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\(n_{CuSO_4}=\dfrac{15,2}{160}=0,095mol\\ CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
0,095 0,19 0,095 0,095
\(m_{rắn}=m_{Cu\left(OH\right)_2}=0,095.98=9,31g\\ V_{ddNaOH}=\dfrac{0,19}{2}=0,095l\\ b)C_{M_{Na_2SO_4}}=\dfrac{0,095}{0,04+0,095}\approx0,7M\\ c)Cu\left(OH\right)_2\xrightarrow[t^0]{}CuO+H_2O\)
0,095 0,095
\(m_{rắn}=m_{CuO}=0,095.80=7,6g\)
a, \(2NaOH+CuSO_4\rightarrow Na_2SO_4+Cu\left(OH\right)_2\)
\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
b, \(m_{CuSO_4}=250.16\%=40\left(g\right)\Rightarrow n_{CuSO_4}=\dfrac{40}{160}=0,25\left(mol\right)\)
Theo PT: \(n_{CuO}=n_{Cu\left(OH\right)_2}=n_{CuSO_4}=0,25\left(mol\right)\)
\(\Rightarrow a=m_{CuO}=0,25.80=20\left(g\right)\)
c, Ta có: m dd sau pư = m dd NaOH + m dd CuSO4 - mCu(OH)2 = 200 + 250 - 0,25.98 = 425,5 (g)
\(n_{NaOH}=\dfrac{200.10\%}{40}=0,5\left(mol\right)\)
\(PTHH:CuCl_2+2NaOH\rightarrow2NaCl+Cu\left(OH\right)_2\)
bđ: 0,3 0,5
pứ: 0,25 0,5 0,5 0,25
[ ]: 0,05 0 0,5 0,25
\(PTHH:Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
(mol) 0,25 0,25
\(a.m_C=80.0,25=20\left(g\right)\)
\(b.m_{NaCl}=58,5.0,5=29,25\left(g\right)\\ m_{Cu\left(OH\right)_2}=0,25.98=24,5\left(g\right)\\ m_{CuCl_2\left(du\right)}=135.0,05=6,75\left(g\right)\)
\(c.m_{ddspu}=100+200-24,5=275,5\left(g\right)\\ C\%_{ddCuCl_2\left(du\right)}=\dfrac{135.0,05}{275,5}.100=2,45\left(\%\right)\\ C\%_{ddNaCl}=\dfrac{0,5.58,5}{275,25}.100=10,62\left(\%\right)\)
\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1mol\)
a)\(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\)
0,1 0,2 0,1 0,1 0,1
b)\(m_{HCl}=0,1\cdot36,5=3,65\left(g\right)\)
\(a\%=\dfrac{3,65}{100}\cdot100\%=3,65\%\)
c)\(m_{CaCO_3}=0,1\cdot100=10\left(G\right)\)
\(\Rightarrow\%m_{CaCO_3}=\dfrac{10}{16}\cdot100\%=62,5\%\)
\(\Rightarrow\%m_{CaCl_2}=100\%-62,5\%=37,5\%\)
d)\(m_{CaCl_2}=0,1\cdot111=11,1\left(g\right)\)
\(m_{H_2O}=0,1\cdot18=1,8\left(g\right)\)
\(m_{ddsau}=10+100-0,1\cdot44-1,8=103,8\left(g\right)\)
\(\Rightarrow C\%=\dfrac{11,1}{103,8}\cdot100\%=10,7\%\)
\(n_{CuSO_4}=\dfrac{200.16\%}{160}=0,2\left(mol\right)\)
PTHH :
\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2\downarrow+Na_2SO_4\)
0,2 0,4 0,2 0,2
\(m_{NaOH}=0,4.40=16\left(g\right)\)
\(m_{ddNaOH}=\dfrac{16.100}{10}=160\left(g\right)\)
\(c,m_{Na_2SO_4}=0,2.142=28,4\left(g\right)\)
\(m_{ddNa_2SO_4}=200+160-\left(0,2.98\right)=340,4\left(g\right)\)
\(C\%_{Na_2SO_4}=\dfrac{28,4}{240,4}.100\%\approx8,34\%\)
\(d,PTHH:\)
\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
0,2 0,2
\(m_{CuO}=0,2.80=16\left(g\right)\)
a, \(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
b, \(m_{CuSO_4}=200.16\%=32\left(g\right)\Rightarrow n_{CuSO_4}=\dfrac{32}{160}=0,2\left(mol\right)\)
\(n_{NaOH}=2n_{CuSO_4}=0,4\left(mol\right)\Rightarrow m_{ddNaOH}=\dfrac{0,4.40}{10\%}=160\left(g\right)\)
c, \(n_{Cu\left(OH\right)_2}=n_{Na_2SO_4}=n_{CuSO_4}=0,2\left(mol\right)\)
\(\Rightarrow C\%_{Na_2SO_4}=\dfrac{0,2.142}{200+160-0,2.98}.100\%\approx8,34\%\)
d, \(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
\(n_{CuO}=n_{Cu\left(OH\right)_2}=0,2\left(mol\right)\Rightarrow m_{CuO}=0,2.80=16\left(g\right)\)
\(a,2NaOH+MgSO_4\rightarrow Mg\left(OH\right)_2+Na_2SO_4\\ n_{NaOH}=0,5.1=0,5\left(mol\right)\\ b,n_{Mg\left(OH\right)_2}=\dfrac{0,5}{2}=0,25\left(mol\right)=n_{Na_2SO_4}\\ m_{kt}=m_{Mg\left(OH\right)_2}=58.0,25=14,5\left(g\right)\\ c,V_{ddX}=V_{ddNaOH}+V_{ddMgSO_4}=0,5+0,5=1\left(l\right)\\ C_{MddNa_2SO_4}=\dfrac{0,25}{1}=0,25\left(M\right)\)
Cho 200 g dung dịch chứa 2 muối MgCl2 và CuCL2 tác dụng vừa đủ với 300 g dung dịch NaOH 8 phần trăm . Lọc kết tủa thu được đem nung ở nhiệt độ cao thu đc 16 g hỗn hợp chất rắn . a, Viêt pthh . b , tính nồng độ phần trăm các chất trong dung dịch ban đầu
a) \(MgCl_2+2NaOH\rightarrow Mg\left(OH\right)_2+2NaCl\)
\(CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl\)
\(Mg\left(OH\right)_2\rightarrow MgO+H_2O\)
\(Cu\left(OH\right)_2\rightarrow CuO+H_2O\)
b) \(n_{NaOH}=\dfrac{300.8\%}{40}=0,6\left(mol\right)\)
Gọi x,y lần lượt là số mol MgCl2, CuCl2
\(\left\{{}\begin{matrix}2x+2y=0,6\\40x+80y=16\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)
=> \(C\%_{MgCl_2}=\dfrac{0,2.95}{200}.100=9,5\%\)
\(C\%_{CuCl_2}=\dfrac{0,1.135}{200}.100=6,75\%\)
Ta có: \(n_{CuSO_4}=\dfrac{16}{160}=0,1\left(mol\right)\)
a. \(PTHH:CuSO_4+2NaOH--->Cu\left(OH\right)_2\downarrow+Na_2SO_4\)
b. Theo PT: \(n_{Cu\left(OH\right)_2}=n_{CuSO_4}=0,1\left(mol\right)\)
\(\Rightarrow m_{Cu\left(OH\right)_2}=0,1.98=9,8\left(g\right)\)
c. Theo PT: \(n_{NaOH}=2.n_{CuSO_4}=2.0,1=0,2\left(mol\right)\)
\(\Rightarrow m_{NaOH}=0,2.40=8\left(g\right)\)
\(\Rightarrow C_{\%_{NaOH}}=\dfrac{8}{200}.100\%=4\%\)