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\(n_{C_2H_2Br_4}=\dfrac{17.3}{346}=0.05\left(mol\right)\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
\(n_{C_2H_2}=0.05\left(mol\right)\)
\(m_{C_2H_2}=0.05\cdot26=1.3\left(g\right)\)
\(m_{CH_4}=4.33-1.3=3.03\left(g\right)\)
\(\%m_{C_2H_2}=\dfrac{1.3}{4.33}\cdot100\%=30.02\%\)
\(\%m_{CH_4}=69.98\%\)
a, \(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
\(n_{Br_2}=\dfrac{8}{160}=0,05\left(mol\right)\)
\(n_{C_2H_2}=\dfrac{1}{2}n_{Br_2}=0,025\left(mol\right)\Rightarrow m_{C_2H_2}=0,025.26=0,65\left(g\right)\)
b, \(\left\{{}\begin{matrix}\%V_{C_2H_2}=\dfrac{0,025.22,4}{33,6}.100\%\approx1,67\%\\\%V_{CH_4}\approx98,33\%\end{matrix}\right.\)
n Br2=\(\dfrac{32}{160}\)=0,2 mol
C2H2+2Br2->C2H2Br4
0,1------0,2 mol
=>%VC2H2=\(\dfrac{0,1.22,4}{5,6}\).100=40%
=>%VCH4=100-40=60%
=>n CH4=\(\dfrac{5,6-0,1.22,4}{22,4}\)=0,15 mol
CH4+2O2-to>CO2+2H2O
0,15----0,3
C2H2+\(\dfrac{5}{2}\)O2-to>2CO2+H2O
0,1-----0,25 mol
=>VO2=(0,3+0,25).22,4=12,32l
a, nBr2 = 8/160 = 0,05 (mol)
PTHH: C2H4 + Br2 -> C2H4Br2
Mol: 0,05 <--- 0,05 <--- 0,05
Vhh khí = 2,8/22,4 = 0,125 (mol)
%VC2H4 = 0,05/0,125 = 40%
%CH4 = 100% - 40% = 60%
b, nCH4 = 0,125 - 0,05 = 0,075 (mol)
PTHH: C2H4 + 3O2 -> (t°) 2CO2 + 2H2O
Mol: 0,05 ---> 0,15
CH4 + 2O2 -> (t°) CO2 + 2H2O
Mol: 0,075 ---> 0,15
Vkk = (0,15 + 0,15) . 5 . 22,4 = 33,6 (l)
\(n_{C_2H_4Br_2}=\dfrac{9,4}{188}=0,05mol\)
\(n_{hh}=\dfrac{5,6}{22,4}=0,25mol\)
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
0,05 0,05 0,05 ( mol )
\(m_{Br_2}=0,05.160=8g\)
\(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,05}{0,25}.100=20\%\\\%V_{CH_4}=100\%-20\%=80\%\end{matrix}\right.\)
a) \(C_2H_4 + Br_2 \to C_2H_4Br_2\)
b)
\(n_{C_2H_4} = n_{Br_2} = \dfrac{5,6}{160} = 0,035(mol)\\ \%V_{C_2H_4} = \dfrac{0,035.22,4}{0,86}.100\% = 91,16\%\\ \%V_{CH_4} = 100\% - 91,16\% = 8,84\%\)
nBr2 = 32/160 = 0,2 (mol)
PTHH: C2H4 + Br2 -> C2H4Br2
Mol: 0,2 <--- 0,2
nhh khí = 44,8/22,4 = 2 (mol)
%VC2H4 = 0,2/2 = 10%
%VCH4 = 100% - 10% = 90%
a, \(n_{C_2H_4}+n_{C_2H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\left(1\right)\)
PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
Theo PT: \(n_{Br_2}=n_{C_2H_4}+2n_{C_2H_2}=\dfrac{72}{160}=0,45\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{C_2H_4}=0,15\left(mol\right)\\n_{C_2H_2}=0,15\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{C_2H_4}=\dfrac{0,15.28}{0,15.28+0,15.26}.100\%\approx51,85\%\\\%m_{C_2H_2}\approx48,15\%\end{matrix}\right.\)
\(\%V_{C_2H_4}=\%V_{C_2H_2}=\dfrac{0,15.22,4}{6,72}.100\%=50\%\)
b, Theo PT: \(\left\{{}\begin{matrix}n_{C_2H_4Br_2}=n_{C_2H_4}=0,15\left(mol\right)\\n_{C_2H_2Br_4}=n_{C_2H_2}=0,15\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{C_2H_4Br_2}=0,15.188=28,2\left(g\right)\\m_{C_2H_2Br_4}=0,15.346=51,9\left(g\right)\end{matrix}\right.\)
\(n_{Br_2}=\dfrac{32}{160}=0,2\left(mol\right)\)
PT: \(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
_____0,1_____0,2_______0,1 (mol)
a, \(\left\{{}\begin{matrix}\%V_{C_2H_2}=\dfrac{0,1.22,4}{6,72}.100\%\approx33,33\%\\\%V_{CH_4}\approx66,67\%\end{matrix}\right.\)
b, \(n_{CH_4}=\dfrac{6,72}{22,4}-0,1=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{CH_4}=\dfrac{0,2.16}{0,2.16+0,1.26}.100\%\approx55,17\%\\\%m_{C_2H_2}\approx44,83\%\end{matrix}\right.\)
c, \(m_{C_2H_2Br_4}=0,1.346=34,6\left(g\right)\)