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a)
$Zn + 2HCl \to ZnCl_2 + H_2$
b)
n Zn = 13/65 = 0,2(mol)
n HCl = 2n Zn = 0,4(mol)
m HCl = 0,4.36,5 = 14,6(gam)
c)
m dd HCl = 14,6/3,65% = 400(gam)
d)
n H2 = n Zn = 0,2(mol)
V H2 = 0,2.22,4 = 4,48(lít)
\(a) Fe + 2HCl \to FeCl_2 + H_2\\ n_{H_2} = n_{Fe} = \dfrac{16,8}{56} = 0,3(mol)\\ V_{H_2} = 0,3.22,4 = 6,72(lít)\\ b) n_{HCl} = 2n_{Fe} = 0,6(mol)\ \Rightarrow m_{HCl} = 0,6.36,5 = 21,9(gam)\)
(Thiếu C% của HCl nên không tìm được khối lượng dung dịch )
\(c) n_{FeCl_2} = n_{Fe} = 0,3(mol)\\ m_{FeCl_2} = 0,3.127 = 38,1(gam)\)
`a)PTHH:`
`Fe + 2HCl -> FeCl_2 + H_2`
`0,3` `0,6` `0,3` `0,3` `(mol)`
`n_[Fe]=[22,4]/56=0,4(mol)`
`n_[HCl]=0,3.2=0,6(mol)`
Ta có:`[0,4]/1 > [0,6]/2`
`=>Fe` dư
`b)m_[FeCl_2]=0,3.127=38,1(g)`
`c)m_[Fe(dư)]=(0,4-0,3).56=5,6(g)`
\(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)
\(n_{HCl}=0,3.2=0,6\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
Xét: \(\dfrac{0,4}{1}>\dfrac{0,6}{2}\) ( mol )
0,3 0,6 0,3 ( mol )
\(m_{FeCl_2}=0,3.127=38,1\left(g\right)\)
\(m_{Fe\left(dư\right)}=\left(0,4-0,3\right).56=5,6\left(g\right)\)
BTKL: \(m_{Fe}+m_{HCl}=m_{muối}+m_{H_2}\)
\(\Rightarrow m_{H_2}=5,6+7,3-12,7=0,2\left(g\right)\)
PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\n_{H_2SO_4}=\dfrac{49}{98}=0,5\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Axit còn dư
\(\Rightarrow\left\{{}\begin{matrix}n_{H_2}=0,2\left(mol\right)\\n_{H_2SO_4\left(dư\right)}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,2\cdot22,4=4,48\left(l\right)\\m_{H_2SO_4\left(dư\right)}=0,3\cdot98=29,4\left(g\right)\end{matrix}\right.\)
nH2SO4=0,5(mol)
nZn=0,2(mol)
a) PTHH: Zn + H2SO4 -> ZnSO4 + H2
ta có: 0,5/1 > 0,2/1
=> Zn hết, H2SO4 dư, tính theo nZn
b) m(H2SO4 dư)= (0,5-0,2).98=29,4(g)
c) nH2= nZn=0,2(mol)
=>V(H2,đktc)=0,2.22,4=4,48(l)
\(n_{Fe}=\dfrac{5,6}{56}=0,1mol\)
\(n_{HCl}=\dfrac{14,6}{36,5}=0,4mol\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,1 < 0,4 ( mol )
0,1 0,2 0,1 0,1 ( mol )
Chất dư là HCl
\(m_{HCl\left(dư\right)}=\left(0,4-0,2\right).36,5=7,3g\)
\(V_{H_2}=0,1.22,4=2,24l\)
\(m_{FeCl_2}=0,1.127=12,7g\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\\
n_{HCl}=\dfrac{14,6}{36,5}=0,4\left(mol\right)\\
pthh:Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
\(LTL:\dfrac{0,1}{1}< \dfrac{0,4}{1}\)
=> H2SO4 d
\(n_{H_2SO_4\left(pu\right)}=n_{Fe}=0,1\left(mol\right)\\
m_{H_2SO_4\left(d\right)}=\left(0,4-0,1\right).98=29,4g\)
\(n_{H_2}=n_{FeSO_4}=n_{Fe}=0,1\left(mol\right)\)
\(V_{H_2}=0,1.22,4=2,24l\\
m_{FeSO_4}=0,1.152=15,2g\)
PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\\n_{HCl}=0,25\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,1}{1}< \dfrac{0,25}{2}\) \(\Rightarrow\) HCl còn dư, Kẽm p/ứ hết
\(\Rightarrow\left\{{}\begin{matrix}n_{H_2}=0,1\left(mol\right)\\n_{HCl\left(dư\right)}=0,05\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=22,4\cdot0,1=2,24\left(l\right)\\m_{HCl\left(dư\right)}=0,05\cdot36,5=1,825\left(g\right)\end{matrix}\right.\)
nFe = 8,4 : 56 = 0,15 (mol)
n HCl = 3,65 : 36,5 = 0,1 (mol)
pthh : Fe + 2HCl ---> FeCl2 + H2
LTL :
0,15/1 > 0,1 / 2
=> Fe du
nFe(pu ) = nHCl = 0,1 (mol)
=> nFe (d) = nFe(bd ) - nFe(pu ) = 0,15 - 0,1 = 0,05 (mol)
mFe (d) = 0,05. 56 = 2, 8 ( g)