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\(n_{H_2SO_4}=0,05.0,4=0,02\left(mol\right)\\ n_{HCl}=0,35.0,2=0,07\left(mol\right)\\ \left[H_2SO_4\right]=\dfrac{0,02}{0,05+0,35}=0,05\left(M\right)\\ \left[HCl\right]=\dfrac{0,07}{0,05+0,35}=0,175\left(M\right)\\ \Rightarrow\left[H^+\right]=0,05.2+0,175.1=0,275\left(M\right)\\ \left[SO^{2-}_4\right]=0,05\left(M\right)\\ \left[Cl^-\right]=0,175\left(M\right)\)
\(a.n_{NaCl}=0,2.2=0,4\left(mol\right)\\ n_{CaCl_2}=0,5.0,2=0,1\left(mol\right)\\ \left[Na^+\right]=\left[NaCl\right]=\dfrac{0,4.1}{0,2+0,2}=1\left(M\right)\\ \left[Ca^{2+}\right]=\left[CaCl_2\right]=\dfrac{0,1.1}{0,2+0,2}=0,25\left(M\right)\\ \left[Cl^-\right]=1.1+0,25.2=1,5\left(M\right)\)
\(b.\\ n_{MgSO_4}=\dfrac{12}{120}=0,1\left(mol\right)\\ n_{Al_2\left(SO_4\right)_3}=\dfrac{34,2}{342}=0,1\left(mol\right)\\ \left[Mg^{2+}\right]=\left[MgSO_4\right]=\dfrac{0,1}{0,2+0,3}=0,2\left(M\right)\\ \left[Al^{3+}\right]=2.\left[Al_2\left(SO_4\right)_3\right]=2.\dfrac{0,1}{0,2+0,3}=0,4\left(M\right)\\ \left[SO^{2-}_4\right]=0,2.1+0,2.3=0,8\left(M\right)\)
a, \(n_{H^+}=n_{Cl^-}=n_{HCl}=0,003\left(mol\right)\)
\(\Rightarrow\left[H^+\right]=\left[Cl^-\right]=\dfrac{0,003}{0,1}=0,03M\)
b, \(n_{H^+}=2n_{H_2SO_4}=0,05\left(mol\right)\Rightarrow\left[H^+\right]=\dfrac{0,05}{0,05}=1M\)
\(n_{SO_4^{2-}}=n_{H_2SO_4}=0,025\left(mol\right)\Rightarrow\left[SO_4^{2-}\right]=\dfrac{0,025}{0,05}=0,5M\)
a) Ta có: \(n_{Al\left(NO_3\right)_3}=\dfrac{4,26}{213}=0,02\left(mol\right)\) \(\Rightarrow\left\{{}\begin{matrix}n_{Al^+}=0,02\left(mol\right)\\n_{NO_3^-}=0,06\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\left[Al^+\right]=\dfrac{0,02}{0,1}=0,2\left(M\right)\\\left[NO_3^-\right]=\dfrac{0,06}{0,1}=0,6\left(M\right)\end{matrix}\right.\)
b) Ta có: \(\left[Na^+\right]=0,1+0,02\cdot2+0,3=0,304\left(M\right)\)
c) Bạn xem lại đề !!
\(n_{H_2SO_4\left(2M\right)}=0,15.2=0,3\left(mol\right)\)
\(n_{H_2SO_4\left(3M\right)}=0,15.3=0,45\left(mol\right)\)
\(n_{H_2SO_4\left(B\right)}=0,3+0,45=0,75\left(mol\right)\)
\(\Rightarrow C_{M_{ddB}}=\dfrac{0,75}{0,2}=3,75M\)
\(n_{H_2SO_4\left(tổng\right)}=0,15.2+0,05.3=0,45\left(mol\right)\\ V_{ddH_2SO_4\left(tổng\right)}=150+50=200\left(ml\right)=0,2\left(l\right)\\ C_{MddH_2SO_4\left(sau\right)}=C_{MddB}=\dfrac{0,45}{0,2}=2,25\left(M\right)\)
\(n_{NaOH}=0,02.2=0,04\left(mol\right)\\ 2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\\ a.n_{H_2SO_4}=n_{Na_2SO_4}=\dfrac{0,04}{2}=0,02\left(mol\right)\\ C_{MddH_2SO_4}=\dfrac{0,02}{0,08}=0,25\left(M\right)\\ b.\left[Na^+\right]=\dfrac{0,02.2}{0,02+0,08}=0,4\left(M\right)\\ \left[SO^{2-}_4\right]=\dfrac{0,02}{0,02+0,08}=0,2\left(M\right)\)
\(n_{OH^-}=0,5.0,2+0,2.2.0,3=0,22\left(mol\right)\Rightarrow\left[OH^-\right]=\dfrac{0,22}{0,5}=0,44M\)
\(n_{Na^+}=0,5.0,2=0,1\left(mol\right)\Rightarrow\left[Na^+\right]=\dfrac{0,1}{0,5}=0,2M\)
\(n_{Ba^{2+}}=0,2.0,3=0,06\left(mol\right)\Rightarrow\left[Ba^{2+}\right]=\dfrac{0,06}{0,5}=0,12M\)
dd Hcl 1M => [H+]=1M
dd h2so4 1M =[H+]=1M
==> tổng [H+]= 2M
vs dd bazơ làm tương tự nha!
b) nH+ ban đầu= 2* 0,1= 0,2mol
nOH- bđ=1,5* 0,3=0,45mol
==> nOH- dư=0,25mol
==>[OH-] dư= 0,25 : 0,4= 0,625M==> pH=14+log(0,625) ok!
kết tủa là baso4 bạn dùng số mol chất hết để tính m nha!
\(n_{HCl}=\dfrac{7,3}{36,5}=0,2\left(mol\right)\\ n_{H_2SO_4}=\dfrac{9,8}{98}=0,1\left(mol\right)\\ \left[HCl\right]=\dfrac{0,2}{0,2}=1\left(M\right)\\ \left[H_2SO_4\right]=\dfrac{0,1}{0,2}=0,5\left(M\right)\\ \left[SO_4^{2-}\right]=\left[H_2SO_4\right]=0,5\left(M\right)\\ \left[Cl^-\right]=\left[HCl\right]=1\left(M\right)\\ \left[H^+\right]=1+0,5.2=2\left(M\right)\)
Em cảm ơn ạ