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\(m_{NaOH}=200.10\%=20\left(g\right)\Rightarrow n_{NaOH}=\dfrac{20}{40}=0,5\left(mol\right)\)
PTHH: 2Na + 2H2O → 2NaOH + H2
Mol: 0,5 0,5 0,5
\(m_{Na}=0,5.23=11,5\left(g\right)\)
\(V_{H_2}=0,25.22,4=5,6\left(l\right)\)
\(a.2Na+2H_2O\rightarrow2NaOH+H_2\\ b.n_{Na}=\dfrac{9,2}{23}=0,4\left(mol\right)\\ n_{H_2}=\dfrac{1}{2}n_{Na}=0,2\left(mol\right)\\ \Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\\ n_{NaOH}=n_{Na}=0,4\left(mol\right)\\ \Rightarrow m_{NaOH}=0,4.40=16\left(g\right)\\ c.H_2+CuO-^{t^o}\rightarrow Cu+H_2O\\ n_{CuO}=\dfrac{12}{80}=0,15\left(mol\right)\\ LTL:\dfrac{0,2}{1}>\dfrac{0,15}{1}\Rightarrow H_2dưsauphảnứng\\ n_{H_2\left(pứ\right)}=n_{CuO}=0,15\left(mol\right)\\ \Rightarrow n_{H_2\left(dư\right)}=0,2-0,15=0,05\left(mol\right)\\ \Rightarrow m_{H_2\left(Dư\right)}=0,05.2=0,1\left(g\right)\)
\(n_{Na}=\dfrac{9,2}{23}=0,4\left(mol\right)\)
\(pthh:2Na+2H_2O->2NaOH+H_2\)
0,4 0,4 0,2
=> \(V_{H_2}=0,2.22,4=4,48\left(L\right)\\ m_{NaOH}=0,4.40=16\left(G\right)\)
nNa = 9.2/23 = 0.4 (mol)
2Na + 2H2O => 2NaOH + H2
0.4.........................0.4.......0.2
VH2 = 0.2 * 22.4 = 4.48 (l)
mNaOH = 0.4 * 40 = 16 (g)
mdd = 9.2 + 100 - 0.2 * 2 = 108.8 (g)
C% NaOH = 16 / 108.8 * 100% = 14.71%
PTHH: \(Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\uparrow\)
Ta có: \(n_{Na}=\dfrac{9,2}{23}=0,4\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{NaOH}=0,4\left(mol\right)\\n_{H_2}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{NaOH}=0,4\cdot40=16\left(g\right)\\V_{H_2}=0,2\cdot22,4=4,48\left(l\right)\\m_{H_2}=0,2\cdot2=0,4\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd\left(saup/ứ\right)}=m_{Na}+m_{H_2O}-m_{H_2}=108,8\left(g\right)\)
\(\Rightarrow C\%_{NaOH}=\dfrac{16}{108,8}\cdot100\%\approx14,71\%\)
Câu 3:
c, Từ phần trên, có nH2 = nFe = 0,1 (mol)
\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
\(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,1}{3}\), ta được Fe2O3 dư.
Theo PT: \(n_{Fe}=\dfrac{2}{3}n_{H_2}=\dfrac{1}{15}\left(mol\right)\Rightarrow m_{Fe}=\dfrac{1}{15}.56=\dfrac{56}{15}\left(g\right)\)
a) \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PTHH: `Fe + 2HCl -> FeCl_2 + H_2`
0,1-->0,2----->0,1------>0,1
`=> m_{FeCl_2} = 0,1.127 = 12,7 (g)`
b) `V_{H_2} = 0,1.22,4 = 2,24 (l)`
c) `n_{Fe_2O_3} = (16)/(160) = 0,1 (mol)`
PTHH: \(Fe_2O_3+3H_2\xrightarrow[]{t^o}2Fe+3H_2O\)
Xét tỉ lệ: \(0,1>\dfrac{0,1}{3}\Rightarrow\) Fe2O3
Theo PT: \(n_{Fe}=\dfrac{2}{3}.n_{H_2}=\dfrac{1}{15}\left(mol\right)\)
\(\Rightarrow m_{Fe}=\dfrac{1}{15}.56=\dfrac{56}{15}\left(g\right)\)
\(2Na+2H_2O\rightarrow2NaOH+H_2\\ n_{Na}=\dfrac{4,6}{23}=0,2\left(mol\right)\\ n_{H_2O}=\dfrac{1,8}{18}=0,1\left(mol\right)\\ LTL:\dfrac{0,2}{2}>\dfrac{0,1}{2}\\ \Rightarrow Nadư\\ n_{Na\left(pứ\right)}=n_{H_2O}=0,1\left(mol\right)\\ n_{Na\left(dư\right)}=0,2-0,1=0,1\left(mol\right)\\ \Rightarrow m_{Na}=0,1.23=2,3\left(g\right)\\ n_{H_2}=\dfrac{1}{2}n_{H_2O}=0,05\left(mol\right)\\ \Rightarrow V_{H_2}=0,05.22,4=1,12\left(l\right)\)
Bài 12:
\(n_{Na}=\dfrac{4,6}{23}=0,2\left(mol\right)\)
\(n_{Ca}=\dfrac{8}{40}=0,2\left(mol\right)\)
PTHH: 2Na + 2H2O --> 2NaOH + H2
0,2----------------------->0,1
Ca + 2H2O --> Ca(OH)2 + H2
0,2---------------------->0,2
=> VH2 = (0,1 + 0,2).24,79 = 7,437(l)
nNa = 4,6 : 23 = 0,2 (mol)
2Na + 2H2O - > 2NaOH + H2
0,2 0,1
nCa = 8 : 40 = 0,2 (mol)
Ca + 2H2O -- > Ca(OH)2 + H2
0,2 0,2
nH2 = 0,1 + 0,2 = 0,3 (mol)
VH2 = 0,3 . 24,79 = 7,437 (l)
\(n_{Zn}=\dfrac{6,5}{65}=0,1mol\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,1 0,2 0,1 0,1
\(V_{H_2}=0,1\cdot22,4=2,24l\)
a)\(2Na+2H_2O\xrightarrow[]{}2NaOH+H_2\)
b)\(n_{Na}=\dfrac{6,9}{23}=0,3\left(m\right)\)
\(PTHH:2Na+2H_2O\xrightarrow[]{}2NaOH+H_2\)
tỉ lệ :2 2 2 1
số mol :0,3 0,3 0,3 0,15
\(V_{H_2}=0,15.22,4=3,36\left(m\right)\)