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BTKL : \(m_{CO_2}+m_{H_2O}=m_X+m_{O_2}=15,96\left(g\right)\)
=> \(m_{binhtang}=m_{CO_2}+m_{H_2O}=15,96\left(g\right)\)
\(n_P=\dfrac{12,4}{31}=0,4\left(mol\right)\\ a,PTHH:4P+5O_2\rightarrow\left(t^o\right)2P_2O_5\\ b,n_{O_2}=\dfrac{5}{4}.0,4=0,5\left(mol\right)\\ V_{O_2\left(đktc\right)}=0,5.22,4=11,2\left(l\right)\\ c,n_{P_2O_5}=\dfrac{2}{4}.0,4=0,2\left(mol\right)\\ m_{P_2O_5}=142.0,2=28,4\left(g\right)\)
a, nO2 = 5,6/22,4 = 0,25 (mol)
PTHH: C + O2 -> (t°) CO3
Mol: 0,25 <--- 0,25 ---> 0,25
b, mCO2 = 0,25 . 44 = 11 (g)
c, LTL: 0,2 < 0,25 => O2 dư
\(n_C=\dfrac{14,4}{44}=\dfrac{18}{55}\left(mol\right)\\ C+O_2\rightarrow\left(t^o\right)CO_2\\ n_{O_2}=n_C=n_{CO_2}=\dfrac{18}{55}\left(mol\right)\\ a,V_{O_2\left(đktc\right)}=\dfrac{18}{55}.22,4=\dfrac{2016}{275}\left(lít\right)\\ b,V_{kk}=\dfrac{100}{21}.\dfrac{2016}{275}=\dfrac{381}{11}\left(lít\right)\\ c,2KClO_3\rightarrow\left(t^o\right)2KCl+3O_2\\ n_{KClO_3\left(LT\right)}=\dfrac{2}{3}.n_{O_2}=\dfrac{2}{3}.\dfrac{18}{55}=\dfrac{12}{55}\left(mol\right)\\ \Rightarrow n_{KClO_3\left(TT\right)}=120\%.\dfrac{12}{55}=\dfrac{72}{275}\left(mol\right)\\ \Rightarrow m_{KClO_3}=122,5.\dfrac{72}{275}=\dfrac{1764}{55}\left(g\right)\)
\(n_{CaCO_3}=\dfrac{7,5}{100}=0,075\left(mol\right)\)
=> nC = 0,075 (mol)
Có \(n_{CO_2}=n_C=0,075\left(mol\right)\)
=> \(n_{H_2O}=\dfrac{4,2-0,075.44}{18}=0,05\left(mol\right)\)
=> nH = 0,1 (mol)
\(n_{O_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Bảo toàn O: \(n_{O\left(A\right)}=0,075.2+0,05-0,1.2=0\left(mol\right)\)
=> A chứa C, H
mA = mC + mH = 0,075.12 + 0,1.1 = 1 (g)
\(m_{tăng}=m_{H_2O}+m_{CO_2}=4,2\left(g\right)\\ n_{CaCO_3}=\dfrac{7,5}{100}=0,075\left(mol\right)\)
PTHH: Ca(OH)2 + CO2 ---> CaCO3 + H2O
0,075 0,075
\(\rightarrow m_{CO_2}=0,075.44=3,3\left(g\right)\\ \rightarrow m_{H_2O}=4,2-3,3=0,9\left(g\right)\\ \rightarrow n_{H_2O}=\dfrac{0,9}{18}=0,05\left(mol\right)\\ \rightarrow n_{O\left(sau.pư\right)}=0,05+0,075.2=0,1\left(mol\right)\\ n_{O\left(trong.O_2\right)}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\ \rightarrow\left\{{}\begin{matrix}n_C=0,075\left(mol\right)\\n_H=0,05.2=0,1\left(mol\right)\\n_O=0,1-0,1=0\left(mol\right)\end{matrix}\right.\)
=> mA = 0,075.12 + 0,1.1 + 0 = 1 (g)
a, \(n_{CH_4}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
PTHH:
CH4 + 2O2 --to--> CO2 + 2H2O
0,5--->1------------->0,5
Ca(OH)2 + CO2 ---> CaCO3 + H2O
0,5----->0,5
b, \(V_{O_2}=1.22,4=22,4\left(l\right)\)
c, \(m_{CaCO_3}=0,5.100=50\left(g\right)\)