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Ca(HCO3)2 + Ca(OH)2 -> 2CaCO3 + 2H2O
Ca(HCO3)2 -> CaCO3 + CO2 + H2O
Ca(HCO3)2 + Ba(OH)2 -> CaCO3 + 2H2O + BaCO3
Ca(HCO3)2 + NaOH ->CaCO3 + NaHCO3 + H2O
a) CaCO3\(\rightarrow\)CaO(A)+CO2(P)
CaO+H2O(B)\(\rightarrow\)Ca(OH)2(C)
Ca(OH)2+2HCl(D)\(\rightarrow\)CaCl2(E)+2H2O
CaCl2+K2CO3(F)\(\rightarrow\)CaCO3+2KCl
CO2+NaOH(X)\(\rightarrow\)NaHCO3(Q)
2NaHCO3+2KOH(Y)\(\rightarrow\)Na2CO3+K2CO3(R)+2H2O
K2CO3+Ca(NO3)2(Z)\(\rightarrow\)CaCO3+2KNO3
%Na = 39,316% => MZ = 58,5
=> Z là NaCl
=> X là H2 và Y là HCl
Pt: Cl2 + H2 → 2HCl
HCl + NaOH → NaCl + H2O
2NaCl + H2SO4đặc → Na2SO4 + 2HCl
4HCl + MnO2 → MnCl2 + Cl2↑ + 2H2O
PTHH: \(X+2HCl\rightarrow XCl_2+H_2\)
\(Y+2HCl\rightarrow YCl_2+H_2\)
\(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
\(n_{HCl\left(pứ\right)}=2.n_{H_2}=2.0,4=0,8\left(mol\right)\)
Áp dụng ĐLBTKL:
\(m=16+0,8.36,5-0,4.2=44,4\left(g\right)\)
b) Ta có: \(\dfrac{n_X}{n_Y}=\dfrac{1}{1}\Rightarrow n_X=n_Y\)
\(\dfrac{M_X}{M_Y}=\dfrac{3}{7}\Rightarrow M_X=\dfrac{3}{7}M_Y\)
Ta có: \(M_X.n_X+M_Y.n_Y=16\left(1\right)\)
\(\left(M_X+71\right).n_X+\left(M_Y+71\right).n_Y=44,4\left(2\right)\)
\(\Leftrightarrow M_X.n_Y+M_Y.n_Y=16\left(3\right)\)
\(M_X.n_Y+71.n_Y+M_Y.n_Y+71.n_Y=44,4\left(4\right)\)
Lấy (4)-(3), ta được: \(142n_Y=28,4\)
\(\Leftrightarrow n_Y=\dfrac{28,4}{142}=0,2\left(mol\right)\)
Theo (3),ta có: \(M_X.0,2+M_Y.0,2=16\)
\(\left(M_X+M_Y\right).0,2=16\)
\(\left(\dfrac{3}{7}M_Y+M_Y\right).0,2=16\)
\(\left(\dfrac{10}{7}M_Y\right).0,2=16\)
\(\Rightarrow M_Y=56\)\(\Rightarrow M_X=56\)\(.\)\(\dfrac{3}{7}=24\)
Vậy X là Magie(Mg), Y là Sắt(Fe)
Đặt : \(n_{Fe}=a\left(mol\right),n_{Zn}=b\left(mol\right)\)
\(\Rightarrow56a+65b=18,6\left(g\right)\)
Các PTHH :
\(FeO+H_2\rightarrow Fe+H_2O\)
\(ZnO+H_2\rightarrow Zn+H_2O\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(Bte:2x+2y=\dfrac{6,72}{22,4}.2\left(2\right)\)
Từ(1),(2) \(\Rightarrow\left\{{}\begin{matrix}a=0,1\left(mol\right)=n_{FeO}\\b=0,2\left(mol\right)=n_{ZnO}\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{FeO}=0,1.72=7,2\left(g\right)\\m_{ZnO}=0,2.81=16,2\left(g\right)\end{matrix}\right.\)
b) \(m_{ddspu}=18,6+200-0,3.2=218\left(g\right)\)
Theo Pt : \(n_{Zn}=n_{ZnCl2}=0,2\left(mol\right)\)
\(C\%_{ZnCl2}=\dfrac{0,2.136}{218}.100\%=12,48\%\)
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