Hãy nhập câu hỏi của bạn vào đây, nếu là tài khoản VIP, bạn sẽ được ưu tiên trả lời.
\(n_{CaCO_3}=\dfrac{30}{100}=0.3\left(mol\right)\)
\(Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\)
\(..............0.3.........0.3\)
\(CO+O\rightarrow CO_2\)
\(......0.3......0.3\)
\(m_Y=m_R+m_O=40+0.3\cdot16=44.8\left(g\right)\)
\(Fe_2O_3 + 3CO \xrightarrow{t^o} 2Fe + 3CO_2\\ FeO + CO \xrightarrow{t^o} Fe + CO_2\\ Fe_3O_4 + 4CO \xrightarrow{t^o} 3Fe + 4H_2O\\ CuO + CO \xrightarrow{t^o} Cu + CO_2\\ CO_2 + Ca(OH)_2 \to CaCO_3 + H_2O\\ n_{CO_2} = n_{CaCO_3} = \dfrac{30}{100} = 0,3(mol)\\ CO + O_{oxit} \to CO_2\\ n_{O(oxit)} = n_{CO_2} = 0,3(mol)\\ \Rightarrow m = m_{kim\ loại} + m_{O(oxit)} = 40 + 0,3.16 = 44,8(gam)\)
\(m_{Cu}=12g\Rightarrow n_{Cu}=\dfrac{12}{64}=0,1875mol\)
\(\Rightarrow m_{Fe}=m_{kl}-m_{Cu}=24-12=12g\Rightarrow n_{Fe}=\dfrac{3}{14}mol\)
\(CuO+H_2\rightarrow Cu+H_2O\)
\(\dfrac{12}{64}\) \(\dfrac{12}{64}\)
\(Fe_2O_3+3H_2\rightarrow2Fe+3H_2O\)
\(\dfrac{9}{28}\) \(\dfrac{3}{14}\)
\(\Rightarrow\Sigma n_{H_2}=\dfrac{12}{64}+\dfrac{9}{28}=\dfrac{57}{112}mol\)
\(\Rightarrow V_{H_2}=\dfrac{57}{112}\cdot22,4=11,4l\)
\(M_A=18.2=36\left(g/mol\right)\)
Áp dụng sơ đồ đường chéo:
\(\dfrac{n_{CO}}{n_{CO_2}}=\dfrac{44-36}{36-28}=\dfrac{1}{1}\)
\(n_{CaCO_3}=\dfrac{40}{100}=0,4\left(mol\right)\)
Đặt CTHH của oxit sắt là \(Fe_xO_y\)
PTHH:
\(Fe_xO_y+yCO\xrightarrow[]{t^o}xFe+yCO_2\) (1)
\(Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\) (2)
Theo PT (2): \(n_{CO_2}=n_{CaCO_3}=0,4\left(mol\right)\)
\(\Rightarrow n_{CO\left(d\text{ư}\right)}=n_{CO_2}=0,4\left(mol\right)\)
Theo PT (1): \(n_{Fe_xO_y}=\dfrac{1}{y}.n_{CO_2}=\dfrac{0,4}{y}\left(mol\right);n_{CO\left(p\text{ư}\right)}=n_{CO_2}=0,4\left(mol\right)\)
\(\Rightarrow M_{Fe_xO_y}=\dfrac{23,2}{\dfrac{0,4}{y}}=86y\left(g/mol\right)\\ \Rightarrow56x+16y=86y\\ \Leftrightarrow\dfrac{x}{y}=\dfrac{3}{4}\)
=> CT của oxit là Fe3O4
V = (0,4 + 0,4).22,4 = 17,92 (l)
2.
Số mol CuO là: \(n_{CuO}=\frac{m}{M}=\frac{40}{80}=0,5\left(mol\right)\)
\(PTHH:CuO+CO\rightarrow Cu+CO_2\uparrow\)
\(\left(mol\right)\) \(1\) \(1\) \(1\) \(1\)
\(\left(mol\right)\) \(0,5\) \(0,5\) \(0,5\) \(0,5\)
Ta có: \(H=\frac{n_{TT}}{n_{LT}}\Leftrightarrow n_{TT}=n_{LT}.H=0,5.90\%=0,45\left(mol\right)\)
Khối lượng Cu thu được là:
\(m_{Cu}=n.M=0,45.64=28,8\left(g\right)\)
Gọi CT oxit sắt là FexOy
Gọi nCu=a(mol)
nH2=\(\dfrac{6,72}{22,4}\)=0,3(mol)
FexOy+yH2to→xFe+yH2O(1)
Fe+2HCl→FeCl2+H2(2)
Theo pthh(2)
nFe=nH2=0,3(mol)
Theo pthh(1)
nFexOy=\(\dfrac{0,3}{x}\)(mol)
Ta có: 64a+56.0,3=29,6
⇒a=0,2(mol)
⇒mCu=0,2.64=12,8(g)
⇒mFexOy=36−12,8=23,2(g)
=>MFexOy= \(\dfrac{\dfrac{23,2}{0,3}}{x}\)=\(\dfrac{232x}{3}\)
=>56x+16y=\(\dfrac{232x}{3}\)
=>\(\dfrac{64x}{3}=16y\)
->\(\dfrac{x}{y}=\dfrac{3}{4}\)
⇒CTHH:Fe3O4
Ta có :
%m Cu=\(\dfrac{12,8}{36}100\)=35,56%
=>%m Fe3O4=100%-35,56%=64,44%
PTHH: \(CuO+CO\xrightarrow[]{t^o}Cu+CO_2\)
\(Fe_2O_3+3CO\xrightarrow[]{t^o}2Fe+3CO_2\)
\(FeO+CO\xrightarrow[]{t^o}Fe+CO_2\)
\(Fe_3O_4+4CO\xrightarrow[]{t^o}3Fe+4CO_2\)
\(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3\downarrow+H_2O\)
Theo các PTHH: \(n_{CaCO_3}=\dfrac{40}{100}=0,4\left(mol\right)=n_{CO_2}=n_{CO}\) \(\Rightarrow\left\{{}\begin{matrix}m_{CO}=0,4\cdot28=11,2\left(g\right)\\m_{CO_2}=0,4\cdot44=17,6\left(g\right)\end{matrix}\right.\)
Bảo toàn khối lượng: \(m_{Oxit}+m_{CO}=m_{KL}+m_{CO_2}\)
\(\Rightarrow m_{Oxit}=m_{KL}+m_{CO_2}-m_{CO}=40+17,6-11,2=46,4\left(g\right)\)