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\(n_{H_2SO_4}=0,05.0,4=0,02\left(mol\right)\\ n_{HCl}=0,35.0,2=0,07\left(mol\right)\\ \left[H_2SO_4\right]=\dfrac{0,02}{0,05+0,35}=0,05\left(M\right)\\ \left[HCl\right]=\dfrac{0,07}{0,05+0,35}=0,175\left(M\right)\\ \Rightarrow\left[H^+\right]=0,05.2+0,175.1=0,275\left(M\right)\\ \left[SO^{2-}_4\right]=0,05\left(M\right)\\ \left[Cl^-\right]=0,175\left(M\right)\)
\(n_{HCl}=\dfrac{7,3}{36,5}=0,2\left(mol\right)\\ n_{H_2SO_4}=\dfrac{9,8}{98}=0,1\left(mol\right)\\ \left[HCl\right]=\dfrac{0,2}{0,2}=1\left(M\right)\\ \left[H_2SO_4\right]=\dfrac{0,1}{0,2}=0,5\left(M\right)\\ \left[SO_4^{2-}\right]=\left[H_2SO_4\right]=0,5\left(M\right)\\ \left[Cl^-\right]=\left[HCl\right]=1\left(M\right)\\ \left[H^+\right]=1+0,5.2=2\left(M\right)\)
Tổng số mol [H+] trong 2 axit :
nH+= 0.2(0.1+0.1*2)=0.06 (nhớ chứ ý H2SO4)
nOH-=0.02
H+ + OH- => H2O
0.06 0.02
=> nH+ dư = 0.04 => [H+]=0.1 =>pH=1
a, \(n_{H^+}=n_{Cl^-}=n_{HCl}=0,003\left(mol\right)\)
\(\Rightarrow\left[H^+\right]=\left[Cl^-\right]=\dfrac{0,003}{0,1}=0,03M\)
b, \(n_{H^+}=2n_{H_2SO_4}=0,05\left(mol\right)\Rightarrow\left[H^+\right]=\dfrac{0,05}{0,05}=1M\)
\(n_{SO_4^{2-}}=n_{H_2SO_4}=0,025\left(mol\right)\Rightarrow\left[SO_4^{2-}\right]=\dfrac{0,025}{0,05}=0,5M\)
a, \(\left\{{}\begin{matrix}n_{Ba^{2+}}=4.10^{-3}\left(mol\right)\\n_{Na^+}=3.10^{-3}\left(mol\right)\\n_{OH^-}=0,011\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\left[Ba^{2+}\right]=\dfrac{4.10^{-3}}{0,2+0,3}=0,008M\\\left[Na^+\right]=\dfrac{3.10^{-3}}{0,2+0,3}=0,006M\\\left[OH^-\right]=\dfrac{0,011}{0,2+0,3}=0,022M\end{matrix}\right.\)
b, Để trung hòa dung dịch A thì:
\(n_{H^+}=n_{OH^-}\)
\(\Leftrightarrow0,01.V_{ddHCl}=\left(0,02.2+0,01\right).0,2\)
\(\Leftrightarrow V_{ddHCl}=1\left(l\right)\)
\(n_{H^+}=n_{HCl}=0,03mol\)
\(n_{OH^-}=2n_{Ba\left(OH\right)_2}=0,07mol\)
\(H^+\) + \(OH^-\) \(\rightarrow\) \(H_2O\)
bđ 0,03 0,07
pư 0,03 0,03 0,03
kt 0 0,04 0,03
\(\Rightarrow\)\(\left[OH^-\right]=\dfrac{n_{sau}}{V}=\dfrac{0,04}{1}=0,04M\)
\(n_{H^+\left(1\right)}=n_{Cl^-\left(1\right)}=0,1.0,05=0,005\left(mol\right)\)
\(n_{H^+\left(2\right)}=n_{Cl^-\left(2\right)}=0,2.0,25=0,05\left(mol\right)\)
\(\Rightarrow n_{H^+}=n_{Cl^-}=0,055\left(mol\right)\)