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31)
BTNT C: \(n_C=n_{CO_2}=n_{BaCO_3}=\dfrac{59,1}{197}=0,3\left(mol\right)\)
Ta có: \(m_{gi\text{ảm}}=m_{BaCO_3}-m_{CO_2}-m_{H_2O}\)
\(\Rightarrow59,1-0,3.44-m_{H_2O}=38,7\Leftrightarrow m_{H_2O}=7,2\left(g\right)\\ \Rightarrow n_{H_2O}=\dfrac{7,2}{18}=0,4\left(mol\right)\Rightarrow n_H=2n_{H_2O}=0,8\left(mol\right)\)
Ta có: \(n_{H_2O}>n_{CO_2}\left(0,4>0,3\right)\Rightarrow X\) thuộc dãy đồng đẳng ankan
Đặt CTPT của X là \(C_nH_{2n+2}\left(n\in N;n\ge1\right)\)
Ta có: \(n_X=n_{H_2O}-n_{CO_2}=0,1\left(mol\right)\)
Mà \(m_X=0,3.12+0,8=4,4\left(g\right)\)
\(\Rightarrow M_X=\dfrac{4,4}{0,1}=44\left(g/mol\right)\\ \Rightarrow14n+2=44\Leftrightarrow n=3\left(t/m\right)\)
Vậy X là C3H8 => Chọn C
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Câu 9:
\(94n_{C_6H_5OH}+46n_{C_2H_5OH}=13,04\left(g\right)\left(1\right)\)
PT: \(C_6H_5OH+Na\rightarrow C_6H_5ONa+\dfrac{1}{2}H_2\)
\(C_2H_5OH+Na\rightarrow C_2H_5ONa+\dfrac{1}{2}H_2\)
Theo PT: \(n_{H_2}=\dfrac{1}{2}n_{C_6H_5OH}+\dfrac{1}{2}n_{C_2H_5OH}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{C_6H_5OH}=0,08\left(mol\right)\\n_{C_2H_5OH}=0,12\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\%n_{C_2H_5OH}=\dfrac{0,12}{0,12+0,08}.100\%=60\%\)
Đáp án: B
Câu 31:
Ta có: m tinh bột = 1000.80% = 800 (kg) \(\Rightarrow n_{\left(C_6H_{10}O_5\right)_n}=\dfrac{800}{162n}=\dfrac{400}{81n}\left(kmol\right)\)
PT: \(\left(C_6H_{10}O_5\right)_n+nH_2O\underrightarrow{H^+,t^o}nC_6H_{12}O_6\)
\(C_6H_{12}O_6\underrightarrow{t^o,xt}2C_2H_5OH+2CO_2\)
\(\Rightarrow n_{C_2H_5OH\left(LT\right)}=2n_{C_6H_{12}O_6}=2n.n_{\left(C_6H_{10}O_5\right)_n}=\dfrac{800}{81}\left(kmol\right)\)
Mà: H = 70% \(\Rightarrow n_{C_2H_5OH\left(TT\right)}=\dfrac{800}{81}.70\%=\dfrac{560}{81}\left(kmol\right)\)
\(\Rightarrow m_{C_2H_5OH\left(TT\right)}=\dfrac{560}{81}.46=\dfrac{25760}{81}\left(kg\right)\)
\(\Rightarrow V_{C_2H_5OH}=\dfrac{\dfrac{25760}{81}}{0,8}=\dfrac{32200}{81}\left(l\right)\)
\(\Rightarrow V_{C_2H_5OH\left(60^o\right)}=\dfrac{\dfrac{32200}{81}}{0,6}\approx662,55\left(l\right)\)
Đáp án: A
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\(M_X=17.2=34\left(g/mol\right)\)
Quy đổi hh \(X\left\{{}\begin{matrix}CH_4\\C_2H_4\\C_3H_4\\C_4H_4\end{matrix}\right.\rightarrow C_xH_4\left(1< x< 4\right)\)
\(m_X=34.0,075=2,55\left(g\right)\)
Mà \(n_H=4n_X=0,3\left(mol\right)\Rightarrow n_C=\dfrac{2,55-0,3}{12}=0,1875\left(mol\right)\)
BTNT: \(\left\{{}\begin{matrix}n_{CO_2}=n_C=0,1875\left(mol\right)\\n_{H_2O}=\dfrac{1}{2}n_H=0,15\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow m=m_{CO_2}+m_{H_2O}=0,1875.44+0,15.18=10,95\left(g\right)\)
Chọn D
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Câu 21:
\(n_{C_6H_6}=\dfrac{6,24}{78}=0,08\left(mol\right)\)
\(n_{HNO_3}=\dfrac{13,23}{63}=0,21\left(mol\right)\)
PT: \(C_6H_6+3HNO_3\underrightarrow{^{t^o,xt}}C_6H_3\left(NO_2\right)_3+3H_2O\)
Xét tỉ lệ: \(\dfrac{0,08}{1}>\dfrac{0,21}{3}\), ta được C6H6 dư.
Theo PT: \(n_{C_6H_3\left(NO_2\right)_3\left(LT\right)}=\dfrac{1}{3}n_{HNO_3}=0,07\left(mol\right)\)
\(\Rightarrow m_{C_6H_3\left(NO_2\right)_3\left(LT\right)}=0,07.213=14,91\left(g\right)\)
\(\Rightarrow H\%=\dfrac{10,1388}{14,91}.100\%=68\%\)
→ Đáp án: A
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31 không có phát biểu nào đúng hoàn toàn cả nhưng có thể chọn ý A
32. D
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Câu 31:
PT: \(CH_2=CH_2+H_2O\underrightarrow{t^o,xt}CH_3CH_2OH\)
→ Đáp án: A
Câu 32:
Ta có: \(n_{CO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
\(n_X=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
Gọi CTPT của X là CnH2n.
\(\Rightarrow n=\dfrac{n_{CO_2}}{n_X}=5\)
Vậy: X là C5H10.
→ Đáp án: D