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a, \(MgCl_2+2NaOH\rightarrow Mg\left(OH\right)_2+2NaCl\)
\(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O\)
b, \(n_{MgCl_2}=0,2.0,25=0,05\left(mol\right)\)
Theo PT: \(n_{MgO}=n_{Mg\left(OH\right)_2}=n_{MgCl_2}=0,05\left(mol\right)\)
\(\Rightarrow m_{MgO}=0,05.40=2\left(g\right)\)
c, \(n_{NaOH}=2n_{MgCl_2}=0,1\left(mol\right)\)
\(\Rightarrow m_{ddNaOH}=\dfrac{0,1.40}{15\%}=\dfrac{80}{3}\left(g\right)\)
a)PTHH: \(Ba\left(OH\right)+Na_2CO_3\rightarrow2NaOH+BaCO_3\downarrow\)
\(BaCO_3\underrightarrow{t^o}BaO+CO_2\uparrow\)
Ta có: \(n_{Ba\left(OH\right)_2}=0,4\cdot0,2=0,08\left(mol\right)\)
\(\Rightarrow n_{NaOH}=0,16mol\) \(\Rightarrow C_{M_{NaOH}}=\dfrac{0,16}{0,4}=0,4\left(M\right)\) (Coi Vdd thay đổi không đáng kể)
b) Theo PTHH: \(n_{BaCO_3}=n_{Ba\left(OH\right)_2}=n_{BaO}=0,08mol\) \(\Rightarrow m_{BaO}=0,08\cdot153=12,24\left(g\right)\)
a. Ba(OH)2 +Na2CO3 ➝ BaCO3 + 2NaOH
BaCO3 ➝ BaO + CO2
nBa(OH)2 = 0,08 mol
=> nNaOH = 2nBa(OH)2 = 0,16 mol
=> CM = 0,4 M
b) Bảo toàn Ba: nBaO = nBa(OH)2 = 0,08 mol
=> m = 12,24 g
\(n_{NaOH}=\dfrac{200.15\%}{40}=0,75\left(mol\right)\)
\(\left\{{}\begin{matrix}n_{H_2SO_4}=0,0001V\left(mol\right)\\n_{Fe_2\left(SO_4\right)_3}=0,00005V\left(mol\right)\end{matrix}\right.\)
PTHH: 2NaOH + H2SO4 --> Na2SO4 + 2H2O
0,0002V<-0,0001V
6NaOH + Fe2(SO4)3 --> 3Na2SO4 + 2Fe(OH)3
0,0003V<-0,00005V---------------->0,0001V
=> 0,0002V + 0,0003V = 0,75
=> V = 1500 (ml)
nFe(OH)3 = 0,15 (mol)
=> m1 = 0,15.107 = 16,05 (g)
PTHH: 2Fe(OH)3 --to--> Fe2O3 + 3H2O
0,15--------->0,075
=> mFe2O3 = 0,075.160 = 12 (g)
a, \(FeCl_3+3NaOH\rightarrow3NaCl+Fe\left(OH\right)_3\)
\(2Fe\left(OH\right)_3\underrightarrow{t^o}Fe_2O_3+3H_2O\)
b, \(n_{FeCl_3}=0,4.2=0,8\left(mol\right)\)
Theo PT: \(n_{NaCl}=3n_{FeCl_3}=2,4\left(mol\right)\)
\(\Rightarrow C_{M_{NaCl}}=\dfrac{2,4}{0,4+0,2}=4\left(M\right)\)
c, \(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=\dfrac{1}{2}n_{FeCl_3}=0,4\left(mol\right)\)
\(\Rightarrow m_{Fe_2O_3}=0,4.160=64\left(g\right)\)
\(n_{FeCl3}=2.0,4=0,8\left(mol\right)\)
PTHH : \(FeCl_3+3NaOH\rightarrow Fe\left(OH\right)_3+3NaCl\)
0,8----------------------->0,8----------->2,4
b) \(C_{MNaCl}=\dfrac{2,4}{0,4+0,2}=4M\)
c) \(2Fe\left(OH\right)_3\xrightarrow[]{t^o}Fe_2O_3+3H_2O\)
0,8--------------->0,4
\(\Rightarrow a=m_{Fe2O3}=0,4.160=64\left(g\right)\)
\(a,PTHH:3NaOH+FeCl_3\rightarrow3NaCl+Fe\left(OH\right)_3\downarrow\\ 2Fe\left(OH\right)_3\rightarrow^{t^o}Fe_2O_3+3H_2O\uparrow\\ b,n_{FeCl_3}=1,5\cdot0,2=0,3\left(mol\right)\\ \Rightarrow n_{NaOH}=3n_{FeCl_3}=0,9\left(mol\right)\\ \Rightarrow V_{dd_{NaOH}}=\dfrac{0,9}{2}=0,45\left(l\right)\)
Theo đề: \(\left\{{}\begin{matrix}X:Fe\left(OH\right)_3\\A:NaCl\\Y:Fe_2O_3\end{matrix}\right.\)
Theo PT: \(n_{NaCl}=3n_{FeCl_3}=0,9\left(mol\right)\)
\(\Rightarrow C_{M_{NaCl}}=\dfrac{0,9}{0,45+0,2}\approx1,4M\)
\(c,\) Theo PT: \(n_{Fe\left(OH\right)_3}=n_{FeCl_3}=0,3\left(mol\right);n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_X=m_{Fe\left(OH\right)_3}=0,3\cdot107=32,1\left(g\right)\\m_Y=m_{Fe_2O_3}=0,15\cdot160=24\left(g\right)\end{matrix}\right.\)
