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Đặt \(\left\{{}\begin{matrix}n_{Zn}=x\left(mol\right)\\n_{Mg}=y\left(mol\right)\end{matrix}\right.\Rightarrow65x+24y=8,9\left(1\right)\)
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ \Rightarrow x+y=0,2\left(2\right)\\ \left(1\right)\left(2\right)\Rightarrow\left\{{}\begin{matrix}65x+24y=8,9\\x+y=0,2\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,1\left(mol\right)\\y=0,1\left(mol\right)\end{matrix}\right.\\ \Rightarrow\%_{Zn}=\dfrac{0,1\cdot65}{8,9}\cdot100\%\approx73\%\\ \Rightarrow\%_{Mg}=100\%-73\%=27\%\)
\(n_{HCl}=2x+2y=0,4\left(mol\right)\\ \Rightarrow m_{CT_{HCl}}=0,4\cdot36,5=14,6\left(g\right)\\ \Rightarrow m_{dd_{HCl}}=\dfrac{14,6\cdot100\%}{14,6\%}=100\left(g\right)\)
\(a)n_{H_2}=\dfrac{7,55}{22,4}=\dfrac{151}{448}mol\\ n_{Mg}=n_{Zn}=a;n_{Fe}=c\\ Mg+H_2SO_4\rightarrow MgSO_4+H_2\\ a.....a\\ Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\ a.....a\\ Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ b.....b\\ \Rightarrow\left\{{}\begin{matrix}24a+65a+56b=16\\2a+b=\dfrac{151}{448}\end{matrix}\right.\\ \Rightarrow a=0,125;b=\dfrac{39}{448}\\ \%m_{Mg}=\dfrac{24.0,125}{16}\cdot100=18,75\%\\ \%m_{Zn}=\dfrac{65.0,125}{16}\cdot100=50,78\%\\ \%m_{Fe}=100-18,75-50,78=30,47\%\\ b)V_{ddH_2SO_4}=\dfrac{0,125.2+\dfrac{39}{448}}{1}\approx0,337l\)
Bài 4:
a) nH2= 6,72/22,4= 0,3(mol)
Đặt:nMg= x(mol); nZn=y(mol) (x,y>0)
PTHH: Mg + 2 HCl -> MgCl2 + H2
x_______2x________x_____x(mol)
Zn + 2 HCl -> ZnCl2 + H2
y____2y____y________y(mol)
Ta có hpt:
\(\left\{{}\begin{matrix}24x+65y=15,4\\x+y=0,3\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)
mMg=0,1.24=2,4(g)
=>%mMg = (2,4/15,4).100=15,584%
=>%mZn= 84,416%
b) nHCl(tổng)= 0,6(mol)
=> VddHCl=0,6/1=0,6(l)
Chúc em học tốt!
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Theo PT: \(n_{Zn}=n_{H_2}=0,2\left(mol\right)\)
⇒ mZn = 0,2.65 = 13 (g)
⇒ mCu = 19,4 - 13 = 6,4 (g)
Bạn tham khảo nhé!
a, \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH: Zn + 2HCl → ZnCl2 + H2
Mol: 0,2 0,2
(do Cu ko tác dụng với HCl loãng)
b, \(m_{Zn}=0,2.65=13\left(g\right)\)
\(m_{Cu}=19,4-13=6,4\left(g\right)\)
Câu 1:
\(n_{H_2}=\dfrac{2.91362}{22.4}=0.13mol\)
\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
a a a a
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
2b 3b b 3b
Ta có: \(\left\{{}\begin{matrix}24a+54b=2.58\\a+3b=0.13\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0.04\\b=0.03\end{matrix}\right.\)
\(m_{Mg}=0.04\times24=0.96g\)
\(m_{Al}=0.03\times2\times27=1.62g\)
\(V_{H_2SO_4}=\dfrac{0.04+3\times0.03}{0.5}=0.26l\)
Câu 2:
\(n_{H_2}=\dfrac{3.136}{22.4}=0.14mol\)
\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
a a a a
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
b b b b
Ta có: \(\left\{{}\begin{matrix}24a+56b=4.96\\a+b=0.14\end{matrix}\right.\)\(\Leftrightarrow\left\{{}\begin{matrix}a=0.09\\b=0.05\end{matrix}\right.\)
\(m_{Mg}=0.09\times24=2.16g\)
\(m_{Fe}=0.05\times56=2.8g\)
\(C\%_{H_2SO_4}=\dfrac{0.14\times98\times100}{200}=6.86\%\)
Câu 3:
\(n_{H_2}=\dfrac{1.568}{22.4}=0.07mol\)
\(Ba+H_2SO_4\rightarrow BaSO_4+H_2\)
a a a a
\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
b b b b
Ta có: \(\left\{{}\begin{matrix}137a+24b=3.94\\a+b=0.07\end{matrix}\right.\)\(\Leftrightarrow\left\{{}\begin{matrix}a=0.02\\b=0.05\end{matrix}\right.\)
\(m_{Ba}=0.02\times137=2.74g\)
\(m_{Mg}=0.05\times24=1.2g\)
\(CM_{H_2SO_4}=\dfrac{0.07}{0.1}=0.7M\)
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH: Zn + 2HCl -->ZnCl2 + H2
____0,2<----------------------0,2
=> mZn = 0,2.65 = 13 (g)
mCu = mrắn không tan = 19,5 (g)
\(\left\{{}\begin{matrix}\%Zn=\dfrac{13}{13+19,5}.100\%=40\%\\\%Cu=\dfrac{19,5}{13+19,5}.100\%=60\%\end{matrix}\right.\)
`n_(H_2)=4,48/22,4=0,2 (mol)`
Ta có PTHH: `Zn+2HCl --> ZnCl_2 +H_2`
Theo PT: `1`--------------------------------`1`
Theo đề: `0,2`------------------------------`0,2`
`m_(Zn)=0,2.65=13(g)`
Vì `Cu` không phản ứng với `HCl` nên `m_(chất rắn không tan)=m_(Cu)=19,5(gam)`
`%Zn=13/(13+19,5) .100%=40%`
`%Cu=100%-40%=60%`
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\)
\(n_{HCl}=0,2mol\)
\(n_{H_2SO_4}=0,2mol\)
\(n_{H\left(axit\right)}=n_{HCl}+2n_{H_2SO_4}=0,2+0,2.2=0,6mol\)
\(\rightarrow\)\(n_{H\left(axit\right)}=0,6>2n_{H_2}=0,4\rightarrow\)axit dư
\(n_{Zn}=x;n_{Mg}=y\)
Ta có hệ: \(\left\{{}\begin{matrix}65x+24y=8,9\\x+y=0,2\end{matrix}\right.\)
Giải ra x=y=0,1
%Zn=\(\dfrac{65.0,1.100}{8,9}\approx73\%\)
%Mg=27%