Bài 3:
Hòa tan 10,8 g nhôm vào 500 g dd HCl 14,6 % thu được ddX và khí Y.
Điều chế được mấy lít khí Y ( đo ở đkt)
Tính nồng độ % của ddX sau phản ứng
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\(a.n_{Fe}=\dfrac{2,8}{56}=0,05\left(mol\right)\\ n_{HCl}=\dfrac{14,6\%.80}{36,5}=0,32\left(mol\right)\\ a.Fe+2HCl\rightarrow FeCl_2+H_2\\ Vì:\dfrac{0,05}{1}< \dfrac{0,32}{2}\\ \Rightarrow HCldư\\ \Rightarrow n_{H_2}=n_{FeCl_2}=n_{Fe}=0,05\left(mol\right)\\ V_{H_2\left(đktc\right)}=0,05.22,4=1,12\left(l\right)\\ b.Chất.trong.dd.sau.phản.ứng:FeCl_2,HCl\left(dư\right)\\ m_{ddsau}=2,8+80-0,05.2=82,7\left(g\right)\\ C\%_{ddFeCl_2}=\dfrac{0,05.127}{82,7}.100\approx7,678\%\\n_{HCl\left(dư\right)}=0,32-0,05.2=0,22\left(mol\right)\\ C\%_{ddHCl\left(dư\right)}=\dfrac{0,22.36,5}{82,7}.100\approx9,71\% \)
\(\left(a\right)Zn+2HCl\rightarrow ZnCl_2+H_2\\ DungdịchX:ZnCl_2, A:H_2,B:Ag\\ n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ n_{HCl}=2n_{H_2}=0,5\left(mol\right)\\ \Rightarrow x=m_{ddHCl}=\dfrac{0,5.36,5}{3,65}=500\left(g\right)\\ n_{Zn}=n_{H_2}=0,2\left(mol\right)\\ \Rightarrow y=m_{Ag}=27,05-0,2.65=14,05\left(g\right)\\ \left(b\right):m_{ddsaupu}=0,2.65+500-0,2.2=512,6\left(g\right)\\ TheoPT:n_{ZnCl_2}=n_{H_2}=0,2\left(mol\right)\\ C\%_{ZnCl_2}=\dfrac{0,2.136}{512,5}.100=5,3\%\)
a) $n_{Al} = \dfrac{5,4}{27} = 0,2(mol)$
$2Al + 6HCl \to 2AlCl_3 + 3H_2$
$n_{HCl} = 3n_{Al} = 0,6(mol)$
$m_{HCl} = 0,6.36,5 = 21,9(gam)$
b) $n_{H_2} = \dfrac{3}{2}n_{Al} = 0,3(mol)$
$V_{H_2} = 0,3.22,4 = 6,72(lít)$
c)
$m_{dd\ sau\ pư} = 5,4 + 200 - 0,3.2 = 204,8(gam)$
$m_{HCl\ dư} = 200.20\% - 21,9 = 18,1(gam)$
$C\%_{HCl} = \dfrac{18,1}{204,8}.100\% = 8,84\%$
$C\%_{AlCl_3} = \dfrac{0,2.133,5}{204,8}.100\% = 13,04\%$
a) nAl=5,427=0,2(mol)nAl=5,427=0,2(mol)
2Al+6HCl→2AlCl3+3H22Al+6HCl→2AlCl3+3H2
nHCl=3nAl=0,6(mol)
mHCl=0,6.36,5=21,9(gam)mHCl=0,6.36,5=21,9(gam)
b) nH2=32nAl=0,3(mol)nH2=32nAl=0,3(mol)
VH2=0,3.22,4=6,72(lít)VH2=0,3.22,4=6,72(lít)
c)
mdd sau pư=5,4+200−0,3.2=204,8(gam)
mHCl dư=200.20%−21,9=18,1(gam)mHCl dư=200.20%−21,9=18,1(gam)
C%HCl=18,1204,8.100%=8,84%C%HCl=18,1204,8.100%=8,84%
C%AlCl3=0,2.133,5204,8.100%=13,04%
\(n_{Zn}=\dfrac{26}{65}=0,4\left(mol\right)\)
Pt : \(Zn+2HCl\rightarrow ZnCl_2+H_2|\)
1 2 1 1
0,4 0,8 0,4 0,4
a) \(n_{H2}=\dfrac{0,4.1}{1}=0,4\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,4.22,4=8,96\left(l\right)\)
b) \(n_{HCl}=\dfrac{0,4.2}{1}=0,8\left(mol\right)\)
⇒ \(m_{HCl}=0,8.36,5=29,2\left(g\right)\)
\(m_{ddHCl}=\dfrac{29,2.100}{14,6}=200\left(g\right)\)
c) \(n_{ZnCl2}=\dfrac{0,4.1}{1}=0,4\left(mol\right)\)
⇒ \(m_{ZnCl2}=0,4.136=54,4\left(g\right)\)
\(m_{ddspu}=26+200-\left(0,4.2\right)=225,2\left(g\right)\)
\(C_{ZnCl2}=\dfrac{54,4.100}{225,2}=24,16\)0/0
Chúc bạn học tốt
a) 2Al + 6HCl --> 2AlCl3 + 3H2
b) \(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\); nHCl = 0,5.2 = 1 (mol)
Xét tỉ lệ: \(\dfrac{0,1}{2}< \dfrac{1}{6}\) => Al hết, HCl dư
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
0,1->0,3---->0,1---->0,15
=> VH2 = 0,15.22,4 = 3,36 (l)
c) \(\left\{{}\begin{matrix}C_{M\left(AlCl_3\right)}=\dfrac{0,1}{0,5}=0,2M\\C_{M\left(HCl.dư\right)}=\dfrac{1-0,3}{0,5}=1,4M\end{matrix}\right.\)
a) $Fe + 2HCl \to FeCl_2 + H_2$
b) $n_{Fe} = \dfrac{11,2}{56} = 0,2(mol)$
$n_{HCl} = \dfrac{200.7,3\%}{36,5} = 0,4(mol)$
$Fe + 2HCl \to FeCl_2 + H_2$
Ta thấy : $n_{Fe} : 1 = n_{HCl} : 2$ nên phản ứng vừa đủ
$n_{H_2} = n_{Fe} = 0,2(mol)$
$V_{H_2} = 0,2.22,4 = 4,48(lít)$
c) $m_{dd\ sau\ pư} = 11,2 + 200 - 0,2.2 = 210,8(gam)$
$C\%_{FeCl_2} = \dfrac{0,2.127}{210,8}.100\% = 12,05\%$
$a)PTHH:2Al+6HCl\to 2AlCl_3+3H_2$
$n_{H_2}=\dfrac{5,04}{22,4}=0,225(mol)$
$\Rightarrow n_{Al}=0,15(mol)$
$\Rightarrow \%m_{Al}=\dfrac{0,15.27}{9,45}.100\%\approx 42,86\%$
$\Rightarrow \%m_{Cu}=100-42,86=57,14\%$
$b)$ Theo PT: $n_{HCl}=2n_{H_2}=0,45(mol)$
$\Rightarrow C_{M_{HCl}}=\dfrac{0,45.110\%}{0,5}=0,99M$
\(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\\ m_{HCl}=14,6\%.500=73\left(g\right)\\ n_{HCl}=\dfrac{73}{36,5}=2\left(mol\right)\)
PTHH: 2Al + 6HCl ---> 2AlCl3 + 3H2
LTL: \(0,6< \dfrac{2}{3}\) => HCl dư
Theo pthh: \(\left\{{}\begin{matrix}n_{HCl\left(pư\right)}=3n_{Al}=3.0,6=1,8\left(mol\right)\\n_{AlCl_3}=n_{Al}=0,6\left(mol\right)\\n_{H_2}=\dfrac{3}{2}n_{Al}=\dfrac{3}{2}.0,6=0,9\left(mol\right)\end{matrix}\right.\)
=> VH2 = 0,9.22,4 = 20,16 (l)
\(m_{dd}=10,8+500-0,9.2=509\left(g\right)\)
\(m_{AlCl_3}=0,6.133,5=80,1\left(g\right)\\ \Rightarrow C\%_{AlCl_3}=\dfrac{80,1}{509}.100\%=15,74\%\)