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\(a,PTHH:2KClO_3\xrightarrow{t^o}2KCl+3O_2\\ b,n_{KClO_3(thực tế)}=\dfrac{36,75}{122,5}=0,3(mol)\\ n_{O_2(phản ứng)}=\dfrac{6,72}{22,4}=0,3(mol)\\ \Rightarrow n_{KClO_3(phản ứng)}=\dfrac{2}{3}n_{O_2}=0,2(mol)\\ \Rightarrow H\%=\dfrac{0,2}{0,3}.100\%=66,67\%\\ c,n_{KCl}=n_{KClO_3(phản ứng)}=0,2(mol)\\ \Rightarrow m_{KCl}=0,2.74,5=14,9(g)\)
\(a.2KClO_3\xrightarrow[t^0]{xt}2KCl+3O_2\\ b.n_{KClO_3}=\dfrac{m_{KClO_3}}{M_{KClO_3}}=\dfrac{22,05}{122,5}=0,18mol\\ n_{O_2\left(lt\right)}=\dfrac{0,18.3}{2}=0,27mol\\ V_{O_2\left(lt\right)}=n_{O_2\left(lt\right)}.22,4=0,27.22,4=6,048l\\ H=\dfrac{V_{O_2\left(tt\right)}}{V_{O_2\left(lt\right)}}\cdot100\%=\dfrac{3,36}{6,048}\cdot100\%\approx55,56\%\\ c.n_{O_2}=\dfrac{V_{O_2}}{22,4}=\dfrac{3,36}{22,4}=0,15mol\\ n_{KCl}=\dfrac{0,15.2}{3}=0,1mol\\ m_{KCl}=n_{KCl}.M_{KCl}=0,1.74,5=7,45g\)
\(n_{O_2\left(dktc\right)}=\dfrac{V}{22,4}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\\ PTHH:2KClO_3-^{t^o}>2KCl+3O_2\)
tỉ lệ 2 : 2 : 3
n(mol) `1/3`<------------`1/3`<-----`0,5`
\(m_{KClO_3}=n\cdot M=\dfrac{1}{3}\cdot\left(39+35,5+16\cdot3\right)\approx40,83\left(g\right)\)
KCl + O2
$n_{KClO_3} = \dfrac{12,25}{122,5} = 0,1(mol)$
$2KClO_3 \xrightarrow{t^o} 2KCl + 3O_2$
$n_{O_2} = 1,5n_{KClO_3} = 0,15(mol)$
$n_P = 0,5(mol)$
$4P + 5O_2 \xrightarrow{t^o} 2P_2O_5$
$n_P : 4 > n_{O_2} : 5$ nên P dư
$n_{P_2O_5} = \dfrac{2}{5}n_{O_2} = 0,06(mol)$
$m_{P_2O_5} = 0,06.142 = 8,52(gam)$
\(n_{KClO_3}=\dfrac{24,5}{122,5}=0,2mol\)
\(\Rightarrow n_{KCl}=0,2mol\)
\(\Rightarrow m_{KCl}=0,2.74,5=14,9g\)
+) \(n_{O_2}=0,2.3:2=0,3mol\)
=> \(V_{O_2}=0,3.22,4=6,72l\)
\(a.2KClO_3-^{t^o}>2KCl+3O_2\)
0,2 ..........................0,2..................0,3
n O2 = \(\frac{6,72}{22,4}=0,3mol\)
=> n KClO3 pư = 0,2 mol
n KClO3 thực tế = \(\frac{36,75}{39+35,5+16.3}=0,3mol\)
b. H = \(\frac{0,2}{0,3}.100\%\approx66,66\%\)
c. m KCl = \(0,2.\left(39+35,5\right)=14,9g\)