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\(n_{H_2SO_4}=1.0,2=0,2(mol)\\ H_2SO_4+BaCl_2\to BaSO_4\downarrow+2HCl\\ \Rightarrow n_{BaSO_4}=n_{BaCl_2}=0,2(mol)\\ a,m_{BaSO_4}=0,2.233=46,6(g)\\ b,V_{dd_{BaCl_2}}=\dfrac{0,2}{1,5}\approx 0,13(l)\\ c,n_{HCl}=0,4(mol)\\ \Rightarrow C_{M_{HCl}}=\dfrac{0,4}{0,2+0,13}\approx 1,21M\)
\(d,\) Dd sau p/ứ là HCl nên làm quỳ tím hóa đỏ
\(n_{H_2SO_4}=0,2.1=0,2\left(mol\right)\\ H_2SO_4+BaCl_2\rightarrow BaSO_4+2HCl\\ n_{BaCl_2}=n_{BaSO_4}=n_{H_2SO_4}=0,2\left(mol\right)\\ n_{HCl}=2.0,2=0,4\left(mol\right)\\ a,m_{\downarrow}=m_{BaSO_4}=0,2.233=46,6\left(g\right)\\ b,V_{\text{dd}BaCl_2}=\dfrac{0,2}{1,5}=\dfrac{2}{15}\left(l\right)\\ c,C_{M\text{dd}HCl}=\dfrac{0,4}{\dfrac{2}{15}+0,2}=1,2\left(M\right)\\ d,V\text{ì}.c\text{ó}.\text{dd}.HCl\Rightarrow Qu\text{ỳ}.ho\text{á}.\text{đ}\text{ỏ}\)
a, \(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\)
\(n_{HCl}=0,2.2=0,4\left(mol\right)\)
PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
Xét tỉ lệ: \(\dfrac{0,15}{1}< \dfrac{0,4}{2}\), ta được HCl dư.
Theo PT: \(n_{H_2}=n_{Fe}=0,15\left(mol\right)\Rightarrow V_{H_2}=0,15.22,4=3,36\left(l\right)=3360\left(ml\right)\)
b, Theo PT: \(\left\{{}\begin{matrix}n_{FeCl_2}=n_{Fe}=0,15\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{Fe}=0,3\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{HCl\left(dư\right)}=0,4-0,3=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C_{M_{FeCl_2}}=\dfrac{0,15}{0,2}=0,75\left(M\right)\\C_{M_{HCl\left(dư\right)}}=\dfrac{0,1}{0,2}=0,5\left(M\right)\end{matrix}\right.\)
c, Ta có: \(m_{ddHCl}=1,25.200=250\left(g\right)\)
⇒ m dd sau pư = 8,4 + 250 - 0,15.2 = 258,1 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{FeCl_2}=\dfrac{0,15.127}{258,1}.100\%\approx7,38\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,1.36,5}{258.1}.100\%\approx1,41\%\end{matrix}\right.\)
\(n_{Na_2CO_3}=\dfrac{360.21,2\%}{100\%.106}=0,72(mol)\\ n_{H_2SO_4}=2,5.0,2=0,5(mol)\\ PTHH:Na_2CO_3+H_2SO_4\to Na_2SO_4+H_2O+CO_2\uparrow\\ a,\text {Vì }\dfrac{n_{Na_2CO_3}}{1}>\dfrac{n_{H_2SO_4}}{1} \text {nên }Na_2CO_3\text { dư}\\ \Rightarrow n_{CO_2}=n_{H_2SO_4}=0,5(mol)\\ \Rightarrow V_{CO_2}=0,5.22,4=11,2(l)\\\)
\(b,A:Na_2SO_4\\ n_{Na_2SO_4}=n_{H_2SO_4}=0,5(mol)\\ m_{dd_{H_2SO_4}}=200.1,1=220(g);V_{dd_{Na_2CO_3}}=\dfrac{360}{1,2}=300(ml)=0,3(l)\\ \Rightarrow C\%_{Na_2SO_4}=\dfrac{0,5.142}{360+200-0,5.44}.100\%=13,2\%\\ C_{M_{Na_2SO_4}}=\dfrac{0,5}{0,3+0,2}=1M\)
\(a,H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\\ n_{H_2SO_4}=1.0,4=0,4\left(mol\right)\\ n_{NaOH}=0,4.2=0,8\left(mol\right)\\ b,V_{ddNaOH}=\dfrac{0,8}{0,5}=1,6\left(l\right)\\ c,n_{Na_2SO_4}=n_{H_2SO_4}=0,4\left(mol\right)\\ V_{ddNa_2SO_4}=0,4+1,6=2\left(l\right)\\ C_{MddNa_2SO_4}=\dfrac{0,4}{2}=0,2\left(M\right)\)
a, Có: \(n_{NaOH}=0,4.1=0,4\left(mol\right)\)
\(n_{HCl}=0,2.1,5=0,3\left(mol\right)\)
PT: \(NaOH+HCl\rightarrow NaCl+H_2O\)
Xét tỉ lệ: \(\dfrac{0,4}{1}>\dfrac{0,3}{1}\), ta được NaOH dư.
Theo PT: \(n_{NaOH\left(pư\right)}=n_{HCl}=0,3\left(mol\right)\)
\(\Rightarrow n_{NaOh\left(dư\right)}=0,1\left(mol\right)\Rightarrow m_{NaOH\left(dư\right)}=0,1.40=4\left(g\right)\)
b, Khi cho quỳ tím vào dd A thì quỳ tím chuyển xanh do trong A còn dd NaOH dư.
c, Theo PT: \(n_{NaCl}=n_{HCl}=0,3\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C_{M_{NaCl}}=\dfrac{0,3}{0,4+0,2}=0,5M\\C_{M_{NaOH\left(dư\right)}}=\dfrac{0,1}{0,4+0,2}=\dfrac{1}{6}M\end{matrix}\right.\)
Bạn tham khảo nhé!
\(n_{Fe}=\dfrac{1,12}{56}=0,02\left(mol\right)\)
\(n_{H2SO4}=0,05.1=0,05\left(mol\right)\)
Pt : \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
a) Xét tỉ lệ : \(0,02< 0,05\Rightarrow H2SO4dư\)
Theo Pt : \(n_{FeSO4}=n_{H2}=n_{Fe}=0,02\left(mol\right)\)
\(\Rightarrow V_{H2\left(dktc\right)}=0,02.22,4=0,448\left(l\right)\)
b) \(n_{H2SO4\left(dư\right)}=0,05-0,02=0,03\left(mol\right)\)
\(V_{ddH2SO4\left(dư\right)}=\dfrac{0,03}{1}=0,03\left(l\right)=30\left(ml\right)\)
c) \(C_{MFeSO4}=\dfrac{0,02}{0,05}=0,4\left(M\right)\)
\(C_{MH2SO4\left(dư\right)}=\dfrac{\left(0,05-0,02\right)}{0,05}=0,6\left(M\right)\)
Chúc bạn học tốt
Cậu sửa lại giúp tớ câu b) :
\(n_{H2SO4\left(pư\right)}=n_{Fe}=0,02\left(mol\right)\)
\(V_{H2SO4\left(pư\right)}=\dfrac{0,02}{1}=0,02\left(l\right)=20\left(ml\right)\)
PTHH: \(Mg+H_2SO_4\rightarrow MgSO_4+H_2\uparrow\)
a_______a________a______a (mol)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
b_______\(\dfrac{3}{2}\)b_________\(\dfrac{1}{2}\)b_____\(\dfrac{3}{2}\)b (mol)
a) Ta lập HPT: \(\left\{{}\begin{matrix}24a+27b=8,25\\a+\dfrac{3}{2}b=\dfrac{2,24}{22,4}=0,1\end{matrix}\right.\) \(\Leftrightarrow\) Hệ có nghiệm âm
*Bạn xem lại đề !!!
\(n_{NaOH}=0,2.1=0,2\left(mol\right)\\ n_{H_2SO_4}=0,3.1,5=0,45\left(mol\right)\)
\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
0,2------->0,1--------->0,1
Xét \(\dfrac{0,2}{2}< \dfrac{0,45}{1}\Rightarrow\) \(H_2SO_4\)dư
Trong dung dịch D có:
\(\left\{{}\begin{matrix}n_{H_2SO_4}=0,45-0,1=0,35\left(mol\right)\\n_{Na_2SO_4}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}CM_{H_2SO_4}=\dfrac{0,35}{0,5}=0,7M\\CM_{Na_2SO_4}=\dfrac{0,1}{0,5}=0,2M\end{matrix}\right.\)
b
\(Ca\left(OH\right)_2+H_2SO_4\rightarrow CaSO_4+2H_2O\)
0,35<---------0,35
\(V_{Ca\left(OH\right)_2}=\dfrac{0,35.74}{1,2}=\dfrac{259}{12}\approx21,58\left(ml\right)\\ \Rightarrow V_{dd.Ca\left(OH\right)_2}=\dfrac{\dfrac{259}{12}.100\%}{10\%}=\dfrac{1295}{6}\approx215,83\left(ml\right)\)