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PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
Ta có: \(n_{Zn}=\dfrac{9,75}{65}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,3\left(mol\right)\\n_{ZnCl_2}=0,15\left(mol\right)=n_{H_2}\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,15\cdot22,4=3,36\left(l\right)\\m_{ZnCl_2}=0,15\cdot136=20,4\left(g\right)\\C_{M_{HCl}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\end{matrix}\right.\)
\(n_{H_2}=\dfrac{2,479}{22,4}=\dfrac{2479}{22400}mol\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Theo pt ta có: \(n_{Zn}=n_{H_2}=\dfrac{2479}{22400}mol\)\(\approx0,11mol\)
\(\Rightarrow m_{Zn}\approx7,2g\)
\(n_{HCl}=2n_{H_2}=0,22mol\) \(\Rightarrow C_{M_{HCl}}=\dfrac{0,22}{0,1}=2,2M\)
\(m_{CH_3COOH}=\dfrac{80.9}{100}=7,2\left(g\right)\)
\(n_{CH_3COOH}=\dfrac{7,2}{60}=0,12\left(mol\right)\)
PTHH :
\(15CH_3COOH+10NaHCO_3\rightarrow10CH_3COONa+2H_2O+20CO_2\uparrow\)
0,12 0,08 0,08 0,016 0,16
\(a,m_{NaHCO_3}=84.0,08=6,72\left(g\right)\)
\(m_{ddNaHCO_3}=\dfrac{6,72.100}{4,2}=160\left(g\right)\)
\(b,m_{CH_3COONa}=0,08.82=6,56\left(g\right)\)
\(m_{H_2O}=0,016.18=0,288\left(g\right)\)
\(m_{CO_2}=0,16.44=7,04\left(g\right)\)
\(m_{ddCH_3COONa}=80+160-0,288-7,04=232,672\left(g\right)\)
\(C\%=\dfrac{6,56}{232,672}\approx2,82\%\)
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
PTHH: Mg + 2HCl → MgCl2 + H2
Mol: 0,2 0,4 0,2
\(V_{H_2}=0,2.24,79=4,958\left(l\right)\)
\(m_{HCl}=0,4.36,5=14,6\left(g\right)\Rightarrow m_{ddHCl}=\dfrac{14,6.100\%}{20\%}=73\left(g\right)\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\\ n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\\ n_{H_2}=n_{Mg}=0,2\left(mol\right)\\ V_{H_2\left(25^oC,1bar\right)}=0,2.22,4=4,48\left(l\right)\\ n_{HCl}=0,2.2=0,4\left(mol\right)\\ m_{HCl}=0,4.36,5=14,6\left(g\right)\)
\(a.Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\ n_{Zn}=\dfrac{4,55}{65}=0,07\left(mol\right)\\ n_{H_2}=n_{Zn}=0,07\left(mol\right)\\ \Rightarrow V_{H_2}=0,07.22,4=1,568\left(l\right)\\ b.n_{HCl}=2n_{Zn}=0,14\left(mol\right)\\ \Rightarrow CM_{HCl}=\dfrac{0,14}{0,2}=0,7M\\ c.n_{ZnCl_2}=n_{Zn}=0,07\left(mol\right)\\ \Rightarrow m_{ZnCl_2}=0,07.136=9,52\left(g\right)\)
Bài 9 :
\(n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\)
\(CuO+2HCl\rightarrow CuCl_2+H_2O\)
0,05--->0,1-------->0,05
a) \(C_{MddHCl}=\dfrac{0,1}{0,1}=1\left(M\right)\)
b) \(m_{CuCl2}=0,05.135=6,75\left(g\right)\)
c) \(C_{MCuCl2}=\dfrac{0,05}{0,1}0,5\left(M\right)\)
Câu 10 :
\(n_{FeO}=\dfrac{3,6}{72}=0,05\left(mol\right)\)
\(FeO+2HCl\rightarrow FeCl_2+H_2O\)
0,05-->0,1------->0,05
\(m_{ddHCl}=\dfrac{0,1.36,5}{10\%}100\%=36,5\left(g\right)\)
\(m_{ddspu}=3,6+36,5=40,1\left(g\right)\)
\(C\%_{FeCl2}=\dfrac{0,05.127}{40,1}.100\%=15,84\%\)
n Ba(OH)2 = 2.0,2=0,4 mol
\(Ba\left(OH\right)_2+SO_2->BaSO_3+H_2O\)
0,4 ................0,4...........0,4
m BaSO3 = 0,4. ( 138+32+16.3)=87,2 g
v SO2 = 0,4.22,4=8,96 lít
m BaSO3 = 0,4. ( 137+32+16.3)=86,8 g
xin lũi nha mình nhìn nhầm bạn thông cảm
PTHH: \(Na_2SO_3+2HCl\rightarrow2NaCl+H_2O+SO_2\uparrow\)
Ta có: \(n_{SO_2}=\dfrac{2,479}{22,4}=\dfrac{2479}{22400}\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{Na_2SO_3}=\dfrac{2479}{22400}\left(mol\right)\\n_{HCl}=\dfrac{2479}{11200}\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Na_2SO_3}=\dfrac{2479}{22400}\cdot126\approx13,94\left(g\right)\\C_{M_{HCl}}=\dfrac{\dfrac{2479}{11200}}{0,25}\approx0,89\left(M\right)\end{matrix}\right.\)
cảm ơn bạn nhiều