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Gọi \(\left\{{}\begin{matrix}n_{NaOH}=a\left(mol\right)\\n_{KOH}=b\left(mol\right)\end{matrix}\right.\)
\(n_{Mg\left(OH\right)_2}=\dfrac{14,5}{58}=0,25\left(mol\right)\)
PTHH:
2NaOH + MgSO4 ---> Mg(OH)2 + Na2SO4
a -----------------------------> 0,5a
2KOH + MgSO4 ---> Mg(OH)2 + K2SO4
b -------------------------------> 0,5b
Hệ pt \(\left\{{}\begin{matrix}40a+56b=24,8\\0,5a+0,5b=0,25\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\left(mol\right)\\b=0,3\left(mol\right)\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}m_{NaOH}=0,2.40=8\left(g\right)\\m_{KOH}=0,3.56=16,8\left(g\right)\end{matrix}\right.\rightarrow\left\{{}\begin{matrix}\%m_{NaOH}=\dfrac{8}{24,8}=32,26\%\\\%m_{KOH}=100\%-32,26\%=67,74\%\end{matrix}\right.\)
2NaOH+MgSO4->Mg(OH)2+Na2SO4
x-----------------------------1\2x
2KOH+MgSO4->K2SO4+Mg(OH)2
y--------------------------------------1\2y
=> ta có :
\(\left\{{}\begin{matrix}40x+56y=24,8\\0,5x+0,5y=0,25\end{matrix}\right.=>\left\{{}\begin{matrix}x=0,2\\y=0,3\end{matrix}\right.\)
%mNaOH=\(\dfrac{0,2.40}{24,8}100\)=32,25%
=>%m KOH=67,75%
\(n_{BaCO_3}=\dfrac{19.7}{197}=0.1\left(mol\right)\)
\(n_{Ba\left(OH\right)_2}=0.15\cdot1=0.15\left(mol\right)\)
\(n_{MgCO_3}=a\left(mol\right),n_{CaCO_3}=b\left(mol\right)\)
\(\Rightarrow m_A=84a+100b=18.4\left(g\right)\left(1\right)\)
\(MgCO_3+2HCl\rightarrow MgCl_2+CO_2+H_2O\)
\(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)
\(n_{CO_2}=a+b\left(mol\right)\)
TH1 : Không tạo muối axit , Ba(OH)2 dư
\(\Rightarrow n_{CO_2}=n_{BaCO_3}=0.1\left(mol\right)\)
\(\Rightarrow a+b=0.1\left(2\right)\)
\(\left(1\right),\left(2\right):a=-0.525,b=0.625\left(L\right)\)
TH2 : Phản ứng tạo hai muối vừa đủ
\(n_{CO_2}=0.1+\left(0.15-0.1\right)\cdot2=0.2\left(mol\right)\)
\(\Rightarrow a+b=0.1\left(3\right)\)
\(\left(1\right),\left(3\right):a=b=0.1\)
\(\%MgCO_3=\dfrac{8.4}{18.4}\cdot100\%=45.65\%\)
\(\%CaCO_3=54.35\%\)
\(\left\{{}\begin{matrix}m_{Mg}=\dfrac{40.9}{100}=3,6\left(g\right)\\m_{Al}=9-3,6=5,4\left(g\right)\end{matrix}\right.\\ \rightarrow\left\{{}\begin{matrix}n_{Mg}=\dfrac{3,6}{24}=0,15\left(mol\right)\\n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\end{matrix}\right.\)
PTHH:
Mg + 2HCl ---> MgCl2 + H2
0,15 ------------------------> 0,15
2Al + 6HCl ---> 2AlCl3 + 3H2
0,2 ---------------------------> 0,3
\(\rightarrow V_{H_2}=\left(0,15+0,3\right).22,4=10,08\left(l\right)\)
\(n_{H_2O}=\dfrac{6,48}{18}=0,36\left(mol\right)\)
PTHH: FexOy + yH2 --to--> xFe + yH2O
Theo pthh: \(n_{O\left(oxit\right)}=n_{H_2\left(pư\right)}=n_{H_2O}=0,36\left(mol\right)\)
\(\rightarrow m_{oxit}=15,12+16.0,36=20,88\left(g\right)\)
\(n_{Fe}=\dfrac{15,12}{56}=0,27\left(mol\right)\)
CTHH: FexOy
=> x : y = 0,27 : 0,36 = 3 : 4
=> CTHH: Fe3O4 (oxit sắt từ)
mMg = 40%x9 = 3,6(g) =>nMg=3,6:24 = 0,15 (mol)
=> mAl = 9-3,6 = 5,4(g) => nAl = 5,4:27 = 0,2 (mol)
pthh : 2Al+6HCl -> 2AlCl3+3H2
0,2 0,3
Mg+2HCl -> MgCl2 +H2
0,15 0,15
=> nH2 = 0,15 + 0,3 = 0,45 (mol)
=> VH2 = 0,45.22,4 = 10,08 (L)
mH2 = 0,45 . 2 = 0,9 (mol)
áp dụng BLBTKL ta có :
mH2 + moxit sắt = mFe + mH2O
=> moxit sắt = 20,7 (g)
Gọi số mol FeO, Fe2O3 trong mỗi phần là a, b (mol)
=> 72a + 160b = 39,2
P1:
PTHH: FeO + 2HCl --> FeCl2 + H2O
a---------------->a
Fe2O3 + 3HCl --> 2FeCl3 + 3H2O
b-------------------->2b
=> 127a + 325b = 77,7
=> a = 0,1 (mol); b = 0,2 (mol)
\(\left\{{}\begin{matrix}\%m_{FeCl_2}=\dfrac{0,1.127}{77,7}.100\%=16,345\%\\\%m_{FeCl_3}=\dfrac{0,4.162,5}{77,7}.100\%=83,655\%\end{matrix}\right.\)
P2: \(\left\{{}\begin{matrix}FeO:0,1\left(mol\right)\\Fe_2O_3:0,2\left(mol\right)\end{matrix}\right.\)
Gọi \(\left\{{}\begin{matrix}n_{HCl}=x\left(mol\right)\\n_{H_2SO_4}=y\left(mol\right)\end{matrix}\right.\)
Muối khan gồm \(\left\{{}\begin{matrix}Fe^{3+}:0,4\left(mol\right)\\Fe^{2+}:0,1\left(mol\right)\\Cl^-:x\left(mol\right)\\SO_4^{2-}:y\left(mol\right)\end{matrix}\right.\)
Bảo toàn điện tích => x + 2y = 1,4
mmuối = (0,4 + 0,1).56 + 35,5x + 96y = 83,95
=> 35,5x + 96y = 55,95
=> \(\left\{{}\begin{matrix}x=0,9\\y=0,25\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}C_{M\left(HCl\right)}=\dfrac{0,9}{0,5}=1,8M\\C_{M\left(H_2SO_4\right)}=\dfrac{0,25}{0,5}=0,5M\end{matrix}\right.\)
\(a,m_{P1}=m_{P2}=\dfrac{78,4}{2}=39,2\left(g\right)\\ Đặt:n_{FeO\left(tổng\right)}=2a\left(mol\right);n_{Fe_2O_3\left(tổng\right)}=2b\left(mol\right)\left(a,b>0\right)\\ -Xét.phần.1:\\ PTHH:FeO+2HCl\rightarrow FeCl_2+H_2O\\ Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\\ \Rightarrow\left\{{}\begin{matrix}72a+160b=39,2\\127a+162,5.2.b=77,7\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,2\end{matrix}\right.\\ \%m_{FeO}=\dfrac{0,1.72}{0,1.72+0,2.160}.100\approx18,367\%\\ \Rightarrow\%m_{Fe_2O_3}\approx81,633\%\\ \)
\(b,-Xét.phần.2:m_{muối}=m_{Fe}+m_{Cl^-}+m_{SO^{2-}_4}\left(1\right)\\ Đặt:r=n_{HCl}\left(mol\right);s=n_{H_2SO_4}\left(mol\right)\left(r,s>0\right)\\ \left(1\right)\Leftrightarrow56.\left(0,1+0,2.2\right)+35,5r+96s=83,95\\ \Leftrightarrow35,5r+96s=55,95\left(2\right)\\ Mặt.khác,BTĐT:n_{Cl^-}+2.n_{SO^{2-}_4}=2.n_{Fe^{2+}}+3.n_{Fe^{3+}}\\ \Leftrightarrow r+2s=2.0,1+3.0,2.2\\ \Leftrightarrow r+s=1,4\left(3\right)\\ \left(2\right),\left(3\right)\Rightarrow\left\{{}\begin{matrix}r+2s=1,4\\35,5r+96s=55,95\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}r=0,9\\s=0,25\end{matrix}\right.\\ \Rightarrow C_{MddHCl}=\dfrac{r}{0,5}=\dfrac{0,9}{0,5}=1,8\left(M\right)\\ C_{MddH_2SO_4}=\dfrac{s}{0,5}=\dfrac{0,25}{0,5}=0,5\left(M\right)\)
PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
\(MgO+2HCl\rightarrow MgCl_2+H_2O\)
a) Ta có: \(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)=n_{Mg}\)
\(\Rightarrow\%m_{Mg}=\dfrac{0,5\cdot24}{16}=75\%\) \(\Rightarrow\%m_{MgO}=25\%\)
b) Ta có: \(\left\{{}\begin{matrix}n_{Mg}=0,5\left(mol\right)\\n_{MgO}=\dfrac{16\cdot25\%}{40}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{HCl}=2n_{Mg}+2n_{MgO}=1,2\left(mol\right)\) \(\Rightarrow m_{ddHCl}=\dfrac{1,2\cdot36,5}{20\%}=219\left(g\right)\)
c) Theo các PTHH: \(\left\{{}\begin{matrix}n_{H_2}=0,5\left(mol\right)\\n_{MgCl_2}=0,6\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{H_2}=0,5\cdot2=1\left(g\right)\\m_{MgCl_2}=0,6\cdot95=57\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{hhA}+m_{ddHCl}-m_{H_2}=234\left(g\right)\) \(\Rightarrow C\%_{MgCl_2}=\dfrac{57}{234}\cdot100\%\approx24,36\%\)
Cho mình hỏi ở cái PTHH ấy! sao ta không tính số mol ở dưới??
The Eiffel Tower is located in Paris, France. It was constructed between 1887 and 1889 as anentrance way to the 1889 World’s Fair and to celebrate the 100thanniversary of the French Revolution. The Tower was opened to visitors on May 6th, 1889.
Gustave Eiffel’s design was chosen from among 107 designs that were submitted to the World’s Fair design competition. However, many Parisians, especially artists, did not like his design and protested the tower’s construction. They thought it would be an eyesore, but once it was built, most Parisians soon loved the tower.
The tower is made of iron and weighs over 10,000 tons. It is 324 meters tall, including an antenna at its top, and has a staircase with 1,665 steps. There are also elevators to take visitors to the top platform where there is a panoramic view of Paris. The original elevators, now computerized, are still in use. Over 60 tons of paint are applied to the tower every seven years to keep it from rusting.
The Eiffel Tower has become a symbol of Paris. It is the most recognized monument in Europe mainly because many people think it is an architectural masterpiece. Over 250 million people have visited it since May of 1889.
70.66. How long did it take to build The Eiffel Tower?(1 Point)A. around 2 years B. around 6 years C. 100 yearsD. 60 years
71.67. Who designed The Eiffel Tower? (1 Point)A. the Parisians B. the French RevolutionC. Gustave EiffelD. the World’s Fair
72.68. Why do they repaint The Eiffel Tower frequently?(1 Point)A. to keep it from rustingB. to make it more beautifulC. to attract visitorsD. to display it in the World’s Fair design competition
73.69. How many people have visited The Eiffel Tower until now?(1 Point)A. about 10.000 peopleB. about 324 million peopleC. more than 250 million peopleD. about 189 million people
74.70. What is the major reason for The Eiffel Tower to be a well-known tourist attraction in Europe?(1 Point)A. Because of its history.B. Because it is computerized.C. Because it has architectural beauty.D. Because it is repainted frequently.
Tham khảo:))
hết chuyện làm hã em?:))