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nS = 3,2/32 = 0,1 (mol)
nO2 = 8,96/22,4 = 0,4 (mol)
PTHH: S + O2 -> (t°) SO2
Mol: 0,1 ---> 0,1
nO2 (Al) = 0,4 - 0,1 = 0,3 (mol)
PTHH: 4Al + 3O2 -> (t°) 2Al2O3
Mol: 0,4 <--- 0,3
mAl = 0,4 . 27 = 10,8 (g)
mhh = 10,8 + 3,2 = 14 (g)
\(m_{tăng}=m_{O_2}=7.2\left(g\right)\)
\(n_{O_2}=\dfrac{7.2}{32}=0.225\left(mol\right)\)
\(V_{kk}=5V_{O_2}=5\cdot0.225\cdot22.4=25.2\left(l\right)\)
\(Đặt:n_{Mg}a\left(mol\right),n_{Cu}=b\left(mol\right),n_{Al}=c\left(mol\right)\)
\(Mg+\dfrac{1}{2}O_2\underrightarrow{t^0}MgO\)
\(Cu+\dfrac{1}{2}O_2\underrightarrow{t^0}CuO\)
\(4Al+3O_2\underrightarrow{t^0}2Al_2O_3\)
\(TC:n_{O_2}=0.5a=0.5b=0.75c=\dfrac{0.225}{3}=0.075\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}a=0.15\\b=0.15\\c=0.1\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Mg}=0.15\cdot24=3.6\left(g\right)\\m_{Cu}=0.15\cdot64=9.6\left(g\right)\\m_{Al}=0.1\cdot27=2.7\left(g\right)\end{matrix}\right.\)
\(n_{O_2}=\dfrac{3,36}{22,4}=0,15mol\)
Gọi \(\left\{{}\begin{matrix}n_C=x\\n_S=y\end{matrix}\right.\)
\(C+O_2\rightarrow\left(t^o\right)CO_2\)
x x ( mol )
\(S+O_2\rightarrow\left(t^o\right)SO_2\)
y y ( mol )
Ta có:
\(\left\{{}\begin{matrix}12x+32y=2,8\\x+y=0,15\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,05\end{matrix}\right.\)
\(\rightarrow m_C=0,1.12=1,2g\)
\(\rightarrow m_S=0,05.32=1,6g\)
\(\rightarrow\left\{{}\begin{matrix}\%m_C=\dfrac{1,2}{2,8}.100=42,85\%\\\%m_S=100\%-42,85\%=57,15\%\end{matrix}\right.\)
Gọi \(\left\{{}\begin{matrix}n_C=a\left(mol\right)\\n_S=b\left(mol\right)\end{matrix}\right.\left(a,b>0\right)\)
PTHH:
C + O2 --to--> CO2
a--->a
S + O2 --to--> SO2
b--->b
=> \(\left\{{}\begin{matrix}12a+32b=2,8\\a+b=\dfrac{3,36}{22,4}=0,15\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\left(mol\right)\\b=0,05\left(mol\right)\end{matrix}\right.\left(TM\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_C=0,1.12=1,2\left(g\right)\\m_S=0,05.32=1,6\left(g\right)\end{matrix}\right.\)
a)
2H2 + O2 --to--> 2H2O
2CO + O2 --to--> 2CO2
b)
Gọi số mol H2, CO là a, b
=> 2a + 28b = 68
PTHH: 2H2 + O2 --to--> 2H2O
a--->0,5a
2CO + O2 --to--> 2CO2
b----->0,5b
=> 0,5a + 0,5b = \(\dfrac{89,6}{22,4}=4\)
=> a = 6(mol); b = 2(mol)
\(\left\{{}\begin{matrix}\%m_{H_2}=\dfrac{6.2}{68}.100\%=17,65\%\\\%m_{CO}=\dfrac{2.28}{68}.100\%=82,35\%\end{matrix}\right.\)
\(n_{O_2}=\dfrac{89.6}{22.4}=4\left(mol\right)\)
\(n_{H_2O}=3a\left(mol\right)\)
\(n_{CO_2}=a\left(mol\right)\)
\(2H_2+O_2\underrightarrow{^{^{t^0}}}2H_2O\)
\(2CO+O_2\underrightarrow{^{^{t^0}}}2CO_2\)
\(n_{O_2}=1.5a+0.5a=4\left(mol\right)\)
\(\Leftrightarrow a=2\)
\(n_{H_2}=3\left(mol\right),n_{CO}=1\left(mol\right)\)
\(\%V_{H_2}=\dfrac{3}{4}\cdot100\%=75\%\)
\(\%V_{CO}=25\%\)
\(\%m_{H_2}=\dfrac{3\cdot2}{3\cdot2+1\cdot28}\cdot100\%=17.64\%\)
\(\%m_{CO}=100-17.64=82.36\%\)
Gọi \(\left\{{}\begin{matrix}n_{Al}=x\\n_{Cu}=y\end{matrix}\right.\)
\(4Al+3O_2\rightarrow\left(t^o\right)2Al_2O_3\)
x 1/2 x ( mol )
\(2Cu+O_2\rightarrow\left(t^o\right)2CuO\)
y y ( mol )
Ta có:
\(\left\{{}\begin{matrix}27x+64y=18,2\\51x+80y=26,2\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,2\end{matrix}\right.\)
\(\Rightarrow m_{Al}=0,2.27=5,4g\)
\(\Rightarrow m_{Cu}=0,2.64=12,8\)
\(\%m_{Al}=\dfrac{5,4}{18,2}.100=29,67\%\)
\(\%m_{Cu}=100\%-29,67=70,33\%\)
PTHH: \(4FeS+7O_2\underrightarrow{t^o}2Fe_2O_3+4SO_2\) (1)
\(2ZnS+3O_2\underrightarrow{t^o}2ZnO+2SO_2\) (2)
a) Gọi số mol của FeS là \(a\) \(\Rightarrow n_{Fe_2O_3}=\dfrac{1}{2}a\left(mol\right)\)
Gọi số mol của ZnS là \(b\) \(\Rightarrow n_{ZnO}=b\left(mol\right)\)
Ta lập được hệ phương trình
\(\left\{{}\begin{matrix}88a+97b=54,6\\80a+81b=48,2\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,4\\b=0,2\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{FeS}=0,4\cdot88=35,2\left(g\right)\\m_{ZnS}=19,4\left(g\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{FeS}=\dfrac{35,2}{54,6}\cdot100\%\approx64,47\text{%}\\\%m_{ZnS}=35,53\%\end{matrix}\right.\)
b+c) Theo các PTHH: \(\left\{{}\begin{matrix}n_{O_2\left(1\right)}=\dfrac{7}{4}n_{FeS}=0,7\left(mol\right)\\n_{O_2\left(2\right)}=\dfrac{3}{2}n_{O_2\left(2\right)}=0,3\left(mol\right)\\n_{SO_2\left(1\right)}=n_{FeS}=0,4\left(mol\right)\\n_{SO_2\left(2\right)}=n_{ZnS}=0,2\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\Sigma n_{O_2}=1\left(mol\right)\\\Sigma n_{SO_2}=0,6\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{O_2}=1\cdot22,4=22,4\left(l\right)\\V_{SO_2}=0,6\cdot22,4=13,44\left(l\right)\end{matrix}\right.\)
lỗi
Giúp mình đi :(