trộn 200 ml dd HCl 0,01M vs 300 ml dd Ba(OH)2 0,02M . tính pH sau phản ứng
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![](https://rs.olm.vn/images/avt/0.png?1311)
![](https://rs.olm.vn/images/avt/0.png?1311)
a, \(\left\{{}\begin{matrix}n_{Ba^{2+}}=4.10^{-3}\left(mol\right)\\n_{Na^+}=3.10^{-3}\left(mol\right)\\n_{OH^-}=0,011\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\left[Ba^{2+}\right]=\dfrac{4.10^{-3}}{0,2+0,3}=0,008M\\\left[Na^+\right]=\dfrac{3.10^{-3}}{0,2+0,3}=0,006M\\\left[OH^-\right]=\dfrac{0,011}{0,2+0,3}=0,022M\end{matrix}\right.\)
b, Để trung hòa dung dịch A thì:
\(n_{H^+}=n_{OH^-}\)
\(\Leftrightarrow0,01.V_{ddHCl}=\left(0,02.2+0,01\right).0,2\)
\(\Leftrightarrow V_{ddHCl}=1\left(l\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
a, \(n_{H^+}=0,025.0,2=0,005\left(mol\right)\)
\(n_{OH^-}=0,01.2.0,3=0,006\left(mol\right)\)
\(\Rightarrow n_{OH^-dư}=0,001\left(mol\right)\)
\(\Rightarrow\left[OH^-\right]_{dư}=\dfrac{0,001}{1}=10^{-3}\)
\(\Rightarrow\left[H^+\right]=10^{-11}\)
\(\Rightarrow pH=11\)
b, \(n_{Fe^{2+}}=n_{SO_4^{2-}}=0,02.0,1=0,002\left(mol\right)\)
\(n_{Ba^{2+}}=0,01.0,3=0,003\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{BaSO_4\downarrow}=n_{SO_4^{2-}}=0,002\left(mol\right)\\n_{Fe\left(OH\right)_2\downarrow}=n_{OH^-dư}=0,001\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow m_{\downarrow}=0,002.233+0,001.90=0,556\left(g\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
Ok, để thử coi chứ tui ngu hóa thấy mồ :(
a/ \(n_{NaOH}=0,2.0,1=0,02\left(mol\right)\)
\(NaOH\rightarrow Na^++OH^-\)
\(n_{Na^+}=n_{OH^-}=0,02\left(mol\right)\)
\(\Rightarrow C_{MNa^+}=\frac{0,02}{0,4+0,1}=0,04\left(mol/l\right)\)
\(n_{Ba\left(OH\right)_2}=0,3.0,4=0,12\left(mol\right)\)
\(Ba\left(OH\right)_2=Ba^{2+}+2OH^-\)
\(\Rightarrow n_{OH^-}=0,24\left(mol\right);n_{Ba^{2+}}=0,12\left(mol\right)\)
\(\Rightarrow C_{MBa^{2+}}=\frac{0,12}{0,5}=0,24\left(mol/l\right)\)
\(n_{OH^-}=0,02+0,24=0,26\left(mol\right)\)
\(\Rightarrow C_{MOH^-}=\frac{0,26}{0,5}=0,52\left(mol/l\right)\)
b/ \(n_{HCl}=0,2V\left(mol\right)\)
\(\Rightarrow n_{H^+}=n_{Cl^-}=0,2V\)
\(\Rightarrow C_{MCl^-}=\frac{0,2V}{2V}=0,1\left(mol/l\right)\)
\(n_{H_2SO_4}=0,3V\left(mol\right)=\frac{n_{H^+}}{2}=n_{SO_4^{2-}}\)
\(\Rightarrow C_{MSO_4^{2-}}=\frac{0,3V}{2V}=0,15\left(mol/l\right)\)
\(n_{H^+}=0,2V+0,6V=0,8V\left(mol\right)\)
\(\Rightarrow C_{MH^+}=\frac{0,8V}{2V}=0,4\left(mol/l\right)\)
Bác nào hảo tâm giúp em mấy câu còn lại chớ đến đây thì em chịu chết òi :(
![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{OH^-}=0,5.0,2+0,2.2.0,3=0,22\left(mol\right)\Rightarrow\left[OH^-\right]=\dfrac{0,22}{0,5}=0,44M\)
\(n_{Na^+}=0,5.0,2=0,1\left(mol\right)\Rightarrow\left[Na^+\right]=\dfrac{0,1}{0,5}=0,2M\)
\(n_{Ba^{2+}}=0,2.0,3=0,06\left(mol\right)\Rightarrow\left[Ba^{2+}\right]=\dfrac{0,06}{0,5}=0,12M\)
![](https://rs.olm.vn/images/avt/0.png?1311)
Dd Y có HCl. → Ba(OH)2 pư hết, HCl dư.
Ta có: \(n_{Ba\left(OH\right)_2}=0,3.0,05=0,015\left(mol\right)\)
\(n_{HCl\left(dư\right)}=0,01.\left(0,3+0,5\right)=0,008\left(mol\right)\)
PT: \(Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\)
______0,015___0,03_____0,015 (mol)
⇒ nHCl = 0,03 + 0,008 = 0,038 (mol)
\(\Rightarrow b=C_{M_{HCl}}=\dfrac{0,038}{0,5}=0,076\left(M\right)\)
- Khi cô cạn dd thì HCl bay hơi hết, chất rắn khan là BaCl2,
m cr khan = mBaCl2 = 0,015.208 = 3,12 (g)
\(nH^+\)= nHCl=0,0002(mol)
\(nOH^-\)=2.0,02.0,03=0,0012(mol)
\(H^+\) + \(OH^-\)\(\rightarrow\)H2O
0,0002(mol) \(\rightarrow\) 0,0002(mol)
=> n\(OH^-\)dư = 0,001(mol)
=> CM OH- =\(\dfrac{0,001}{0,5}\)=\(2.10^{-3}\)(CM)
=> CM H+=\(5.10^{-12}\)
=> ph= -lg(\(5.10^{-12}\))=11,3
300 ml = 0,3l mới đúng bạn ơi