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Câu 3:
c, Từ phần trên, có nH2 = nFe = 0,1 (mol)
\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
\(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,1}{3}\), ta được Fe2O3 dư.
Theo PT: \(n_{Fe}=\dfrac{2}{3}n_{H_2}=\dfrac{1}{15}\left(mol\right)\Rightarrow m_{Fe}=\dfrac{1}{15}.56=\dfrac{56}{15}\left(g\right)\)
a) \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PTHH: `Fe + 2HCl -> FeCl_2 + H_2`
0,1-->0,2----->0,1------>0,1
`=> m_{FeCl_2} = 0,1.127 = 12,7 (g)`
b) `V_{H_2} = 0,1.22,4 = 2,24 (l)`
c) `n_{Fe_2O_3} = (16)/(160) = 0,1 (mol)`
PTHH: \(Fe_2O_3+3H_2\xrightarrow[]{t^o}2Fe+3H_2O\)
Xét tỉ lệ: \(0,1>\dfrac{0,1}{3}\Rightarrow\) Fe2O3
Theo PT: \(n_{Fe}=\dfrac{2}{3}.n_{H_2}=\dfrac{1}{15}\left(mol\right)\)
\(\Rightarrow m_{Fe}=\dfrac{1}{15}.56=\dfrac{56}{15}\left(g\right)\)
\(n_{Zn}=\dfrac{1,625}{65}=0,025mol\)
\(n_{HCl}=\dfrac{3,65}{36,5}=0,1mol\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,025 < 0,1 ( mol )
0,025 0,05 0,025 0,025 ( mol )
\(V_{H_2}=0,025.22,4=0,56l\)
Chất dư là HCl
\(m_{HCl\left(dư\right)}=\left(0,1-0,05\right).36,5=1,825g\)
\(m_{ZnCl_2}=0,025.136=3,4g\)
huhu cảm ơn bạn đề dài quá nên đưa lên đây làm giúp
\(n_{Al}=\dfrac{0,54}{27}=0,02mol\\ n_{H_2SO_4}=0,07.0,5=0,035mol\\ 2Al+3H_2SO_4->Al_2\left(SO_4\right)_3+3H_2\\ \Rightarrow H_2SO_4:dư\\ V=\dfrac{3}{2}.0,02.22,4=0,672L\\ C_{M\left(H_2SO_4\right)}=\dfrac{0,005}{0,07}=0,071M\\ C_{M\left(Al_2\left(SO_4\right)_3\right)}=\dfrac{0,01}{0,07}=\dfrac{1}{7}\left(M\right)\\ CuO+H_2-t^{^0}->Cu+H_2O\\ n_{H_2}=0,03mol\\ n_{CuO}=\dfrac{6,4}{80}=0,08\Rightarrow CuO:dư\\ m_{rắn}=6,4-16.0,03=5,92g\)
a)
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
PTHH: Zn + 2HCl --> ZnCl2 + H2
0,2-->0,4----->0,2--->0,2
=> VH2 = 0,2.22,4 = 4,48 (l)
b) mHCl = 0,4.36,5 = 14,6 (g)
=> \(m_{dd.HCl}=\dfrac{14,6.100}{7,3}=200\left(g\right)\)
c)
mdd sau pư = 13 + 200 - 0,2.2 = 212,6 (g)
mZnCl2 = 0,2.136 = 27,2 (g)
=> \(C\%=\dfrac{27,2}{212,6}.100\%=12,8\%\)
PTHH: \(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
\(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
\(2Cu+O_2\underrightarrow{t^o}2CuO\)
Ta có: \(n_{O_2}=\dfrac{1,6}{32}=0,05\left(mol\right)\)\(\Rightarrow n_{Cu}=n_{CuO}=0,1\left(mol\right)\)
\(\Rightarrow\%m_{CuO}=\dfrac{0,1\cdot80}{40}\cdot100\%=20\%\)
\(\Rightarrow\%m_{Fe_2O_3}=80\%\)
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Zn}=0,2\left(mol\right)\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)
c, \(n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\Rightarrow m_{ZnCl_2}=0,2.136=27,2\left(g\right)\)
d, \(n_{HCl}=2n_{Zn}=0,4\left(mol\right)\Rightarrow m_{HCl}=0,4.36,5=14,6\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{14,6}{7,3\%}=200\left(g\right)\)
⇒ m dd sau pư = 13 + 200 - 0,2.2 = 212,6 (g)
\(\Rightarrow C\%_{ZnCl_2}=\dfrac{27,2}{212,6}.100\%\approx12,79\%\)
a) $2Al + 6HCl \to 2AlCl_3 + 3H_2$
b) n Al = 8,1/27 = 0,3(mol)
Theo PTHH :
n H2 = 3/2 n Al = 0,45(mol)
V H2 = 0,45.22,4 = 10,08(lít)
c) n AlCl3 = n Al = 0,3(mol)
m AlCl3 = 0,3.133,5 = 40,05(gam)
d) n HCl = 3n Al = 0,9(mol)
m dd HCl = 0,9.36,5/7,3% = 450(gam)
Sau phản ứng :
m dd = 8,1 + 450 -0,45.2 = 457,2(gam)
C% AlCl3 = 40,05/457,2 .100% = 8,76%
\(n_{H_2O}=\dfrac{2,4\cdot10^{23}}{6\cdot10^{23}}=0,4\left(mol\right)\\ n_{Ca}=\dfrac{m}{M}=\dfrac{4}{40}=0,1\left(mol\right)\\ PTHH:Ca+2H_2O->Ca\left(OH\right)_2+H_2\)
tỉ lệ 1 : 2 : 1 ; 1
n(mol) 0,1----->0,2--------->0,1--------->0,1
\(\dfrac{n_{Ca}}{1}< \dfrac{n_{H_2O}}{2}\left(\dfrac{0,1}{1}< \dfrac{0,4}{2}\right)\)
`=>` `Ca` hết, `H_2 O` dư, tính theo `Ca`
\(n_{H_2O\left(dư\right)}=0,4-0,2=0,2\left(mol\right)\)
\(m_{H_2O\left(dư\right)}=n\cdot M=0,2\cdot18=3,6\left(g\right)\\ V_{H_2\left(dktc\right)}=n\cdot22,4=0,1\cdot22,4=2,24\left(l\right)\\ m_{Ca\left(OH\right)_2}=n\cdot M=0,1\cdot74=7,4\left(g\right)\)
\(n_{Ca}=\dfrac{4}{40}=0,1\left(mol\right)\)
\(n_{H_2O}=\dfrac{2,4.10^{23}}{6.10^{23}}=0,4\left(mol\right)\)
PTHH :
\(Ca+2H_2O\rightarrow Ca\left(OH\right)_2+H_2\)
trc p/u: 0,1 0,4
p/u: 0,1 0,2 0,1 0,1
sau p/u: 0 0,2 0,1 0,1
-----> sau p/u : H2O dư
\(a,m_{H_2Odư}=0,2.18=3,6\left(g\right)\)
\(b,V_{H_2}=0,1.22,4=2,24\left(l\right)\)
\(c,m_{Ca\left(OH\right)_2}0,1.74=7,4\left(g\right)\)