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a)\(n_{H_2}=\dfrac{3,36}{22,4}=0,15mol\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,15 0,3 0,15
\(m_{Zn}=0,15\cdot65=9,75\left(g\right)\)
\(\%m_{Zn}=\dfrac{9,75}{17,85}\cdot100\%=54,62\%\)
\(\%m_{ZnO}=100\%-54,62\%=45,38\%\)
b)\(m_{ZnO}=17,85-9,75=8,1\left(g\right)\Rightarrow n_{ZnO}=\dfrac{8,1}{81}=0,1mol\)
\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
0,1 0,2
\(\Rightarrow\Sigma n_{HCl}=0,3+0,2=0,5mol\)
\(\Rightarrow V=\dfrac{0,5}{1}=0,5l=500ml\)
Đặt: \(n_{Zn}=a\left(mol\right);n_{ZnO}=b\left(mol\right)\left(a,b>0\right)\)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(a.Zn+2HCl\rightarrow ZnCl_2+H_2\\ ZnO+2HCl\rightarrow ZnCl_2+H_2O\\ \Rightarrow\left\{{}\begin{matrix}65a+81b=14,6\\a=0,1\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\\ b.m_{Zn}=0,1.65=6,5\left(g\right)\\ m_{ZnO}=0,1.81=8,1\left(g\right)\\ d.m_{ddHCl}=\dfrac{\left(0,1+0,1\right).2.36,5.100}{7,3}=200\left(g\right)\)
Zn+2HCl->ZnCl2+H2
ZnO+2HCl->ZnCl2+H2O
nH2=0.2(mol)->nZn=0.2(mol).mZn=13(g)
mZnO=21.1-13=8.1(g)
nZnO=0.1(mol)
Tổng nHCl cần dùng:0.2*2+0.1*2=0.6(mol)
mHCl=21.9(g)
C%ddHCl=21.9:200*100=10.95%
n muối=0.2+.1=0.3(mol)
m muối=40.8(g)
C32:
a, \(n_C=\dfrac{2,4}{12}=0,2\left(mol\right)\)
PT: \(C+O_2\underrightarrow{t^o}CO_2\)
Theo PT: \(n_{CO_2}=n_C=0,2\left(mol\right)\Rightarrow V_{CO_2}=0,2.22,4=4,48\left(l\right)\)
b, \(n_{NaOH}=0,3.1=0,3\left(mol\right)\)
\(\Rightarrow\dfrac{n_{NaOH}}{n_{CO_2}}=1,5\) → Pư tạo NaHCO3 và Na2CO3
PT: \(CO_2+NaOH\rightarrow NaHCO_3\)
\(CO_2+2NaOH\rightarrow Na_2CO_3+H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{CO_2}=n_{NaHCO_3}+n_{Na_2CO_3}=0,2\\n_{NaOH}=n_{NaHCO_3}+2n_{Na_2CO_3}=0,3\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}n_{NaHCO_3}=0,1\left(mol\right)\\n_{Na_2CO_3}=0,1\left(mol\right)\end{matrix}\right.\)
⇒ mNaHCO3 = 0,1.84 = 8,4 (g)
mNa2CO3 = 0,1.106 = 10,6 (g)
c, \(C_{M_{NaHCO_3}}=C_{M_{Na_2CO_3}}=\dfrac{0,1}{0,3}=\dfrac{1}{3}\left(M\right)\)
Lần sau bạn đăng tách câu hỏi ra nhé.
C31:
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
b, \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Theo PT: \(n_{Zn}=n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,1.65}{14,6}.100\%\approx44,52\%\\\%m_{ZnO}\approx55,48\%\end{matrix}\right.\)
c, \(n_{ZnO}=\dfrac{14,6-0,1.65}{81}=0,1\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Zn}+2n_{ZnO}=0,4\left(mol\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{0,4.36,5}{10\%}=146\left(g\right)\)
Tiếp bài của creeper nhé:
c. Ta có: \(n_{ZnO}=\dfrac{4,86}{81}=0,06\left(mol\right)\)
Theo PT(1): \(n_{HCl}=2.n_{ZnO}=2.0,06=0,12\left(mol\right)\)
Theo PT(2): \(n_{HCl}=2.n_{Zn}=2.0,1=0,2\left(mol\right)\)
=> \(n_{HCl}=0,12+0,2=0,32\left(mol\right)\)
=> \(m_{HCl}=0,32.36,5=11,68\left(g\right)\)
Ta có: \(C_{\%_{HCl}}=\dfrac{11,68}{m_{dd_{HCl}}}.100\%=12\%\)
=> \(m_{dd_{HCl}}=\dfrac{292}{3}\left(g\right)\)
Theo đề, ta có:
\(D=\dfrac{\dfrac{292}{3}}{V_{dd_{HCl}}}=1,2\)(g/ml)
=> \(V_{dd_{HCl}}=81,1\left(ml\right)\)
a,\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH: Zn + 2HCl → ZnCl2 + H2
Mol: 0,2 0,4 0,2
\(\Rightarrow\%m_{Zn}=\dfrac{0,2.65.100\%}{21,1}=61,61\%;\%m_{ZnO}=100-61,61=38,39\%\)
b,\(n_{ZnO}=\dfrac{21,1-13}{81}=0,1\left(mol\right)\)
PTHH: ZnO + 2HCl → ZnCl2 + H2O
Mol: 0,1 0,2
\(m_{ddHCl}=\dfrac{\left(0,2+0,4\right).36,5.100\%}{7,3\%}=300\left(g\right)\)
c,
PTHH: Zn + H2SO4 → ZnSO4 + H2
Mol: 0,2 0,2
PTHH: ZnO + H2SO4 → ZnSO4 + H2O
Mol: 0,1 0,1
\(n_{H_2SO_4}=0,2+0,1=0,3\left(mol\right)\Rightarrow V_{ddH_2SO_4}=\dfrac{0,3}{0,5}=0,6\left(l\right)=600\left(ml\right)\)
\(m_{ddH_2SO_4}=600.1,12=672\left(g\right)\)
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH: Zn + 2HCl -->ZnCl2 + H2
____0,2<----------------------0,2
=> mZn = 0,2.65 = 13 (g)
mCu = mrắn không tan = 19,5 (g)
\(\left\{{}\begin{matrix}\%Zn=\dfrac{13}{13+19,5}.100\%=40\%\\\%Cu=\dfrac{19,5}{13+19,5}.100\%=60\%\end{matrix}\right.\)
`n_(H_2)=4,48/22,4=0,2 (mol)`
Ta có PTHH: `Zn+2HCl --> ZnCl_2 +H_2`
Theo PT: `1`--------------------------------`1`
Theo đề: `0,2`------------------------------`0,2`
`m_(Zn)=0,2.65=13(g)`
Vì `Cu` không phản ứng với `HCl` nên `m_(chất rắn không tan)=m_(Cu)=19,5(gam)`
`%Zn=13/(13+19,5) .100%=40%`
`%Cu=100%-40%=60%`
a) PTHH : \(Zn+H_2SO_4-->ZnSO_4+H_2\uparrow\) (1)
\(ZnO+H_2SO_4-->ZnSO_4+H_2O\) (2)
b) Theo pthh (1) : \(n_{Zn}=n_{H2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
=> \(m_{Zn}=0,1.65=6,5\left(g\right)\)
=> \(m_{ZnO}=22,7-6,5=16,2\left(g\right)\)
c) \(ZnO=\dfrac{16,2}{81}=0,2\left(mol\right)\)
Theo pthh (1) và (2) : \(\Sigma n_{H2SO4}=n_{Zn}+n_{ZnO}=0,1+0,2=0,3\left(mol\right)\)
=> \(C_{M\left(ddH2SO4\right)}=\dfrac{0,3}{0,1}=1,5M\)
a) PTHH : Zn+H2SO4−−>ZnSO4+H2↑Zn+H2SO4−−>ZnSO4+H2↑ (1)
ZnO+H2SO4−−>ZnSO4+H2OZnO+H2SO4−−>ZnSO4+H2O (2)
b) Theo pthh (1) : nZn=nH2=2,2422,4=0,1(mol)nZn=nH2=2,2422,4=0,1(mol)
=> mZn=0,1.65=6,5(g)mZn=0,1.65=6,5(g)
=> mZnO=22,7−6,5=16,2(g)mZnO=22,7−6,5=16,2(g)
c) ZnO=16,281=0,2(mol)ZnO=16,281=0,2(mol)
Theo pthh (1) và (2) : ΣnH2SO4=nZn+nZnO=0,1+0,2=0,3(mol)ΣnH2SO4=nZn+nZnO=0,1+0,2=0,3(mol)
=> CM(ddH2SO4)=0,30,1=1,5M
tích đúng đê
a, \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH: Zn + 2HCl → ZnCl2 + H2
Mol: 0,2 0,2
(do Cu ko tác dụng với HCl loãng)
b, \(m_{Zn}=0,2.65=13\left(g\right)\)
\(m_{Cu}=19,4-13=6,4\left(g\right)\)
