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Ta có: \(n_{CH_4}+n_{C_2H_2}=\dfrac{1,68}{22,4}=0,075\left(mol\right)\left(1\right)\)
PT: \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
\(2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\)
\(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_{3\downarrow}+H_2O\)
Theo PT: \(n_{CaCO_3}=n_{CO_2}=n_{CH_4}+2n_{C_2H_2}=\dfrac{10}{100}=0,1\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_4}=0,05\left(mol\right)\\n_{C_2H_2}=0,025\left(mol\right)\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}V_{CH_4}=0,05.22,4=1,12\left(l\right)\\V_{C_2H_2}=0,025.22,4=0,56\left(l\right)\end{matrix}\right.\)
\(n_{C_2H_4}=\dfrac{4.48}{22.4}=0.2\left(mol\right)\)
\(C_2H_4+3O_2\underrightarrow{^{t^0}}2CO_2+2H_2O\)
\(0.2.........0.6........0.4..........0.4\)
\(V_{O_2}=0.6\cdot22.4=13.44\left(l\right)\)
\(m_{H_2O}=0.4\cdot18=7.2\left(g\right)\)
\(Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\)
\(..............0.4.....0.4\)
\(m_{CaCO_3}=0.4\cdot100=40\left(g\right)\)
Gọi \(\left\{{}\begin{matrix}n_{CO_2}=a\left(mol\right)\\n_{H_2O}=b\left(mol\right)\end{matrix}\right.\)
\(m_{giảm}=m_{CaCO_3}-m_{CO_2}-m_{H_2O}\)
=> 60 - 44a - 18b = 12
=> 44a + 18b = 48 (1)
\(a=n_{CO_2}=n_{CaCO_3}=\dfrac{60}{100}=0,6\left(mol\right)\)
=> b = 1,2 (mol)
Bảo toàn C: nC = 0,6 (mol)
Bảo toàn H: nH = 2,4 (mol)
=> m = 0,6.12 + 2,4.1 = 9,6 (g)
Bảo toàn O: \(n_{O_2}=\dfrac{2a+b}{2}=1,2\left(mol\right)\)
=> VO2 = 1,2.22,4 = 26,88 (l)
=> A
ta có: nCO2 = nCaCO3 = 0,15 mol => nH2O = 0,4 molsau phản ứng với H2 thì Anken trở thành Ankan. Gọi CT chung của 2 Ankan là CaH(2a+2)CaH(2a+2) + (3a+1)/2 O2 ---> aCO2 + (a+1)H2O=> nCaH(2a+2) = nH2O - nCO2 = 0,4 - 0,15 = 0,25 mol (vô lí vì a >= 1 mà nCaH(2a+2) > nCO2)
Theo CTHH: \(n_C=2n_{hh}=\dfrac{2,24}{22,4}.2=0,2\left(mol\right)\)
PTHH:
\(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\\ C_2H_6O+3O_2\underrightarrow{t^o}2CO_2+3H_2O\\ 2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\)
Bảo toàn C: \(n_{CO_2}=n_C=0,2\left(mol\right)\)
PTHH: \(Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3\downarrow+H_2O\)
0,2----->0,2
=> mkết tủa = 0,2.100 = 20 (g)
a, \(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
\(n_{Br_2}=\dfrac{16}{160}=0,1\left(mol\right)\)
Theo PT: \(n_{C_2H_2}=\dfrac{1}{2}n_{Br_2}=0,05\left(mol\right)\)
\(\Rightarrow V_{C_2H_2}=0,05.22,4=1,12\left(l\right)\)
\(\Rightarrow V_{CH_4}=3,36-1,12=2,24\left(l\right)\)
b, \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
\(2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\)
\(n_{CH_4}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Theo PT: \(n_{O_2}=2n_{CH_4}+\dfrac{5}{2}n_{C_2H_2}=0,325\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,325.22,4=7,28\left(l\right)\Rightarrow V_{kk}=5V_{O_2}=36,4\left(l\right)\)
Theo PT: \(n_{CO_2}=n_{CH_4}+2n_{C_2H_2}=0,2\left(mol\right)\)
\(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_{3\downarrow}+H_2O\)
\(\Rightarrow n_{CaCO_3}=n_{CO_2}=0,2\left(mol\right)\Rightarrow m_{CaCO_3}=0,2.100=20\left(g\right)\)