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\(n_{H^+}=2.0,4.0,05=0,04mol\\ n_{OH^-}=2.0,1.0,175=0,035mol\\ pH=-log\left[H^+\right]=-log\left(\dfrac{0,04-0,035}{0,4+0,1}\right)=2\)
a) \(n_{H^+}=n_{HCl}+2n_{H_2SO_4}=0,1\cdot0,12+0,1\cdot0,04=0,016\)
\(C_M=\dfrac{0,016}{0,2}=0,08M\)
\(\Rightarrow pH=-log\left(0,08\right)=1,1\)
b) \(n_{OH^-}=n_{KOH}+2n_{Ba\left(OH\right)_2}=0,012+2\cdot0,004=0,02\)
\(C_M=\dfrac{0,02}{0,2}=0,1\)
\(\Rightarrow pH=-log\left(\dfrac{10^{-14}}{0,1}\right)=13\)
a) Ta có: \(n_{NaCl}=\dfrac{5,85}{58,5}=0,1\left(mol\right)\)
\(\Rightarrow C_{M_{NaCl}}=\dfrac{0,1}{0,5}=0,2\left(M\right)=\left[Na^+\right]=\left[Cl^-\right]\)
b) Ta có: \(n_{Ba\left(OH\right)_2}=\dfrac{34,2}{171}=0,2\left(mol\right)\)
\(\Rightarrow C_{M_{Ba\left(OH\right)_2}}=\dfrac{0,2}{0,5}=0,4\left(M\right)\) \(\Rightarrow\left\{{}\begin{matrix}\left[Ba^{2+}\right]=0,4\left(M\right)\\\left[OH^-\right]=0,8\left(M\right)\end{matrix}\right.\)
c) Ta có: \(n_{H_2SO_4}=0,025\cdot2=0,05\left(mol\right)\)
\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,05}{0,125+0,025}\approx0,33\left(M\right)\) \(\Rightarrow\left\{{}\begin{matrix}\left[H^+\right]=0,66\left(M\right)\\\left[SO_4^{2-}\right]=0,33\left(M\right)\end{matrix}\right.\)
a, \(n_{H^+}=0,025.0,2=0,005\left(mol\right)\)
\(n_{OH^-}=0,01.2.0,3=0,006\left(mol\right)\)
\(\Rightarrow n_{OH^-dư}=0,001\left(mol\right)\)
\(\Rightarrow\left[OH^-\right]_{dư}=\dfrac{0,001}{1}=10^{-3}\)
\(\Rightarrow\left[H^+\right]=10^{-11}\)
\(\Rightarrow pH=11\)
b, \(n_{Fe^{2+}}=n_{SO_4^{2-}}=0,02.0,1=0,002\left(mol\right)\)
\(n_{Ba^{2+}}=0,01.0,3=0,003\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{BaSO_4\downarrow}=n_{SO_4^{2-}}=0,002\left(mol\right)\\n_{Fe\left(OH\right)_2\downarrow}=n_{OH^-dư}=0,001\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow m_{\downarrow}=0,002.233+0,001.90=0,556\left(g\right)\)
Đáp án B
nH+ = 0,1 .2.0,05 + 0,1.0,1 =0,02
nOH- = 0,1.0,2 + 0,1.0,1.2 = 0,04
⇒ Trong dung dịch sau phản ứng có nOH- dư = 0,04 – 0,02 = 0,02 mol
V dd thu = 100 + 100 = 200ml
⇒ [OH-] = 0,1 ⇒ pH = 13
Đáp án B.
\(a.n_{H^+}=0,025.0,025.2=\dfrac{1}{800}\left(mol\right)\\ \left[H^+\right]=\dfrac{\dfrac{1}{800}}{0,1+0,025}=0,01\left(M\right)\\ \Rightarrow pH=-log\left[0,01\right]=2\\ b.n_{OH^-}=0,0025.0,1=0,00025\left(mol\right)\\ \left[OH^-\right]=\dfrac{0,00025}{0,4+0,1}=\dfrac{1}{2000}\left(M\right)\\ pH=14+log\left[\dfrac{1}{2000}\right]=10,69897\)