Hãy nhập câu hỏi của bạn vào đây, nếu là tài khoản VIP, bạn sẽ được ưu tiên trả lời.
Gọi số mol FeO, Fe2O3 trong mỗi phần là a, b (mol)
=> 72a + 160b = 39,2
P1:
PTHH: FeO + 2HCl --> FeCl2 + H2O
a---------------->a
Fe2O3 + 3HCl --> 2FeCl3 + 3H2O
b-------------------->2b
=> 127a + 325b = 77,7
=> a = 0,1 (mol); b = 0,2 (mol)
\(\left\{{}\begin{matrix}\%m_{FeCl_2}=\dfrac{0,1.127}{77,7}.100\%=16,345\%\\\%m_{FeCl_3}=\dfrac{0,4.162,5}{77,7}.100\%=83,655\%\end{matrix}\right.\)
P2: \(\left\{{}\begin{matrix}FeO:0,1\left(mol\right)\\Fe_2O_3:0,2\left(mol\right)\end{matrix}\right.\)
Gọi \(\left\{{}\begin{matrix}n_{HCl}=x\left(mol\right)\\n_{H_2SO_4}=y\left(mol\right)\end{matrix}\right.\)
Muối khan gồm \(\left\{{}\begin{matrix}Fe^{3+}:0,4\left(mol\right)\\Fe^{2+}:0,1\left(mol\right)\\Cl^-:x\left(mol\right)\\SO_4^{2-}:y\left(mol\right)\end{matrix}\right.\)
Bảo toàn điện tích => x + 2y = 1,4
mmuối = (0,4 + 0,1).56 + 35,5x + 96y = 83,95
=> 35,5x + 96y = 55,95
=> \(\left\{{}\begin{matrix}x=0,9\\y=0,25\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}C_{M\left(HCl\right)}=\dfrac{0,9}{0,5}=1,8M\\C_{M\left(H_2SO_4\right)}=\dfrac{0,25}{0,5}=0,5M\end{matrix}\right.\)
\(a,m_{P1}=m_{P2}=\dfrac{78,4}{2}=39,2\left(g\right)\\ Đặt:n_{FeO\left(tổng\right)}=2a\left(mol\right);n_{Fe_2O_3\left(tổng\right)}=2b\left(mol\right)\left(a,b>0\right)\\ -Xét.phần.1:\\ PTHH:FeO+2HCl\rightarrow FeCl_2+H_2O\\ Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\\ \Rightarrow\left\{{}\begin{matrix}72a+160b=39,2\\127a+162,5.2.b=77,7\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,2\end{matrix}\right.\\ \%m_{FeO}=\dfrac{0,1.72}{0,1.72+0,2.160}.100\approx18,367\%\\ \Rightarrow\%m_{Fe_2O_3}\approx81,633\%\\ \)
\(b,-Xét.phần.2:m_{muối}=m_{Fe}+m_{Cl^-}+m_{SO^{2-}_4}\left(1\right)\\ Đặt:r=n_{HCl}\left(mol\right);s=n_{H_2SO_4}\left(mol\right)\left(r,s>0\right)\\ \left(1\right)\Leftrightarrow56.\left(0,1+0,2.2\right)+35,5r+96s=83,95\\ \Leftrightarrow35,5r+96s=55,95\left(2\right)\\ Mặt.khác,BTĐT:n_{Cl^-}+2.n_{SO^{2-}_4}=2.n_{Fe^{2+}}+3.n_{Fe^{3+}}\\ \Leftrightarrow r+2s=2.0,1+3.0,2.2\\ \Leftrightarrow r+s=1,4\left(3\right)\\ \left(2\right),\left(3\right)\Rightarrow\left\{{}\begin{matrix}r+2s=1,4\\35,5r+96s=55,95\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}r=0,9\\s=0,25\end{matrix}\right.\\ \Rightarrow C_{MddHCl}=\dfrac{r}{0,5}=\dfrac{0,9}{0,5}=1,8\left(M\right)\\ C_{MddH_2SO_4}=\dfrac{s}{0,5}=\dfrac{0,25}{0,5}=0,5\left(M\right)\)
Câu 1:
Ta có: \(n_{H_2SO_4}=0,25.1=0,25\left(mol\right)\)
PT: \(Na_2CO_3+H_2SO_4\rightarrow Na_2SO_4+H_2O+CO_2\)
\(CaCO_3+H_2SO_4\rightarrow CaSO_4+H_2O+CO_2\)
\(MgCO_3+H_2SO_4\rightarrow MgSO_4+H_2O+CO_2\)
Theo PT, có: \(n_{H_2O}=n_{CO_2}=n_{H_2SO_4}=0,25\left(mol\right)\)
\(\Rightarrow V_{CO_2}=0,25.22,4=5,6\left(l\right)\)
Theo ĐLBT KL, có: mhh + mH2SO4 = m muối + mH2O + mCO2
⇒ m muối = mhh + mH2SO4 - mH2O - mCO2
= 25,2 + 0,25.98 - 0,25.18 - 0,25.44
= 34,2 (g)
Bạn tham khảo nhé!
Câu 2:
Ta có: \(n_{H_2SO_4}=0,5\cdot0,75=0,375\left(mol\right)=n_{H_2O}\)
\(\Rightarrow\left\{{}\begin{matrix}m_{H_2SO_4}=0,375\cdot98=36,75\left(g\right)\\m_{H_2O}=0,375\cdot18=6,75\left(g\right)\end{matrix}\right.\)
Bảo toàn khối lượng: \(m_{oxit}=m_{muối}+m_{H_2O}-m_{H_2SO_4}=28,5\left(g\right)\)
\(2Al+6HCl\to 2AlCl_3+3H_2\\ Fe+2HCl\to FeCl_2+H_2\\ n_{HCl}=0,2.4=0,8(mol)\\ \Rightarrow \begin{cases} 56.n_{Fe}+27.n_{Al}=22\\ 2.n_{Fe}+3.n_{Al}=0,8 \end{cases}\Rightarrow \begin{cases} n_{Fe}=0,39(mol)\\ n_{Al}=0,007(mol) \end{cases}\\ \Rightarrow \begin{cases} \%m_{Fe}=\dfrac{0,39.56}{22}.100\%=99,27\%\\ \%m_{Al}=100\%-99,27\%=0,73\% \end{cases}\)
Bài 1:
nHCl=0,08(mol)
nH2O=0,8/2=0,04(mol)
=>mO(trong H2O)= mO(trong oxit)=0,04. 16= 0,64(g)
=>m(Fe,Mg trong oxit)= 5 - 0,64= 4,36(g)
=> m(muối)= m(Fe,Mg) + mCl- = 4,36+ 0,08.35,5=7,2(g)
Bài 2:
nHCl=0,05.2=0,1(mol) => nCl- =0,1(mol) => mCl- = 0,1.35,5=3,55(g)
3,55> 3,071 => Em coi lại đề
Bài 3 em cũng xem lại đề hé
a,Fe + 2HCl → FeCl + H2 (1)
FeO + 2HCl → FeCl + H2O (2)
nH2 = 3,36/ 22,4 = 0,15 ( mol)
Theo (1) nH2 = nFe = 0,15 ( mol)
mFe = 0,15 x 56 = 8.4 (g)
m FeO = 12 - 8,4 = 3,6 (g)
a, \(n_{H_2}=\frac{3,36}{22,4}=0,15\left(mol\right)\)
\(Fe+2HCl->FeCl_2+H_2\left(1\right)\)
\(FeO+2HCl->FeCl_2+H_2O\left(2\right)\)
theo (1) \(n_{Fe}=n_{H_2}=0,15\left(mol\right)\)
=> \(m_{Fe}=0,15.56=8,4\left(g\right)\)
=> \(m_{FeO}=12-8,4=3,6\left(g\right)\)
ta thấy : nFe =nH2 = 0,15
=> mFe =0,15 x 56 = 8,4g
%Fe=8,4/12 x 100 = 70%
=>%FeO = 100 - 70 = 30%
b) BTKLra mdd tìm mct of HCl
c) tìm mdd sau pứ -mH2 nha bạn
Giả sử trong mỗi phần có: \(\left\{{}\begin{matrix}n_{Fe}=a\left(mol\right)\\n_{Cu}=b\left(mol\right)\\n_{Zn}=c\left(mol\right)\\n_O=d\left(mol\right)\end{matrix}\right.\)
=> 56a + 64b + 65c + 16d = 32,21
P1:
nO = nH2O = d (mol)
=> nHCl = 2d (mol)
Theo ĐLBTKL: mrắn bđ + mHCl = mmuối + mH2O
=> 32,21 + 73d = 59,16 + 18d
=> d = 0,49 (mol)
P2:
Gọi số mol HCl, H2SO4 là a, b (mol)
nH2O = nO = 0,49 (mol)
Bảo toàn H: a + 2b = 0,98 (1)
Theo ĐLBTKL: mrắn bđ + mHCl + mH2SO4 = mmuối + mH2O
=> 32,21 + 36,5a + 98b = 65,41 + 0,49.18
=> 36,5a + 98b = 42,02 (2)
(1)(2) => a = 0,48 (mol); b = 0,25 (mol)
=> \(\left\{{}\begin{matrix}C_{M\left(HCl\right)}=\dfrac{0,48}{1}=0,48M\\C_{M\left(H_2SO_4\right)}=\dfrac{0,25}{1}=0,25M\end{matrix}\right.\)