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nAl = 5.4 / 27 = 0.2 (mol)
2Al + 6HCl => 2AlCl3 + 3H2
0.2......0.6............0.2.......0.3
a) VH2 = 0.3 * 22.4 = 6.72 (l)
b) mAlCl3 = 0.2 * 133.5 = 26.7 (g)
c) VddHCl = 0.6 / 1.5 = 0.4 (l)
d) CMAlCl3 = 0.2 / 0.4 = 0.5 (M)
PTHH: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,6\left(mol\right)\\n_{AlCl_3}=0,2\left(mol\right)\\n_{H_2}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\\m_{AlCl_3}=0,2\cdot133,5=26,7\left(g\right)\\V_{HCl}=\dfrac{0,6}{1,5}=0,4\left(l\right)=400\left(ml\right)\\C_{M_{AlCl_3}}=\dfrac{0,2}{0,4}=0,5\left(M\right)\end{matrix}\right.\)
PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)
Ta có: \(n_{H_2SO_4}=0,3\cdot1=0,3\left(mol\right)=n_{Zn}=n_{ZnSO_4}=n_{H_2}\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Zn}=0,3\cdot65=19,5\left(g\right)\\V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\\C_{M_{ZnSO_4}}=\dfrac{0,3}{0,3}=1\left(M\right)\end{matrix}\right.\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
0,3 0,3 0,3 0,3
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
\(m_{Fe}=0,3.56=16,8\left(g\right)\)
\(C_{M_{H_2SO_4}}=\dfrac{n}{V}=\dfrac{0,3}{0,2}=1,5M\)
\(C_{M_{FeSO_4}}=\dfrac{n}{V}=\dfrac{0,3}{0,2}=1,5M\)
PTHH: Fe + H₂SO₄ --> FeSO₄ + H₂
200ml = 0,2 lít.
a) Số mol H₂: nH₂ = 6,72 ÷ 22,4 = 0,3 mol
Theo PTHH => Số mol Fe: nFe = 0,3 mol
=> Khối lượng Fe: mFe = 16,8g
b) Số mol H₂SO₄: nH₂SO₄ = 0,3 mol
Nồng độ mol dd: CM = 0,3 ÷ 0,2 = 1,5M
\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{FeCl_2}=n_{H_2}=n_{Fe}=0,15\left(mol\right)\\ n_{HCl}=0,15.2=0,3\left(mol\right)\\ a,m_{FeCl_2}=127.0,15=19,05\left(g\right)\\ b,V_{H_2\left(đktc\right)}=0,15.22,4=3,36\left(l\right)\\ c,C_{MddHCl}=\dfrac{0,3}{0,02}=15\left(M\right)\)
Sửa lại câu c .
\(n_{H_2SO_4}=\dfrac{49.40}{100}:98=0,2\left(mol\right)\)
\(PTHH:\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
trc p/u : 0,3 0,2
p/u : 0,2 0,2 0,2 0,2
sau : 0,1 0 0,2 0,2
-> Fe dư
\(m_{ddFeSO_4}=0,3.56+49-0,4=65,4\left(g\right)\) ( ĐLBTKL )
\(m_{FeSO_4}=0,2.152=30,4\left(g\right)\)
\(C\%=\dfrac{30,4}{65,4}.100\%\approx46,48\%\)
PTHH :
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
0,3 0,3 0,3 0,3
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
\(a,m_{Fe}=0,3.56=16,8\left(g\right)\)
\(b,C_M=\dfrac{n}{V}=\dfrac{0,3}{0,2}=1,5M\)
\(c,n_{H_2SO_4}=\dfrac{\dfrac{49.40}{100}}{98}=0,2\left(mol\right)\)
\(\rightarrow n_{FeSO_4}=n_{H_2SO_4}=0,2\left(mol\right)\)
\(m_{FeSO_4}=0,2.152=30,4\left(g\right)\)
\(m_{ddFeSO_4}=49+\left(0,2.56\right)-0,2.2=59,8\left(g\right)\)( định luật bảo toàn khối lượng )
\(C\%=\dfrac{30,4}{59,8}.100\%\approx50,84\%\)
a,\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right);n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: Fe + 2HCl → FeCl2 + H2
Mol: 0,15 0,3
Ta có: \(\dfrac{0,2}{1}>\dfrac{0,15}{1}\) ⇒ H2 pứ hết,Fe dư
\(V_{H_2}=3,36\left(l\right)\) (đề cho)
b, ko tính đc k/lg dd ,chỉ tính đc thể tích dd
\(V_{ddHCl}=\dfrac{0,2}{1}=0,2\left(l\right)=200\left(ml\right)\)
a, \(MgO+H_2SO_4\rightarrow MgSO_4+H_2O\)
b, Ta có: \(m_{H_2SO_4}=200.9,8\%=19,6\left(g\right)\)
\(\Rightarrow n_{H_2SO_4}=\dfrac{19,6}{98}=0,2\left(mol\right)\)
Theo PT: \(n_{MgO}=n_{MgSO_4}=n_{H_2SO_4}=0,2\left(mol\right)\)
\(\Rightarrow m_{MgO}=0,2.40=8\left(g\right)\)
c, Ta có: m dd sau pư = 8 + 200 = 208 (g)
\(\Rightarrow C\%_{MgSO_4}=\dfrac{0,2.120}{208}.100\%\approx11,54\%\)
\(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\)
\(m_{HCl}=\dfrac{150.18,25}{100}=27,375\left(g\right)\)
\(n_{HCl}=\dfrac{27,375}{36,5}=0,75\left(mol\right)\)
PTHH :
\(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
trc p/u : 0,3 0,75
p/u: 0,3 0,6 0,3 0,3
sau p/u : 0 0,15 0,3 0,3
---> Sau p/ư HCl dư
\(a,V_{H_2}=0,3.22,4=6,72\left(l\right)\)
\(b,m_{ddHCl}=0,6.36,5=21,9\left(g\right)\)
\(c,m_{ZnCl_2}=0,3.136=40,8\left(g\right)\)
\(m_{ddZnCl_2}=19,5+150-\left(0,3.2\right)=168,9\left(g\right)\)
\(C\%=\dfrac{40,8}{168,9}.100\%\approx24,16\%\)
nH2SO4 = 1 . 0,3 = 0,3 mol
Pt: Fe + H2SO4 --> FeSO4 + H2
...0,3........0,3.............0,3.........0,3
mFe pứ = 0,3 . 56 = 16,8 (g)
VH2 thoát ra = 0,3 . 22,4 = 6,72 (lít)
CM FeSO4 = \(\dfrac{0,3}{0,3}=1M\)