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Câu 5 :
\(n_{H2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
a) Pt : \(Mg+2HCl\rightarrow MgCl_2+H_2|\)
1 2 1 1
0,1 0,2 0,1 0,1
\(MgO+2HCl\rightarrow MgCl_2+H_2O|\)
1 2 1 1
0,15 0,3 0,15
a) \(n_{Mg}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
\(m_{Mg}=0,1.24=2,4\left(g\right)\)
\(m_{MgO}=8,4-2,4=6\left(g\right)\)
0/0Mg = \(\dfrac{2,4.100}{8,4}=28,57\)0/0
0/0MgO = \(\dfrac{6.100}{8,4}=71,43\)0/0
b) Có : \(m_{MgO}=6\left(g\right)\)
\(n_{MgO}=\dfrac{6}{40}=0,15\left(mol\right)\)
\(n_{HCl\left(tổng\right)}=0,2+0,3=0,5\left(mol\right)\)
\(m_{HCl}=0,5.36,5=18,25\left(g\right)\)
\(m_{ddHCl}=\dfrac{18,25.100}{3,65}=500\left(g\right)\)
\(n_{MgCl2\left(tổng\right)}=0,1+0,15=0,25\left(mol\right)\)
⇒ \(m_{MgCl2}=0,15.95=14,25\left(g\right)\)
\(m_{ddspu}=8,4+500-\left(0,1.2\right)=508,2\left(g\right)\)
\(C_{MgCl2}=\dfrac{14,25.100}{508,2}=2,8\)0/0
Chúc bạn học tốt
\(n_{HCl}=2.0,4=0,8(mol)\\ n_{Fe}=x(mol);n_{Al}=y(mol)\\ \Rightarrow 56x+27y=11(1)\\ Fe+2HCl\to FeCl_2+H_2\\ 2Al+6HCl\to 2AlCl_3+3H_2\\ \Rightarrow 2x+3y=0,8(2)\\ (1)(2)\Rightarrow x=0,1(mol);y=0,2(mol)\)
\(a,\Sigma n_{H_2}=x+1,5y=0,4(mol)\\ \Rightarrow V_{H_2}=0,4.22,4=8,96(l)\\ b,m_{Fe}=0,1.56=5,6(g);m_{Al}=0,2.27=5,4(g)\\ c,m_{dd_{HCl}}=400.1,12=448(g)\\ n_{FeCl_2}=0,1(mol);n_{AlCl_3}=0,2(mol)\\ \Rightarrow C\%_{FeCl_2}=\dfrac{0,1.127}{5,6+448-0,1.2}.100\%=2,8\%\\ C\%_{AlCl_3}=\dfrac{0,2.133,5}{5,4+448-0,3.2}.100\%=5,9\%\)
\(n_{H_2}=\dfrac{4.48}{22.4}=0.2\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(0.2.........0.4.........0.2......0.2\)
\(m_{Zn}=0.2\cdot65=13\left(g\right)\Rightarrow m_{ZnO}=14.6-13=1.6\left(g\right)\)
\(\%Zn=\dfrac{13}{14.6}\cdot100\%=89.04\%\)
\(\%ZnO=100\%-89.04\%=10.96\%\)
\(n_{ZnO}=\dfrac{1.6}{81}\approx0.02\left(mol\right)\)
\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
\(0.02........0.04........0.02........0.02\)
\(n_{HCl}=0.4+0.04=0.44\left(mol\right)\)
\(C_{M_{HCl}}=\dfrac{0.44}{0.8}=0.55\left(M\right)\)
Eeeee ngồi tính sang chấn thật nó ra số xấu lần mò hơn 20p chưa biết tính sai chỗ nào
\(a.n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ Đặt:\left\{{}\begin{matrix}n_{Al}=a\left(mol\right)\\n_{Mg}=b\left(mol\right)\end{matrix}\right.\left(a,b>0\right)\\ 2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ Mg+H_2SO_4\rightarrow MgSO_4+H_2\\ \rightarrow\left\{{}\begin{matrix}27a+24b=5,1\\1,5a+b=0,25\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\\ \left\{{}\begin{matrix}\%m_{Al}=\dfrac{27.0,1}{5,1}.100\approx52,941\%\\\%m_{Mg}\approx47,059\%\end{matrix}\right.\)
\(b.m_{ddH_2SO_4}=\dfrac{0,25.98.100}{9,8}=250\left(g\right)\\ m_{ddsau}=m_{Al,Mg}+m_{ddH_2SO_4}-m_{H_2}=5,1+250-0,25.2=254,6\left(g\right)\\ C\%_{ddAl_2\left(SO_4\right)_3}=\dfrac{0,05.342}{254,6}.100\approx6,716\%\\ C\%_{ddMgSO_4}=\dfrac{0,1.120}{254,6}.100\approx4,713\%\)
\(a.n_{CO_2}=\dfrac{3,36}{22,4}=0,15mol\\ Na_2CO_3+2HCl\rightarrow2NaCl+CO_2\uparrow+H_2O\left(1\right)\\ NaOH+HCl\rightarrow NaCl+H_2O\\ n_{Na_2CO_3}=n_{CO_2}=0,15mol\\ \%m_{Na_2CO_3}=\dfrac{0,15.106}{23,9}\cdot100=66,5\%\\ \%m_{NaOH}=100-66,5=33,5\%\)
b. Sai đề, vì
\(n_{HCl\left(thực,tế\right)}=\dfrac{200.3,65}{100}:36,5=0,2mol\\ n_{HCl\left(pư\right)}=0,15.2+\left(23,9-0,15.106\right):40=0,5mol\)
mà \(n_{CO_2}=0,15mol\Rightarrow n_{HCl}=0,3mol\left(pt1\right)\)(nên NaOH và Na2CO3 ko dư)
vậy cần ít nhất 0,5mol HCl để tính
⇒cần thay đổi \(m_{ddHCl}\) hoặc \(C_{\%HCl}\) để tính được câu b