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nBaO=30,6/153=0,2(mol)
a) PTHH: BaO + 2 HNO3 -> Ba(NO3)2 + H2O
b) nHNO3=0,2.2=0,4(mol) => mHNO3= 63.0,4=25,2(g)
=>C%ddHNO3=(25,2/150).100=16,8%
a, mct = \(\dfrac{15\cdot80}{100}\)= 12 (g)
C% = \(\dfrac{12}{80+20}\)* 100 = 12%
b, áp dụng quy tắc đương chéo:
m1= 200g có C%=20%↓ C-5
C%➚
m2=300g có c% =5%➚ 20-C
ta có:
\(\dfrac{200}{300}\)=\(\dfrac{2}{3}\)=\(\dfrac{C-5}{20-C}\)⇒2.(20-C)=3.(C-5)
Giải pt ta được C=11%
a) Gọi KL cần tìm là X
nHCl=\(\frac{5,6}{22,4}\)=0,25
PTHH: X + HCl \(\rightarrow\) XCl2 + H2
0,25 0,5 0,25 0,25
\(\Rightarrow\)mX = \(\frac{16.25}{0,25}\)=65g ( Zn )
b) mHCl= \(0,5.36,5\)=18.25g
mdd= \(\frac{18.25}{0,1825}\)=100g
Cm = \(\frac{0,5}{\frac{0,1}{0,2}}\)=6 mol/l
c) C% = 0,25.(65+71)/(100+16,25-0,5).100=29.73%
\(a)\ n_{Al} = \dfrac{8,1}{27} = 0,3(mol)\\ n_{H_2SO_4} = \dfrac{200.14,7\%}{98} = 0,3(mol)\\ 2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2\\ n_{H_2SO_4} = 0,3 < \dfrac{3}{2}n_{Al} = 0,45\)
Do đó, Al dư
\(n_{H_2} = n_{H_2SO_4} = 0,3(mol)\\ V = 0,3.22,4 = 6,72(lít)\)
b)
\(n_{Al\ pư} = \dfrac{2}{3}n_{H_2SO_4} = 0,2(mol)\\ n_{Al_2(SO_4)_3} = \dfrac{1}{3}n_{H_2SO_4} = 0,1(mol)\\ m_{dd} = 0,2.27 + 200 - 0,3.2 = 204,8(gam)\\ \Rightarrow C\%_{Al_2(SO_4)_3} =\dfrac{0,1.342}{204,8}.100\% = 16,7\%\)
pt: 2Al + 3H2SO4 \(\rightarrow\) Al2(SO4)3 +3H2
nAl =\(\dfrac{8,1}{27}=0,3\left(mol\right)\), \(m_{H_2SO_4}=14,7\%.200=29,4g\Rightarrow n_{H_2SO_4}=\dfrac{29,4}{98}=0,3mol\)
Theo pt: \(nAl:nH_2SO_4=\dfrac{0,3}{2}:\dfrac{0,3}{3}=0,15:0,1=3:2\)
=> Al dư
Theo pt: nH2 = nH2SO4 = 0,3mol => VH2 = 0,3.22,4=6,75 lít
b) theo pt: nAl2(SO4)3 = \(\dfrac{1}{3}nH_2SO_4=0,1mol\)
=> mAl2(SO4)3 = 0,1.342 = 34,2g
Áp dụng bảo toàn khối lượng
mAl + mH2SO4 = mAl2(SO4)3 dung dịch + mH2
=> m dung dịch Al2(SO4)3 = 8,1+200-0,3.2 = 207,5g
C% A = \(\dfrac{34,2}{207,5}.100\%\approx16,48\%\)
\(n_{Zn}=\dfrac{26}{65}=0,4\left(mol\right)\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,4 0,8 0,4 0,4
\(a,V_{H_2}=0,4.22,4=8,96\left(l\right)\\ b,C\%_{HCl}=\dfrac{0,8.36,5}{150}.100\%=19,5\%\\ c,m_{\text{dd}}=26+150-\left(0,4.2\right)=175,2\left(g\right)\\ C\%_{ZnCl_2}=\dfrac{0,4.136}{175,2}.100\%=31\%\)
\(n_{Na}=\dfrac{4.6}{23}=0.2\left(mol\right)\)
\(Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\)
\(0.2......................0.2.......0.1\)
\(V_{H_2}=0.1\cdot22.4=2.24\left(l\right)\)
Dung dịch X : NaOH
\(m_{dd_X}=4.6+200-0.1\cdot2=204.4\left(g\right)\)
\(C\%_{NaOH}=\dfrac{0.2\cdot40}{204.4}\cdot100\%=3.9\%\%\)
\(n_{MgCO_3}=\dfrac{16,8}{84}=0,2mol\\ a.MgCO_3+H_2SO_4->MgSO_4+H_2O+CO_2\\ 2NaOH+H_2SO_{\text{4 }}->Na_2SO_4+2H_2O\\ b.n_{H_2SO_4dư}=\dfrac{1}{2}n_{NaOH}=\dfrac{1}{2}.80.0,1:40=0,1mol\\ n_{H_2SO_4\left(MgCO_3\right)}=0,2mol\\ c.C\%=\dfrac{98.0,3}{200}.100\%=14,7\%\\ V=0,2.22,4=4,48L\\ d.m_{ddsau}=200+16,8-44.0,2+80=288g\\ C\%_{Na_2SO_4}=\dfrac{40.0,1}{288}.100\%=1,39\%\\ C\%_{MgSO_4}=\dfrac{120.0,2}{288}.100\%=8,33\%\)
\(n_{MgCO_3}=\dfrac{16,8}{84}=0,2\left(mol\right)\)
\(n_{NaOH}=\dfrac{80}{40}=2\left(mol\right)\)
PTHH :
\(MgCO_3+H_2SO_4\rightarrow MgSO_4+H_2O+CO_2\uparrow\)
0,2 0,2 0,2
\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
2 1 1
Vậy có 0,2 mol H2SO4 phản ứng với MgCO3
có 1 mol H2SO4 phản ứng với NaOH
\(m_{H_2SO_4}=1,2.98=117,6\left(g\right)\)
\(c,C\%_{H_2SO_4}=\dfrac{117,6}{200}.100\%=58,8\%\)
\(V_{CO_2}=0,2.22,4=4,48\left(l\right)\)
\(d,m_{Na_2SO_4}=1.142=142\left(g\right)\)
\(m_{ddNaOH}=\dfrac{80.100}{10}=800\left(g\right)\)
\(m_{ddH_2SO_4dư}=1.98:58,8\%\approx166,67\left(g\right)\)
\(m_{ddNa_2SO_4}=800+166,67=966,67\left(g\right)\)
\(C\%_{Na_2SO_4}=\dfrac{142}{966,67}.100\%\approx14,69\%\)
\(n_{Na}=\dfrac{6,9}{23}=0,3\left(mol\right)\\ m_{HCl}=200.3,65\%=7,3\left(g\right)\\ n_{HCl}=\dfrac{7,3}{36,5}=0,2\left(mol\right)\)
\(PTHH:2Na+2HCl\rightarrow2NaCl+H_2\uparrow\\ LTL:0,3>0,2\Rightarrow Na.dư\)
Theo pt: nH2 = 2nHCl = 2.0,2 = 0,4 (mol)
VH2 = 0,4.22,4 = 8,96 (l)
Theo pt: nNaCl = nNa (phản ứng) = nHCl = 0,2 (mol)
=> \(\left\{{}\begin{matrix}m_{NaCl}=0,2.58,5=11,7\left(g\right)\\m_{Na\left(dư\right)}=\left(0,3-0,2\right).23=2,3\left(g\right)\\m_{H_2}=0,4.2=0,8\left(g\right)\end{matrix}\right.\)
=> \(m_{dd}=200+6,9-2,3-0,8=203,8\left(g\right)\)
=> C%NaCl = \(\dfrac{11,7}{203,8}=5,74\%\)
a, \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
b, \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=n_{Fe}=0,2\left(mol\right)\Rightarrow m_{H_2SO_4}=0,2.98=19,6\left(g\right)\)
c, \(C\%_{H_2SO_4}=\dfrac{19,6}{50}.100\%=39,2\%\)
d, Theo PT: \(n_{H_2}=n_{Fe}=0,2\left(mol\right)\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)
nCO2=0,4(mol)
a) PTHH: 2 NaOH + CO2 -> Na2CO3 + H2O
0,8_________0,4________0,4(mol)
=> mNaOH=0,8.40=32(g)
=>C%ddNaOH=(32/200).100=16%
b) mddNa2CO3=mddNaOH+mCO2=200+0,4.44=217,6(g)
mNa2CO3=106.0,4=42,4(g)
=>C%ddNa2CO3=(42,4/217,6).100=19,485%
Chúc em học tốt!
nCO2=8,96/22,4=0,4mol
a/ CO2+2NaOH→Na2CO3+H2O
0,4 0,8 0,4 0,4
mNaOH=0,8.40=32g
C%ddNaOH=mct/mdd.100%=32/200.100%=16%
b/mCO2=0,4.44=17,6g
Theo định luật bảo toàn khối lượng:
mCO2+mNaOH=mNa2CO3
17,6g+200g=217,6g
mNa2CO3=0,4.106=42,4g
C%ddNa2CO3=mct/mdd.100%=42,4/217,6.100=19,4852g