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PTHH: 3Fe + 2O2 =(nhiệt)=> Fe3O4
a) nFe = 5,6 / 56 = 0,1 (mol)
\(\Rightarrow n_{O2}=\frac{0,1.2}{3}=\frac{1}{15}\left(mol\right)\)
Thể tích oxi cần dùng ở điều kiện tiêu chuẩn là:
=> VO2(đktc) = \(\frac{1}{15}.22,4\approx1,5\left(lit\right)\)
b) nFe3O4 = \(\frac{0,1}{3}=\frac{1}{30}\left(mol\right)\)
=> mFe3O4 = \(\frac{1}{30}.232\approx7,73\left(gam\right)\)
\(n_{Fe}=\dfrac{28}{56}=0,5mol\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,5 1 0,5
\(V_{H_2}=0,5\cdot22,4=11,2l\)
\(m_{HCl}=1\cdot36,5=36,5g\)
\(n_{Fe_3O_4}=\dfrac{m_{Fe_3O_4}}{M_{Fe_3O_4}}=\dfrac{23,2}{232}=0,1mol\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
0,3 0,2 0,1 ( mol )
\(m_{Fe}=n_{Fe}.M_{Fe}=0,3.56=16,8g\)
\(V_{O_2}=n_{O_2}.22,4=0,2.22,4=4,48l\)
\(V_{kk}=\dfrac{4,48.100}{20}=22,4l\)
\(2KMnO_4\rightarrow\left(t^o\right)K_2MnO_4+MnO_2+O_2\)
0,4 0,2 ( mol )
\(n_{KMnO_4}=\dfrac{0,4}{85\%}=\dfrac{8}{17}mol\)
\(m_{KMnO_4}=n_{KMnO_4}.M_{KMnO_4}=\dfrac{8}{17}.158=74,3529g\)
PTHH: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
Ta có: \(\left\{{}\begin{matrix}n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\n_{O_2}=\dfrac{12,8}{32}=0,4\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{3}< \dfrac{0,4}{2}\) \(\Rightarrow\) Oxi còn dư, Fe p/ứ hết
\(\Rightarrow n_{O_2\left(dư\right)}=0,4-\dfrac{2}{15}=\dfrac{4}{15}\left(mol\right)\)
+) Theo PTHH: \(\left\{{}\begin{matrix}n_{O_2}=\dfrac{2}{15}\left(mol\right)\\n_{Fe_3O_4}=\dfrac{1}{15}\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}V_{kk}=\dfrac{2}{15}\cdot22,4\cdot5\approx14,93\left(l\right)\\m_{Fe_3O_4}=\dfrac{1}{15}\cdot232\approx15,47\left(g\right)\end{matrix}\right.\)
a, \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b, Ta có: \(n_{Fe}=\dfrac{50,4}{56}=0,9\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=0,6\left(mol\right)\Rightarrow V_{O_2}=0,6.22,4=13,44\left(l\right)\)
c, \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,3\left(mol\right)\Rightarrow m_{Fe_3O_4}=0,3.232=69,6\left(g\right)\)
d, \(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
Theo PT: \(n_{KClO_3}=\dfrac{2}{3}n_{O_2}=0,4\left(mol\right)\Rightarrow m_{KClO_3}=0,4.122,5=49\left(g\right)\)
\(n_{Fe}=\dfrac{m}{M}=\dfrac{50,4}{56}=0,9\left(mol\right)\)
\(a.PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
3 2 1
0,9 0,6 0,3
\(b.V_{O_2}=n.24,79=0,6.24,79=14,874\left(l\right)\)
\(c.m_{Fe_3O_4}=n.M=0,3.\left(56.3+16.4\right)=69,6\left(g\right)\)
\(d.V_{O_2}=14,874\left(l\right)\\ \Rightarrow n_{O_2}=\dfrac{V}{24,79}=\dfrac{14,874}{24,79}=0,6\left(mol\right)\\ PTHH:2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
2 2 3
0,6 0,6 0,9
\(m_{KClO_3}=n.M=0,6.\left(39+35,5+16.3\right)=55,5\left(g\right).\)
a, \(n_{Fe_3O_4}=\dfrac{23,2}{232}=0,1\left(mol\right)\)
PT: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
Theo PT: \(n_{Fe}=3n_{Fe_3O_4}=0,3\left(mol\right)\Rightarrow m_{Fe}=0,3.56=16,8\left(g\right)\)
b, \(n_{O_2}=2n_{Fe_3O_4}=0,2\left(mol\right)\Rightarrow V_{O_2}=0,2.22,4=4,48\left(l\right)\)
\(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
0,3 0,2 0,1
\(n_{Fe_3O_4}=\dfrac{23,2}{232}=0,1\left(mol\right)\)
\(a,m_{Fe}=0,3.56=16,8\left(g\right)\)
\(b,V_{O_2}=0,2.22,4=4,48\left(l\right)\)
3 Fe + 2 O2 ----> Fe3O4
0,9 0,6 0,3
nFe= 50,4/56=0,9 mol
VO2 = 0,6 x 22,4= 13,44 lít
mFe3O4 = 0,3 x232=69,6 g
ok