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1. \(CaCl_2+2AgNO_3\rightarrow Ca\left(NO_3\right)_2+2AgCl_{\downarrow}\)
\(n_{AgCl}=\dfrac{28,7}{143,5}=0,2\left(mol\right)\)
Theo PT: \(n_{Ca\left(NO_3\right)_2}=\dfrac{1}{2}n_{AgCl}=0,1\left(mol\right)\)
\(\Rightarrow C_{M_{Ca\left(NO_3\right)_2}}=\dfrac{0,1}{0,15+0,05}=0,5\left(M\right)\)
2. \(n_{Na}=\dfrac{2,3}{23}=0,1\left(mol\right)\)
BTNT Na, có: nNaOH = nNa = 0,1 (mol)
\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(2Al+2NaOH+2H_2O\rightarrow2NaAlO_2+3H_2\)
Xét tỉ lệ \(\dfrac{0,2}{2}>\dfrac{0,1}{2}\), ta được Al dư.
Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{NaOH}=0,15\left(mol\right)\Rightarrow V_{H_2}=0,15.22,4=3,36\left(l\right)\)
\(n_{Al\left(pư\right)}=n_{NaOH}=0,1\left(mol\right)\Rightarrow n_{Al\left(dư\right)}=0,2-0,1=0,1\left(mol\right)\)
\(\Rightarrow m_{Al\left(dư\right)}=0,1.27=2,7\left(g\right)\)
nKCl = 0,1 . 1 = 0,1 (mol)
nAgNO3 = 0,2 . 1 = 0,2 (mol)
PTHH: AgNO3 + KCl -> AgCl + KNO3
LTL: 0,1 < 0,2 => AgNO3 dư
nAgNO3 (p/ư) = nAgCl = nKNO3 = 0,1 (mol)
nAgNO3 (dư) = 0,2 - 0,1 = 0,1 (mol)
Vdd (sau p/ư) = 0,1 + 0,2 = 0,3 (l)
CMAgNO3 = 0,1/0,3 = 0,33M
CMAgCl = 0,1/0,3 = 0,33M
CMKNO3 = 0,1/0,3 = 0,33M
PTHH: \(CaCl_2+Na_2CO_3\rightarrow CaCO_3\downarrow+2NaCl\)
a+b) Ta có: \(n_{CaCl_2}=0,1\cdot2=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{CaCO_3}=0,2\left(mol\right)\\n_{NaCl}=0,4\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{CaCO_3}=0,2\cdot100=20\left(g\right)\\C_{M_{NaCl}}=\dfrac{0,4}{0,1+0,2}\approx1,33\left(M\right)\end{matrix}\right.\)
c) PTHH: \(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\)
Theo PTHH: \(n_{HCl}=2n_{CaCO_3}=0,4\left(mol\right)\) \(\Rightarrow m_{ddHCl}=\dfrac{0,4\cdot36,5}{10\%}=146\left(g\right)\)
a.PTHH:CaCl2+Na2CO3--->CaCO3+2NaCl
Ta có:nCaCl2=0,2
=>nCaCO3=nCaCl2=0,2(mol)=>mCaCO3(kết tủa)=100.0,2=2(g)
b.Vdd=100+200=300(ml)=0,3(l)
CM Nacl=(2.0,2)/0,3=4/3(M)(Đề cho 2 chất td vừa đủ nên dd sau pứ chỉ có NaCl)
c.CaCO3+2HCl--->CaCl2+CO2+H2O
nHCl(cần dùng)=2.0.2=0,4(mol)=>mHCl=36,5.0,4=14,6(g)
=>mddHCl=14,6/10%=146(g)
\(a,2NaOH+MgSO_4\rightarrow Mg\left(OH\right)_2+Na_2SO_4\\ n_{NaOH}=0,5.1=0,5\left(mol\right)\\ b,n_{Mg\left(OH\right)_2}=\dfrac{0,5}{2}=0,25\left(mol\right)=n_{Na_2SO_4}\\ m_{kt}=m_{Mg\left(OH\right)_2}=58.0,25=14,5\left(g\right)\\ c,V_{ddX}=V_{ddNaOH}+V_{ddMgSO_4}=0,5+0,5=1\left(l\right)\\ C_{MddNa_2SO_4}=\dfrac{0,25}{1}=0,25\left(M\right)\)
Ta có: \(n_{Fe}=\dfrac{3,92}{56}=0,07\left(mol\right)\)
\(PTHH:Fe+CuSO_4--->FeSO_4+Cu\downarrow\)
a. Theo PT: \(n_{Cu}=n_{FeSO_4}=n_{Fe}=0,07\left(mol\right)\)
\(\Rightarrow m_{Cu}=0,07.64=4,48\left(g\right)\)
Ta có: \(V_{dd_{FeSO_4}}=V_{dd_{CuSO_4}}=\dfrac{200}{1000}=0,2\left(lít\right)\)
\(\Rightarrow C_{M_{FeSO_4}}=\dfrac{0,07}{0,2}=0,35M\)
\(n_{CuSO_4}=\dfrac{15,2}{160}=0,095mol\\ CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
0,095 0,19 0,095 0,095
\(m_{rắn}=m_{Cu\left(OH\right)_2}=0,095.98=9,31g\\ V_{ddNaOH}=\dfrac{0,19}{2}=0,095l\\ b)C_{M_{Na_2SO_4}}=\dfrac{0,095}{0,04+0,095}\approx0,7M\\ c)Cu\left(OH\right)_2\xrightarrow[t^0]{}CuO+H_2O\)
0,095 0,095
\(m_{rắn}=m_{CuO}=0,095.80=7,6g\)
\(n_{CuSO_4}=0.2\cdot0.5=0.1\left(mol\right)\)
\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
\(0.1.............0.2.................0.1..........0.1\)
\(C_{M_{Na_2SO_4}}=\dfrac{0.1}{0.3+0.2}=0.2\left(M\right)\)
\(Cu\left(OH\right)_2\underrightarrow{^{^{t^0}}}CuO+H_2O\)
\(0.1.............0.1\)
\(m_{CuO}=0.1\cdot80=8\left(g\right)\)
Nồng độ của Na2SO4 mà em !