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nMg = 4,8 : 24 = 0,2 mol
a) Mg + H2SO4 → MgSO4 + H2
Theo tỉ lệ phản ứng => nH2SO4 phản ứng = nMgSO4 = nH2 = 0,2 mol
=> VH2 = 0,2.22,4 = 4,48 lít.
b)
mH2SO4 phản ứng = 0,2.98 = 19,6 gam
=> C% H2SO4 = \(\dfrac{19,6}{300}.100\text{%}\) = 6,53%
c) mMgSO4 = 0,2.120 = 24 gam.
n Zn= 19,5/65=0,3 (mol).
PTPƯ: Zn(0.3) + HCl(0.6) ----> ZnCl2(0.3) + H2(0,3)
mHCl=0,6.36.5=21.9(g)
a) C%HCl= 21.9/300.100%=7,3%
b) VH2=0,3.22,4=6,72(lít)
c) mH2=0,3.2=0,6(g)
mZnCl2=0,3.136=40,8(g)
mddZnCl2 =(19,5+300)-0,6=318,9(g)
C%=mZnCl2/mddZnCl2.100= 40,8/318,9.100=12,793%
1)
a) Fe + 2HCl --> FeCl2 + H2
b) \(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
0,15->0,3--->0,15-->0,15
=> VH2 = 0,15.22,4 = 3,36 (l)
c) mdd sau pư = 8,4 + 250 - 0,15.2 = 258,1 (g)
=> \(C\%_{FeCl_2}=\dfrac{0,15.127}{258,1}.100\%=7,38\%\)
2)
a) Zn + 2HCl --> ZnCl2 + H2
b) \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
PTHH: Zn + 2HCl --> ZnCl2 + H2
0,2-->0,4---->0,2--->0,2
=> VH2 = 0,2.22,4 = 4,48 (l)
mZnCl2 = 0,2.136 = 27,2 (g)
c) \(C_{M\left(dd.HCl\right)}=\dfrac{0,4}{0,2}=2M\)
d)
PTHH: A + 2HCl --> ACl2 + H2
0,2<--0,4
=> \(M_A=\dfrac{4,8}{0,2}=24\left(g/mol\right)\)
=> A là Mg(Magie)
nFe = 5,6/56 = 0,1 (mol)
Fe + H2SO4 --> FeSO4 + H2
0,1 0,1 0,1 0,1
VH2 = 0,1.22,4 = 2,24 (l)
mddH2SO4(cần dùng ) = \(\dfrac{0,1.98.100\%}{4,9\%}=200\left(g\right)\)
mH2 = 0,1.2=0,2 (g)
mdd = mFe + mddH2SO4 - mH2 = 5,6 + 200 - 0,2 = 205,4 (g)
mFeSO4 = 0,1.152 = 15,2(g)
=> \(C\%_{ddFeSO_4}=\dfrac{15,2.100}{205,4}=7,4\%\)
\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\a, PTHH:Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ b,n_{H_2}=n_{H_2SO_4}=n_{Fe}=0,2\left(mol\right)\\ V_{H_2\left(đkc\right)}=0,2.24,79=4,958\left(l\right)\\ c,C_{MddH_2SO_4}=\dfrac{0,2}{0,4}=0,5\left(M\right)\)
Bài 1:
\(n_{H_2SO_4}=\dfrac{300.19,6\%}{98}=0,6\left(mol\right);n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\\ PTHH:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ Vì:\dfrac{0,1}{2}< \dfrac{0,6}{3}\Rightarrow H_2SO_4dư\\ n_{Al_2\left(SO_4\right)_3}=\dfrac{3n_{Al}}{2}=\dfrac{3.0,1}{2}=0,15\left(mol\right)\\ a,m_{Al_2\left(SO_4\right)_3}=342.0,15=51,3\left(g\right)\\ b,m_{ddsau}=m_{Al}+m_{ddH_2SO_4}-m_{H_2}=2,7+300-\dfrac{3}{2}.0,1.2=302,4\left(g\right)\\ c,C\%_{ddAl_2\left(SO_4\right)_3}=\dfrac{51,3}{302,4}.100\%\approx16,964\%\\ n_{H_2SO_4\left(dư\right)}=0,6-\dfrac{3}{2}.0,1=0,45\left(mol\right)\\ C\%_{ddH_2SO_4\left(dư\right)}=\dfrac{0,45.98}{302,4}.100\%\approx14,583\%\)
Bài 2:
\(PTHH:2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ Đặt:n_{Al}=a\left(mol\right);n_{Mg}=b\left(mol\right)\left(a,b>0\right)\\ Hpt:\left\{{}\begin{matrix}27a+24b=7,8\\1,5a+b=\dfrac{8,96}{22,4}=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\\ \%m_{Al}=\dfrac{0,2.27}{7,8}.100\%\approx69,231\%\Rightarrow\%m_{Mg}\approx100\%-69,231\%\approx30,769\%\)
\(n_{Zn}=\dfrac{26}{65}=0,4\left(mol\right)\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,4 0,8 0,4 0,4
\(a,V_{H_2}=0,4.22,4=8,96\left(l\right)\\ b,C\%_{HCl}=\dfrac{0,8.36,5}{150}.100\%=19,5\%\\ c,m_{\text{dd}}=26+150-\left(0,4.2\right)=175,2\left(g\right)\\ C\%_{ZnCl_2}=\dfrac{0,4.136}{175,2}.100\%=31\%\)
Có lẽ đề cho khí H2 ở đktc chứ không phải đkc bạn nhỉ?
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
Theo PT: \(\left\{{}\begin{matrix}n_{Al}=\dfrac{2}{3}n_{H_2}=0,2\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{3}n_{H_2}=0,1\left(mol\right)\end{matrix}\right.\)
⇒ m dd sau pư = 0,2.27 + 300 - 0,3.2 = 304,8 (g)
\(\Rightarrow C\%_{Al_2\left(SO_4\right)_3}=\dfrac{0,1.342}{304,8}.100\%\approx11,2\%\)