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n hh=\(\dfrac{4,48}{22,4}\)=0,2 mol
=>n O2=n hh=0,2 mol
=>VO2=0,2.22,4=4,48l
\(n_B=\dfrac{4,48}{22,4}=0,2mol\)
\(C+O_2\underrightarrow{t^o}CO_2\)
\(S+O_2\underrightarrow{t^o}SO_2\)
\(\Rightarrow n_B=\Sigma n_{O_2}=0,2mol\)
\(\Rightarrow V_{O_2}=0,2\cdot22,4=4,48l\)
\(n_B=\dfrac{4,48}{22,4}=0,2mol\)
\(C+O_2\underrightarrow{t^o}CO_2\)
\(S+O_2\underrightarrow{t^o}SO_2\)
\(\Rightarrow\Sigma n_B=\Sigma n_{O_2}=0,2mol\)
\(\Rightarrow V_{O_2}=0,2\cdot22,4=4,48l\)
TN1: Gọi (nCu, nAl, nFe) = (a,b,c)
=> 64a + 27b + 56c = 14,3 (1)
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
b----------------------->1,5b
Fe + 2HCl --> FeCl2 + H2
c----------------------->c
=> 1,5b + c = 0,3 (2)
TN2: Gọi (nCu, nAl, nFe) = (ak,bk,ck)
=> ak + bk + ck = 0,6 (3)
\(n_{O_2}=\dfrac{44,8}{22,4}.20\%=0,4\left(mol\right)\)
PTHH: 2Cu + O2 --to--> 2CuO
ak--->0,5ak
4Al + 3O2 --to--> 2Al2O3
bk--->0,75bk
3Fe + 2O2 --to--> Fe3O4
ck-->\(\dfrac{2}{3}ck\)
=> 0,5ak + 0,75bk + \(\dfrac{2}{3}ck\) = 0,4 (4)
(1)(2)(3) => \(\left\{{}\begin{matrix}a=0,05\left(mol\right)\\b=0,1\left(mol\right)\\c=0,15\left(mol\right)\\k=2\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}\%m_{Cu}=\dfrac{0,05.64}{14,3}.100\%=22,38\%\\\%m_{Al}=\dfrac{0,1.27}{14,3}.100\%=18,88\%\\\%m_{Fe}=\dfrac{0,15.56}{14,3}.100\%=58,74\%\end{matrix}\right.\)
1) PTHH: 2Fe2O3 + 3CO →4Fe + 3CO2
2) nco=\(\dfrac{V}{22,4}\)=\(\dfrac{3,36}{22,4}=0,15\)(mol)
-Theo PTHH, ta có:
2.nFe2O3=3.nCO=4.nFe=3.nCO2=3.0,15=0,45(mol)
=>nFe2O3=\(\dfrac{0,45}{2}=0,225\left(mol\right)\)
=>mFe2O3=n.M=0,225.(56.2+16.3)=36(g)
c)- Ta có: 3.nCO2=3.0,15=0,45(mol)
=>nCO2=\(\dfrac{0,45}{3}=0,15\left(mol\right)\)
=>VCO2=n.22,4=0,15.22,4=3,36(lít)
Câu 2:
Ta có: 80nCuO + 160nFe2O3 = 16 (1)
m giảm = 16.25% = 4 (g) = mO (trong oxit)
\(\Rightarrow n_{O\left(trongoxit\right)}=\dfrac{4}{16}=0,25\left(mol\right)\)
BTNT O, có: nCuO + 3nFe2O3 = 0,25 (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CuO}=0,1\left(mol\right)\\n_{Fe_2O_3}=0,05\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{CuO}=\dfrac{0,1.80}{16}.100\%=50\%\\\%m_{Fe_2O_3}=50\%\end{matrix}\right.\)
Bạn bổ sung đủ đề câu 3 nhé.
Câu 1:
Ta có: \(n_{CO}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
BTNT C, có: nCO2 = nCO = 0,25 (mol)
BTKL, có: mhh + mCO = m chất rắn + mCO2
⇒ m chất rắn = 30 + 0,25.28 - 0,25.44 = 26 (g)
a)
2CO + O2 --to--> 2CO2
2H2 + O2 --to--> 2H2O
b) \(n_{H_2O}=\dfrac{12,6}{18}=0,7\left(mol\right)\); \(n_{CO_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
PTHH: 2CO + O2 --to--> 2CO2
0,6<--0,3<------0,6
2H2 + O2 --to--> 2H2O
0,7<--0,35<------0,7
=> \(\left\{{}\begin{matrix}V_{CO}=0,6.22,4=13,44\left(l\right)\\V_{H_2}=0,7.22,4=15,68\left(l\right)\end{matrix}\right.\)
VO2 = (0,3 + 0,35).22,4 = 14,56 (l)
c) \(M_A=\dfrac{0,6.28+0,7.2}{0,6+0,7}=14\left(g/mol\right)\)
=> \(d_{A/O_2}=\dfrac{14}{32}=0,4375\)
CO+FeO--->Fe+CO2
Fe2O3+3CO--->2Fe+3CO2
Fe3O4+4CO---->Fe+4CO2
Ta có
n CO2=4,48/22,4=0,2(mol)
theo cả 3 PTHH
n CO=n CO2=0,2(mol)
V CO(đktc)=0,2.22,4=4,48(l)