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Gọi số mol H2, O2 là a, b (mol)
=> \(\left\{{}\begin{matrix}a+b=\dfrac{22,4}{22,4}=1\\M_B=\dfrac{2a+32b}{a+b}=5,5.2=11\left(g/mol\right)\end{matrix}\right.\)
=> a = 0,7 (mol); b = 0,3 (mol)
PTHH: 2H2 + O2 --to--> 2H2O
Xét tỉ lệ: \(\dfrac{0,7}{2}>\dfrac{0,3}{1}\) => H2 dư, O2 hết
PTHH: 2H2 + O2 --to--> 2H2O
0,6<--0,3------->0,6
=> \(\left\{{}\begin{matrix}m_{H_2O}=0,6.18=10,8\left(g\right)\\m_{H_2\left(dư\right)}=\left(0,7-0,6\right).2=0,2\left(g\right)\end{matrix}\right.\)
a, \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
\(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)
\(2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\)
b, Sửa đề: 17,9 (l) → 17,92 (l)
Ta có: \(n_{CO_2}=\dfrac{17,92}{22,4}=0,8\left(mol\right)=n_C\)
\(n_{H_2O}=\dfrac{18}{18}=1\left(mol\right)\Rightarrow n_H=1.2=2\left(mol\right)\)
⇒ mA = mC + mH = 0,8.12 + 2.1 = 11,6 (g)
Theo ĐLBT KL, có: mA + mO2 = mCO2 + mH2O
⇒ mO2 = 0,8.44 + 18 - 11,6 = 41,6 (g)
\(\Rightarrow n_{O_2}=\dfrac{41,6}{32}=1,3\left(mol\right)\Rightarrow V_{O_2}=1,3.22,4=29,12\left(l\right)\)
\(n_{O_2}=\dfrac{89.6}{22.4}=4\left(mol\right)\)
\(n_{H_2O}=3a\left(mol\right)\)
\(n_{CO_2}=a\left(mol\right)\)
\(2H_2+O_2\underrightarrow{^{^{t^0}}}2H_2O\)
\(2CO+O_2\underrightarrow{^{^{t^0}}}2CO_2\)
\(n_{O_2}=1.5a+0.5a=4\left(mol\right)\)
\(\Leftrightarrow a=2\)
\(n_{H_2}=3\left(mol\right),n_{CO}=1\left(mol\right)\)
\(\%V_{H_2}=\dfrac{3}{4}\cdot100\%=75\%\)
\(\%V_{CO}=25\%\)
\(\%m_{H_2}=\dfrac{3\cdot2}{3\cdot2+1\cdot28}\cdot100\%=17.64\%\)
\(\%m_{CO}=100-17.64=82.36\%\)
nO (trong CO2) = 2 . nCO2 = 2 . 26,4/44 = 1,2 (mol)
nO (trong H2O) = nH2O = 13,5/18 = 0,75 (mol)
nO (trong O2) = 1,2 + 0,75 = 1,95 (mol)
nO2 = 1,95/2 = 0,975 (mol)
VO2 = 0,975 . 22,4 = 21,84 (l)
Vkk = 21,84 . 5 = 109,2 (l)
nO (trong CO2) = 2 . nCO2 = 2 . 26,4/44 = 1,2 (mol)
nO (trong H2O) = nH2O = 13,5/18 = 0,75 (mol)
nO (trong O2) = 1,2 + 0,75 = 1,95 (mol)
nO2 = 1,95/2 = 0,975 (mol)
VO2 = 0,975 . 22,4 = 21,84 (l)
Vkk = 21,84 . 5 = 109,2 (l)
a) PTHH: \(2CO+O_2\underrightarrow{t^o}2CO_2\) (1)
\(4H_2+O_2\underrightarrow{t^o}2H_2O\) (2)
b) Ta có: \(\left\{{}\begin{matrix}\Sigma n_{O_2}=\dfrac{9,6}{32}=0,3\left(mol\right)\\n_{CO_2}=\dfrac{8,8}{44}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{O_2\left(1\right)}=0,1mol\\n_{O_2\left(2\right)}=0,2mol\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{CO}=0,1\cdot28=2,8\left(g\right)\\m_{H_2}=0,2\cdot2=0,4\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{CO}=\dfrac{2,8}{2,8+0,4}\cdot100\%=87,5\%\\\%m_{H_2}=12,5\%\end{matrix}\right.\)
c) PTHH: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
Theo PTHH: \(n_{KMnO_4}=2n_{O_2}=0,6mol\)
\(\Rightarrow m_{KMnO_4}=0,6\cdot158=94,8\left(g\right)\)
Gọi \(\left\{{}\begin{matrix}n_{CH_4}=x\left(mol\right)\\n_{C_2H_6}=y\left(mol\right)\end{matrix}\right.\)
\(n_{H_2O}=\dfrac{14,4}{18}=0,8\left(mol\right)\)
\(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
x-------->2x----------->2x
\(C_2H_6+\dfrac{7}{2}O_2\underrightarrow{t^o}2CO_2+3H_2O\)
y-------->3,5y------------->3y
Có hệ phương trình: \(\left\{{}\begin{matrix}x+y=\dfrac{6,72}{22,4}=0,3\\2x+3y=0,8\end{matrix}\right.\)
\(\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)
a
\(\%V_{CH_4}=\dfrac{0,1.22,4.100\%}{6,72}=33,33\%\)
\(\%V_{C_2H_6}=\dfrac{0,2.22,4.100\%}{6,72}=66,67\%\)
b
\(V_{O_2}=\left(2x+3,5y\right).22,4=\left(2.0,1+3,5.0,2\right).22,4=20,16\left(l\right)\)
Cho dữ liệu dư 10% như thế thì phải hỏi là V khí \(O_2\) đã lấy/ đã dùng chứ "cần lấy" là theo PTHH (không cần cho "Biết ...")
\(V_{O_2.đã.lấy}=\dfrac{20,16.\left(100+10\right)\%}{100\%}=22,176\left(l\right)\)
\(a)\\ 2CO + O_2 \xrightarrow{t^o} 2CO\\ 2H_2 + O_2 \xrightarrow{t^o} 2H_2O\\ n_{H_2} = n_{H_2O} = \dfrac{1,8}{18} = 0,1(mol)\\ \)
Theo PTHH :
\(2n_{O_2} = n_{CO} + n_{H_2}\\ \Leftrightarrow 2.\dfrac{3,36}{22,4} = n_{CO} + 0,1\\ \Leftrightarrow n_{CO} = 0,2(mol)\\ \%V_{H_2} = \dfrac{0,1}{0,1+ 0,2}.100\% = 33,33\%\\ \%V_{CO} = 100\%-33,33\% = 66,67\%\\ c) Cách\ 1 :\\ n_{CO_2} = n_{CO} = 0,2(mol)\\ m_{CO_2} = 0,2.44 = 8,8(gam)\\ Cách\ 2 : \\ m_{hh} = m_{CO} + m_{H_2} = 0,2.28 + 0,1.2 = 5,8(gam) \)
Bảo toàn khối lượng :
\(m_{hh} + m_{O_2} = m_{H_2O} + m_{CO_2}\\ \Rightarrow m_{CO_2} = 5,8 + 0,15.32 - 1,8 = 8,8(gam)\)
a)
2CO + O2 --to--> 2CO2
2H2 + O2 --to--> 2H2O
b) \(n_{H_2O}=\dfrac{12,6}{18}=0,7\left(mol\right)\); \(n_{CO_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
PTHH: 2CO + O2 --to--> 2CO2
0,6<--0,3<------0,6
2H2 + O2 --to--> 2H2O
0,7<--0,35<------0,7
=> \(\left\{{}\begin{matrix}V_{CO}=0,6.22,4=13,44\left(l\right)\\V_{H_2}=0,7.22,4=15,68\left(l\right)\end{matrix}\right.\)
VO2 = (0,3 + 0,35).22,4 = 14,56 (l)
c) \(M_A=\dfrac{0,6.28+0,7.2}{0,6+0,7}=14\left(g/mol\right)\)
=> \(d_{A/O_2}=\dfrac{14}{32}=0,4375\)