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nFe = 22.4/56 = 0.4 (mol)
nH2SO4 = 24.5/98 = 0.25 (mol)
Fe + H2SO4 => FeSO4 + H2
0.25.....0.25.....................0.25
mFe(dư) = ( 0.4 - 0.25 ) * 56 = 8.4 (g)
VH2 = 0.25 * 22.4 = 5.6 (l)
nFe=\(\dfrac{22,4}{56}\)= 0,4 ( mol)
nH2SO4=\(\dfrac{24,5}{98}\)=0,25 ( mol )
Fe + H2SO4 → FeSO4 + H2
Trước phản ứng: 0,4 0,25 ( mol )
Phản ứng: 0,25 0,25 0,25 ( mol )
Sau phản ứng: 0,15 0,25 0,25 ( mol )
a) m= n.M= 0,15.56=8,4 (g)
vậy Fe còn dư và dư 8,4 gam
b) VH2= n.22,4= 0,25.22,4=5,6 (l)
a: \(n_{Na}=\dfrac{9.2}{23}=0.4\left(mol\right)\)
\(n_{O_2}=\dfrac{1.12}{22.4}=0.05\left(mol\right)\)
=>Na dư 0,35 mol
b: \(4Na+O_2\rightarrow2Na_2O\)
PTHH: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
Ta có: \(\left\{{}\begin{matrix}n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\n_{O_2}=\dfrac{12,8}{32}=0,4\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{3}< \dfrac{0,4}{2}\) \(\Rightarrow\) Oxi còn dư, Fe p/ứ hết
\(\Rightarrow n_{O_2\left(dư\right)}=0,4-\dfrac{2}{15}=\dfrac{4}{15}\left(mol\right)\)
+) Theo PTHH: \(\left\{{}\begin{matrix}n_{O_2}=\dfrac{2}{15}\left(mol\right)\\n_{Fe_3O_4}=\dfrac{1}{15}\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}V_{kk}=\dfrac{2}{15}\cdot22,4\cdot5\approx14,93\left(l\right)\\m_{Fe_3O_4}=\dfrac{1}{15}\cdot232\approx15,47\left(g\right)\end{matrix}\right.\)
a) PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
b) Ta có: \(\left\{{}\begin{matrix}n_{Zn}=\dfrac{32,5}{65}=0,5\left(mol\right)\\n_{HCl}=\dfrac{3,65}{36,5}=0,1\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,5}{1}>\dfrac{0,1}{2}\) \(\Rightarrow\) HCl phản ứng hết, Zn còn dư
\(\Rightarrow n_{Zn\left(dư\right)}=0,5-0,05=0,45\left(mol\right)\) \(\Rightarrow m_{Zn\left(dư\right)}=0,45\cdot65=29,25\left(g\right)\)
c+d) Theo PTHH: \(n_{ZnCl_2}=n_{H_2}=\dfrac{1}{2}n_{HCl}=0,05mol\)
\(\Rightarrow\left\{{}\begin{matrix}m_{ZnCl_2}=0,05\cdot136=6,8\left(g\right)\\V_{H_2}=0,05\cdot22,4=1,12\left(l\right)\end{matrix}\right.\)
\(n_{Fe}=\dfrac{12.6}{56}=0.225\left(mol\right)\)
\(n_{O_2}=\dfrac{4.2}{22.4}=0.1875\left(mol\right)\)
\(3Fe+2O_2\underrightarrow{^{^{t^0}}}Fe_3O_4\)
\(3.........2\)
\(0.225......0.1875\)
Lập tỉ lệ : \(\dfrac{0.225}{3}< \dfrac{0.1875}{2}\Rightarrow O_2dư\)
\(m_{O_2\left(dư\right)}=\left(0.1875-0.225\cdot\dfrac{2}{3}\right)\cdot32=1.2\left(g\right)\)
\(m_{Fe_3O_4}=\dfrac{0.225}{3}\cdot232=17.4\left(g\right)\)
a) \(n_{Na}=\dfrac{9,2}{23}=0,4\left(mol\right);n_{O_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
PTHH: 4Na + O2 --to--> 2Na2O
Xét tỉ lệ: \(\dfrac{0,4}{4}>\dfrac{0,05}{1}\) => Na dư, O2 hết
PTHH: 4Na + O2 --to--> 2Na2O
0,2<-0,05------>0,1
=> \(m_{Na\left(dư\right)}=\left(0,4-0,2\right).23=4,6\left(g\right)\)
b) \(\left\{{}\begin{matrix}\%m_{Na\left(dư\right)}=\dfrac{4,6}{9,2+0,05.32}.100\%=42,6\%\\\%m_{Na_2O}=\dfrac{0,1.62}{9,2+0,05.32}.100\%=57,4\%\end{matrix}\right.\)
Bài 1:
\(a,2Cu+O_2\underrightarrow{t^o}2CuO\)
b, \(n_{O_2}=\dfrac{1,12}{32}=0,035mol\)
\(n_{Cu}=\dfrac{6,4}{64}=0,1mol\)
\(\dfrac{0,1}{2}>\dfrac{0,035}{1}\) => Cu dư, O2 đủ
\(n_{Cu}\left(dư\right)=0,1-0,07=0,039\left(mol\right)\)
c, \(m_{CuO}=0,07.80=5,6g\)
Bài 2:
\(n_{Al}=\dfrac{13,5}{27}=0,5mol\)
\(n_{O_2}=\dfrac{6,67}{32}=0,21\left(mol\right)\)
\(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)
\(\dfrac{0,5}{4}>\dfrac{0,21}{3}\) => Al dư, O2 đủ
\(n_{Al_2O_3}=\dfrac{2}{3}.0,21=0,14\left(mol\right)\)
\(m_{Al_2O_3}=0,14.102=14,28g\)
nFe = 2.8/56 = 0.05 (mol)
nO2 = 22.4 / 22.4 = 1 (mol)
3Fe + 2O2 -to-> Fe3O4
0.05__1/30______1/60
mO2 (dư) = ( 1 - 1/30) * 32 = 30.93 (g)
mFe3O4 = 1/60 * 232 = 3.867 (g)
a/ \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b/ Ta có: \(n_{Fe}=\dfrac{2.8}{56}=0.05\left(mol\right)\)
\(n_{O_2}=\dfrac{22.4}{22.4}=1\left(mol\right)\)
Ta có: \(\dfrac{n_{Fe\left(bra\right)}}{n_{Fe\left(pt\right)}}=\dfrac{0.05}{3}=0.016< \dfrac{n_{O_2\left(bra\right)}}{n_{O_2\left(pt\right)}}=\dfrac{1}{2}=0.5\)
=> Oxi phản ứng dư
mO2 dư = (1 - 1/30) . 32 = 30.93 (g)
mFe3O4 = 1/60 . 232 = 3.867 (g)