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Bài 14:
Ta có: \(n_{BaCO_3}=\dfrac{39,4}{197}=0,2\left(mol\right)\)
PT: \(BaCO_3+2HCl\rightarrow BaCl_2+CO_2+H_2O\)
a, \(n_{CO_2}=n_{BaCO_3}=0,2\left(mol\right)\Rightarrow V_{CO_2}=0,2.24,79=4,958\left(l\right)\)
b, Sửa đề: tính khối lượng dung dịch HCl → tính nồng độ % dd HCl.
\(n_{HCl}=2n_{BaCO_3}=0,4\left(mol\right)\Rightarrow m_{ddHCl}=\dfrac{0,4.36,5}{100}.100\%=14,6\%\)
c, \(n_{BaCl_2}=n_{BaCO_3}=0,2\left(mol\right)\)
Ta có: m dd sau pư = 39,4 + 100 - 0,2.44 = 130,6 (g)
\(\Rightarrow C\%_{BaCl_2}=\dfrac{0,2.208}{130,6}.100\%\approx31,85\%\)
Bài 12:
Ta có: \(n_{MgCO_3}=\dfrac{25,2}{84}=0,3\left(mol\right)\)
PT: \(MgCO_3+2HCl\rightarrow MgCl_2+CO_2+H_2O\)
a, Theo PT: \(n_{CO_2}=n_{MgCO_3}=0,3\left(mol\right)\)
\(\Rightarrow V_{CO_2}=0,3.24,79=7,437\left(l\right)\)
b, Ta có: m dd sau pư = 25,2 + 200 - 0,3.44 = 212 (g)
Theo PT: \(n_{MgCl_2}=n_{MgCO_3}=0,3\left(mol\right)\)
\(\Rightarrow C\%_{MgCl_2}=\dfrac{0,3.95}{212}.100\%\approx13,44\%\)
Bài 13:
Ta có: \(n_{CaCO_3}=\dfrac{10}{100}=0,1\left(mol\right)\)
PT: \(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)
1. \(n_{CO_2}=n_{CaCO_3}=0,1\left(mol\right)\) \(\Rightarrow V_{CO_2}=0,1.24,79=2,479\left(l\right)\)
2. \(n_{HCl}=2n_{CaCO_3}=0,2\left(mol\right)\Rightarrow m_{ddHCl}=\dfrac{0,2.36,5}{7,3\%}=100\left(g\right)\)
3. Ta có: m dd sau pư = 10 + 100 - 0,1.44 = 105,6 (g)
Theo PT: \(n_{CaCl_2}=n_{CaCO_3}=0,1\left(mol\right)\)
\(\Rightarrow C\%_{CaCl_2}=\dfrac{0,1.111}{105,6}.100\%\approx10,51\%\)
a) 2Al+6HCl→→2AlCl3+3H2
b)
nAl=10,8\27=0,4(mol)
nAlCl3=nAl=0,4(mol)
mAlCl3=0,4.133,5=53,4(g)
c)
nH2=3\2nAl=0,6(mol)
VH2=22,4.0,6=13,44(l)
d) n HCl=0,4.6\2=1,2 mol
=>Cm HCl=1,2\0,1=12M
\(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\)
a) Pt : \(2Al+6HCl\rightarrow2AlCl_3+3H_2|\)
2 6 2 3
0,4 1,2 0,4 0,6
b) \(n_{H2}=\dfrac{0,4.3}{2}=0,6\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,6.24,79=14,874\left(l\right)\)
c) \(n_{AlCl3}=\dfrac{0,6.2}{3}=0,4\left(mol\right)\)
⇒ \(m_{AlCl3}=0,4.133,5=53,4\left(g\right)\)
d) \(n_{HCl}=\dfrac{0,4.6}{2}=1,2\left(mol\right)\)
100ml = 0,1l
\(C_{M_{ddHCl}}=\dfrac{1,2}{0,1}=12\left(M\right)\)
Chúc bạn học tốt
\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
1 1 1 1
0,3 0,3 0,3 0,3
\(n_{Mg}=\dfrac{7,2}{24}=0,3\left(mol\right)\)
a). \(n_{H2}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)
⇒\(V_{H2}=n.22,4=0,3.22,4=6,72\left(l\right)\)
b). \(80ml=0,08l\)
\(n_{H2SO4}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)
→\(C_M=\dfrac{n}{V}=\dfrac{0,3}{0,08}=3,75\left(M\right)\)
c). \(n_{MgSO4}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)
\(V_{MgSO4}=n.22,4=0,3.22,4=6,72\left(l\right)\)
→\(C_M=\dfrac{n}{V}=\dfrac{0,3}{6,72}=0,04\left(M\right)\)
d). \(MgSO_4+Ba\left(OH\right)_2\rightarrow Mg\left(OH\right)_2+BaSO_4\downarrow\)
1 1 1 1
0,3 0,3 0,3
\(n_{BaSO4\uparrow}=\dfrac{0,3.1}{1}\)=0,3(mol)
→\(m_{BaSO4\downarrow}=n.M=0,3.233=69,9\left(g\right)\)
\(n_{Ba\left(OH\right)_2}=\dfrac{0,3.1}{1}\)=0,3(mol)
\(\rightarrow V_{ddBa\left(OH\right)_2}=\dfrac{n}{C_M}=\dfrac{0,3}{1,6}=0,1875\left(l\right)\)
PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
Ta có: \(n_{Zn}=\dfrac{9,75}{65}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,3\left(mol\right)\\n_{ZnCl_2}=0,15\left(mol\right)=n_{H_2}\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,15\cdot22,4=3,36\left(l\right)\\m_{ZnCl_2}=0,15\cdot136=20,4\left(g\right)\\C_{M_{HCl}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\end{matrix}\right.\)
Bài 8:
\(n_{H_2}=\dfrac{7,437}{24,79}=0,3\left(mol\right)\)
PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
_____0,2______0,6_____0,2____0,3 (mol)
a, \(m_{Al}=0,2.27=5,4\left(g\right)\)
b, \(C_{M_{HCl}}=\dfrac{0,6}{0,3}=2\left(M\right)\)
c, \(C_{M_{AlCl_3}}=\dfrac{0,2}{0,2}=1\left(M\right)\)
Bài 9:
Ta có: \(n_{H_2}=\dfrac{2,479}{24,79}=0,1\left(mol\right)\)
PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(MgO+2HCl\rightarrow MgCl_2+H_2O\)
a, \(n_{Mg}=n_{H_2}=0,1\left(mol\right)\Rightarrow m_{Mg}=0,1.24=2,4\left(g\right)\)
\(\Rightarrow m_{MgO}=8,4-2,4=6\left(g\right)\)
b, \(n_{MgO}=\dfrac{6}{40}=0,15\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Mg}+2n_{MgO}=0,5\left(mol\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{0,5.36,5}{3,65\%}==500\left(g\right)\)
Bài 9 :
\(n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\)
\(CuO+2HCl\rightarrow CuCl_2+H_2O\)
0,05--->0,1-------->0,05
a) \(C_{MddHCl}=\dfrac{0,1}{0,1}=1\left(M\right)\)
b) \(m_{CuCl2}=0,05.135=6,75\left(g\right)\)
c) \(C_{MCuCl2}=\dfrac{0,05}{0,1}0,5\left(M\right)\)
Câu 10 :
\(n_{FeO}=\dfrac{3,6}{72}=0,05\left(mol\right)\)
\(FeO+2HCl\rightarrow FeCl_2+H_2O\)
0,05-->0,1------->0,05
\(m_{ddHCl}=\dfrac{0,1.36,5}{10\%}100\%=36,5\left(g\right)\)
\(m_{ddspu}=3,6+36,5=40,1\left(g\right)\)
\(C\%_{FeCl2}=\dfrac{0,05.127}{40,1}.100\%=15,84\%\)
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