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Fe + 2HCl -> FeCl2 + H2
nFe = 5,6/56 = 0,1 mol
=>nH2 = 0,1 mol
=> VH2= 0,1*22,4= 2,24 lít
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PTHH: Fe + 2HCl ---> FeCl2 + H2
0,1-->0,2------------------>0,1
=> \(\left\{{}\begin{matrix}m_{ddHCl}=\dfrac{0,2.36,5}{15\%}=\dfrac{146}{3}\left(g\right)\\V_{H_2}=0,1.22,4=4,48\left(l\right)\end{matrix}\right.\)
a.b.
\(n_{Fe}=\dfrac{2,8}{56}=0,05mol\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,05 0,1 0,05 ( mol )
\(V_{H_2}=0,05.22,4=1,12l\)
\(m_{HCl}=0,1.36,5=3,65g\)
c.
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,05 0,05 ( mol )
\(m_{Cu}=0,05.64=3,2g\)
\(n_{Cu}=\dfrac{6,4}{64}=0,1mol\)
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,1 0,1 ( mol )
\(\left\{{}\begin{matrix}m_{CuO}=0,1.80=8g\\m_{FeO}=12-8=4g\end{matrix}\right.\)
a)
FeO + H2 --to--> Fe + H2O
CuO + H2 --to--> Cu + H2O
b) \(n_{Cu}=\dfrac{6,4}{64}=0,1\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
0,1<--0,1<-----0,1
=> \(m_{FeO}=12-0,1.80=4\left(g\right)\)
=> \(n_{FeO}=\dfrac{4}{72}=\dfrac{1}{18}\left(mol\right)\)
FeO + H2 --to--> Fe + H2O
\(\dfrac{1}{18}\)-->\(\dfrac{1}{18}\)----->\(\dfrac{1}{18}\)
=> \(V_{H_2}=\left(0,1+\dfrac{1}{18}\right).22,4=\dfrac{784}{225}\left(l\right)\)
c) \(m_{Fe}=\dfrac{1}{18}.56=\dfrac{28}{9}\left(g\right)\)
d) \(\left\{{}\begin{matrix}m_{CuO}=0,1.80=8\left(g\right)\\m_{FeO}=4\left(g\right)\end{matrix}\right.\)
a) \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(Đặt:n_{Zn}=x\left(mol\right);n_{Fe}=y\left(mol\right)\)
\(n_{H_2}=0,4\left(mol\right)\)
Theo đề ta có hệ \(\left\{{}\begin{matrix}65x+56y=24,2\\x+y=0,4\end{matrix}\right.\)
=> x=0,2 ; y=0,2
\(\%m_{Zn}=\dfrac{0,2.65}{24,2}.100=53,72\%;\%m_{Fe}=46,28\%\)
b)Bảo toàn nguyên tố H: \(n_{HCl}=2n_{H_2}=0,8\left(mol\right)\)
=> \(V_{HCl}=\dfrac{0,8}{2,5}=0,32\left(l\right)\)
c) \(n_{FeCl_2}=0,2\left(mol\right);n_{ZnCl_2}=0,2\left(mol\right)\)
=> \(CM_{FeCl_2}=\dfrac{0,2}{0,32}=0,625\left(mol\right)\)
\(CM_{ZnCl_2}=\dfrac{0,2}{0,32}=0,625\left(mol\right)\)
nHCl=0,6 mol
FeO+2HCl-->FeCl2+ H2O
x mol x mol
Fe2O3+6HCl-->2FeCl3+3H2O
x mol 2x mol
72x+160x=11,6 =>x=0,05 mol
A/ CFeCl2=0,05/0,3=1/6 M
CFeCl3=0,1/0,3=1/3 M
CHCl du=(0,6-0,4)/0,3=2/3 M
B/
NaOH+ HCl-->NaCl+H2O
0,2 0,2
2NaOH+FeCl2-->2NaCl+Fe(OH)2
0,1 0,05
3NaOH+FeCl3-->3NaCl+Fe(OH)3
0,3 0,1
nNaOH=0,6
CNaOH=0,6/1,5=0,4M
Bài 3 :
\(a) n_{CuO} = a(mol) ; n_{Fe_2O_3} = b(mol)\\ \Rightarrow 80a + 160b = 36(1)\\ CuO + H_2 \xrightarrow{t^o} Cu + H_2O\\ Fe_2O_3 + 3H_2 \xrightarrow{t^o} 2Fe + H_2O\\ n_{Cu} = n_{CuO} = a(mol)\\ n_{Fe} = 2n_{Fe_2O_3} = 2b(mol)\\ \Rightarrow 64a = 4.2b.56(2)\\ (1)(2) \Rightarrow a = 0,35 ; b = 0,05\\ m_{CuO} = 0,35.80 = 28(gam)\\ m_{Fe_2O_3} = 0,05.160 = 8(gam)\\ b) n_{H_2} = a + 3b = 0,5(mol) \Rightarrow V_{H_2} = 0,5.22,4 = 11,2(lít)\)
\(c) Fe + 2HCl \to FeCl_2 + H_2\\ n_{HCl} = 2n_{Fe} = 0,1.2 = 0,2(mol)\\ \Rightarrow m_{dd\ HCl} = \dfrac{0,2.36,5}{10,95\%} = 66,67(gam)\)
Bài 4 :
\(a) Zn + 2HCl \to ZnCl_2 + H_2\\ n_{H_2} = n_{Zn} = \dfrac{1,95}{65} = 0,03(mol)\\ V_{H_2} = 0,03.22,4= 0,672(lít)\\ b) n_{HCl} =2 n_{H_2} = 0,06(mol)\\ \Rightarrow C\%_{HCl} = \dfrac{0,06.36,5}{120}.100\% = 1,825\%\\ m_{dd\ sau\ pư} = 1,95 + 120 - 0,03.2 = 121,89(gam)\\ \Rightarrow C\%_{ZnCl_2} = \dfrac{0,03.136}{121,89}.100\% = 3,35\%\)