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PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
Ta có: \(n_{Zn}=\dfrac{9,75}{65}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,3\left(mol\right)\\n_{ZnCl_2}=0,15\left(mol\right)=n_{H_2}\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,15\cdot22,4=3,36\left(l\right)\\m_{ZnCl_2}=0,15\cdot136=20,4\left(g\right)\\C_{M_{HCl}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\end{matrix}\right.\)
\(n_{CH_3COOH}=\dfrac{300\cdot5\%}{60}=0.25\left(mol\right)\)
\(2CH_3COOH+Zn\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
\(0.25........................................................0.125\)
\(V_{H_2}=0.125\cdot22.4=2.8\left(l\right)\)
\(n_{C_2H_5OH}=0.1\cdot2=0.2\left(mol\right)\)
\(CH_3COOH+C_2H_5OH⇌CH_3COOC_2H_5+H_2O\left(ĐK:H_2SO_{4\left(đ\right)},t^0\right)\)
\(0.2......................0.2.....................0.2\)
\(\Rightarrow CH_3COOHdư\)
\(m_{CH_3COOC_2H_5}=0.2\cdot88=17.6\left(g\right)\)
a) n CH3COOH = 300.5%/60 = 0,25(mol)
Zn + 2CH3COOH $\to$ (CH3COO)2Zn + H2
Theo PTHH :
n H2 = 1/2 n CH3COOH = 0,25/2 = 0,125(mol)
V H2 = 0,125.22,4 = 2,8(lít)
b) n C2H5OH = 0,1.2 = 0,2(mol)
\(CH_3COOH + C_2H_5OH \buildrel{{H_2SO_4,t^o}}\over\rightleftharpoons CH_3COOC_2H_5 + H_2O\)
Ta thấy :
n CH3COOH = 0,25 > n C2H5OH = 0,2 => CH3COOH dư
n CH3COOC2H5 = n C2H5OH = 0,2 mol
=> m CH3COOC2H5 = 0,2.88 = 17,6 gam
\(a,PTHH:Na_2CO_3+H_2SO_4\rightarrow Na_2SO_4+H_2O+CO_2\uparrow\\ b,n_{Na_2CO_3}=\dfrac{10,6}{106}=0,1\left(mol\right)\\ \Rightarrow n_{Na_2SO_4}=0,1\left(mol\right)\\ \Rightarrow m_{Na_2SO_4}=0,1\cdot142=14,2\left(g\right)\\ c,n_{CO_2}=n_{Na_2CO_3}=0,1\left(mol\right)\\ \Rightarrow V_{CO_2\left(đktc\right)}=0,1\cdot22,4=2,24\left(l\right)\)
\(d,n_{Ca\left(OH\right)_2}=0,5\cdot0,3=0,15\left(mol\right)\\ PTHH:CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3\downarrow+H_2O\)
Vì \(\dfrac{n_{Ca\left(OH\right)_2}}{1}>\dfrac{n_{CO_2}}{1}\) nên Ca(OH)2 dư, tính theo CO2
\(\Rightarrow n_{CaCO_3}=n_{CO_2}=0,1\left(mol\right)\\ \Rightarrow m_{CaCO_3}=0,1\cdot100\cdot80\%=8\left(g\right)\)
\(2Al+3H_2SO_4 \to Al_2(SO_4)_3+3H_2\\ n_{Al}=0,4(mol)\\ a/\\ n_{H_2}=\frac{3}{2}.0,4=0,6(mol)\\ V_{H_2}=0,6.22,4=13,44(l)\\ b/\\ n_{H_2SO_4}=n_{H_2}=0,6(mol)\\ n_{ddH_2SO_4}=\frac{0,6.98.100}{20}=294(g)\\ c/\\ n_{Al_2(SO_4)_3}=0,2(mol)\\ C\%_{Al_2(SO_4)_3}=\frac{0,2.342}{10,8+294-0,6.2}.100\%=22,52\%\)
a) \(n_{\left(CH_3COO\right)_2Mg}=\dfrac{7,1}{142}=0,05\left(mol\right)\)
PTHH: 2CH3COOH + Mg --> (CH3COO)2Mg + H2
0,1<----------------------0,05------->0,05
=> VH2 = 0,05.22,4 = 1,12 (l)
b) \(C_{M\left(dd.CH_3COOH\right)}=\dfrac{0,1}{0,025}=4M\)
\(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\)
PTHH :
\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\uparrow\)
0,1 0,1 0,1 0,1
\(a,m_{MgSO_4}=0,1.120=12\left(g\right)\)
\(b,V_{H_2}=0,1.22,4=2,24\left(l\right)\)
\(c,m_{ddH_2SO_4}=\dfrac{0,1.98.100}{10}=98\left(g\right)\)
Ta có: \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
a. PTHH: Zn + H2SO4 ---> ZnSO4 + H2
b. Theo PT: \(n_{H_2}=n_{Zn}=0,1\left(mol\right)\)
=> \(V_{H_2}=0,1.22,4=2,24\left(lít\right)\)
c. Theo PT: \(n_{H_2SO_4}=n_{Zn}=0,1\left(mol\right)\)
=> \(m_{H_2SO_4}=0,1.98=9,8\left(g\right)\)
Ta có: \(C_{M_{H_2SO_4}}=\dfrac{9,8}{m_{dd_{H_2SO_4}}}.100\%=25\%\)
=> \(m_{dd_{H_2SO_4}}=39,2\left(g\right)\)
Ta có: \(m_{H_2}=0,1.2=0,2\left(g\right)\)
=> \(m_{dd_{ZnSO_4}}=6,5+39,2-0,2=45,5\left(g\right)\)
Theo PT: \(n_{ZnSO_4}=n_{Zn}=0,1\left(mol\right)\)
=> \(m_{ZnSO_4}=0,1.161=16,1\left(g\right)\)
=> \(C_{\%_{ZnSO_4}}=\dfrac{16,1}{45,5}.100\%=35,4\%\)
a, \(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
b, \(n_{Mg}=\dfrac{4,1}{24}=\dfrac{41}{240}\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{MgSO_4}=n_{Mg}=\dfrac{41}{240}\left(mol\right)\)
\(\Rightarrow V_{H_2}=\dfrac{41}{240}.24,79\approx4,23\left(l\right)\)
c, \(m_{MgSO_4}=\dfrac{41}{240}.120=20,5\left(g\right)\)
\(n_{Mg}=\dfrac{4,1}{24}=\dfrac{41}{210}\left(mol\right)\)
PTHH :
\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\uparrow\)
41/210 41/210 41/210
\(b,V_{H_2}=\dfrac{41}{240}.24,79=4,235\left(l\right)\)
\(c,m_{MgSO_4}=\dfrac{41}{240}.120=20,5\left(g\right)\)