n_{O_2}=0,6mol\)
\(\Rightarrow m_{KMnO_4}=0,6\cdot158=94,8\left(g\right)\)
Gọi \(\left\{{}\begin{matrix}n_{Mg}=x\left(mol\right)\\x_{Ca}=y\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}24x+40y=17,6\\x=2y\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,4\\y=0,2\end{matrix}\right.\)
a)\(m_{Mg}=0,4\cdot24=9,6g\)
\(m_{Ca}=0,2\cdot40=8g\)
b)\(2Mg+O_2\underrightarrow{t^o}2MgO\)
\(2Ca+O_2\underrightarrow{t^o}2CaO\)
Từ hai pt: \(\Rightarrow\Sigma n_{O_2}=\dfrac{1}{2}n_{Mg}+\dfrac{1}{2}n_{Ca}=\dfrac{1}{2}\cdot0,4+\dfrac{1}{2}\cdot0,2=0,3mol\)
\(\Rightarrow m_{O_2}=0,3\cdot32=9,6g\)
\(V_{O_2}=0,3\cdot22,4=6,72l\)
\(\Rightarrow V_{kk}=5V_{O_2}=5\cdot6,72=33,6l\)
a)
Có \(\left\{{}\begin{matrix}24.n_{Mg}+40.n_{Ca}=17,6\\n_{Mg}=2.n_{Ca}\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}n_{Ca}=0,2\left(mol\right)\\n_{Mg}=0,4\left(mol\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}m_{Ca}=0,2.40=8\left(g\right)\\m_{Mg}=0,4.24=9,6\left(g\right)\end{matrix}\right.\)
b)
PTHH: 2Ca + O2 --to--> 2CaO
0,2-->0,1
2Mg + O2 --to--> 2MgO
0,4--->0,2
=> \(V_{O_2}=\left(0,1+0,2\right).22,4=6,72\left(l\right)\)
\(V_{kk}=6,72.5=33,6\left(l\right)\)
Gọi x, y là số mol của C và S, ta có:
\(C+O_2\rightarrow CO_2\)
x x x
\(S+O_2\rightarrow SO_2\)
y y y
\(\Rightarrow\left\{{}\begin{matrix}x+y=\dfrac{4,48}{22,4}=0,2\\12x+32y=4,4\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,1\end{matrix}\right.mol\)
\(\Rightarrow m_{hh}=0,1.44+0,1.64=10,8g\)
$n_{CO_2} = \dfrac{8,8}{44} = 0,2(mol)$
\(2CO+O_2\xrightarrow[]{t^o}2CO_2\)
0,2 0,1 0,2 (mol)
$n_{O_2} = \dfrac{9,6}{32} = 0,3(mol)$
\(2H_2+O_2\xrightarrow[]{t^o}2H_2O\)
0,4 0,2 0,2 (mol)
\(\%m_{CO}=\dfrac{0,2.44}{0,2.44+0,4.2}.100\%=91,67\%\\ \%m_{H_2}=100\%-91,67\%=8,33\%\)
\(\%n_{CO}=\dfrac{0,2}{0,2+0,4}.100\%=33,33\%\\ \%n_{H_2}=100\%-33,33\%=66,67\%\)
\(a,Đặt:n_{CH_4}=a\left(mol\right);n_{C_4H_{10}}=b\left(mol\right)\left(a,b>0\right)\\ PTHH:CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\\ 2C_4H_{10}+13O_2\rightarrow\left(t^o\right)8CO_2+10H_2O\\ \Rightarrow\left\{{}\begin{matrix}16a+58b=7,4\\22,4a+22,4.4b=22\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}m_{CH_4}=0,1.16=1,6\left(g\right)\\m_{C_4H_{10}}=0,1.58=5,8\left(g\right)\end{matrix}\right.\\ b,n_{O_2}=2a+\dfrac{13}{2}b=2.0,1+6,5.0,1=0,85\left(mol\right)\\ \Rightarrow V_{O_2\left(đktc\right)}=0,85.22,4=19,04\left(l\right)\)
b, \(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
\(n_P=\dfrac{6,2}{31}=0,2mol\\n_{O_2}=\dfrac{0,2.5}{4}=0,25mol \)
\(S+O_2\underrightarrow{t^o}SO_2\)
\(n_S=\dfrac{3,2}{32}=0,1mol\\ n_{O_2}=0,1mol\)
\(C+O_2\underrightarrow{t^o}CO_2\)
\(n_C=\dfrac{2,4}{12}=0,2mol\\ n_{O_2}=0,2mol\\ n_{O_2}\left(tổng\right)=\)
\(0,25+0,1+0,2=0,55mol\\ m_{O_2}\left(trong.hh.B\right)=0,55.32=17,6g\)
a, \(m_{Fe}=0,25.56=14g\)
\(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
\(\Rightarrow n_{O_2}=\dfrac{0,25.2}{3}=0,16mol\\ m_{O_2}=0,16.32=5,12g\)
\(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)
\(n_{O_2}=\dfrac{0,25.3}{4}=0,1875mol\\ m_{O_2}=0,1875.32=6g\)
\(2Zn+O_2\underrightarrow{t^o}2ZnO\)
\(n_{O_2}=\dfrac{0,5.1}{2}=0,25mol\\ m_{O_2}=0,25.32=8g\)
\(\Rightarrow m_{O_2}\left(trong.hỗn.hợp.A\right)=\) \(5,12+6+8=19,12g\)