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\(a)ZnO+2HCl\rightarrow ZnCl_2+H_2O\\ b)n_{ZnO}=\dfrac{8,1}{81}=0,1mol\\ n_{HCl}=\dfrac{300.3,65}{100.36,5}=0,3mol\\ \Rightarrow\dfrac{0,1}{1}< \dfrac{0,3}{2}\Rightarrow HCl.dư\\ ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
0,1 0,2 0,1 0,1
\(m_{ZnCl_2}=0,1.136=13,6g\\ m_{HCl.dư}=\left(0,3-0,2\right).36,5=3,65g\\ m_{H_2O}=0,1.18=1,8g\\ c)C_{\%ZnCl_2}=\dfrac{13,6}{8,1+300}\cdot100=4,41\%\\ C_{\%HCl.dư}=\dfrac{3,65}{8,1+300}\cdot100=1,18\%\)
\(n_{ZnO}=\dfrac{8,1}{81}=0,1\left(mol\right)\)
\(m_{HCl}=3,65\%.300=10,95\left(g\right)\Rightarrow n_{HCl}=\dfrac{10,95}{36,5}=0,3\left(mol\right)\)
a) PTHH : \(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
0,1 0,3 0,1
b) Xét tỉ lệ : \(\dfrac{0,1}{1}< \dfrac{0,3}{2}\Rightarrow HCldư\)
Sau phản ứng gồm có : ZnCl2 và dd HCl dư
\(m_{ZnCl2}=0,1.136=13,6\left(g\right)\)
\(m_{HCl\left(dư\right)}=\left(0,3-0,1.2\right).36,5=3,65\left(g\right)\)
c) \(m_{ddspu}=8,1+300=308,1\left(g\right)\)
\(C\%_{ddHCldư}=\dfrac{3,65}{308,1}.100\%=1,18\%\)
\(C\%_{ZnCl2}=\dfrac{13,6}{308,1}.100\%=4,41\%\)
FeO+H2SO4------->FeSO4+ H2
nFeO=7,2/72=0,1 (mol)
---->nH2SO4=0,1 mol
----->mH2SO4=0,1.98=9,8(g)
---->mdung dich H2SO4=(9,8.100)/49=20(g)
--->Vdung dịch H2SO4=20/1,35=14,8(l)
2NaOH+H2SO4------>Na2SO4+2H2O
nNaOH=2.0,1=0,2(mol)
---->Vnaoh=0,2/1=0,2l
a) nCH3COOH= 0,4(mol)
PTHH: CH3COOH + NaOH -> CH3COONa + H2O
0,4____________0,4(mol)
=> mNaOH=0,4. 40=16(g)
b) nCH3COOH= 1(mol)
nC2H5OH= 100/46= 50/23(mol)
Vì : 1/1< 50/23 :1
=> C2H5OH dư, CH3COOH hết, tính theo nCH3COOH.
PTHH: CH3COOH + C2H5OH \(⇌\) CH3COOC2H5 + H2O (đk: H+ , nhiệt độ)
Ta có: nCH3COOC2H5(thực tế)= 0,625(mol)
Mà theo LT: nCH3COOC2H5(LT)= nCH3COOH=1(mol)
=>H= (0,625/1).100=62,5%
Bài 2 :
\(m_{ct}=\dfrac{19,6.50}{100}=9,8\left(g\right)\)
\(n_{H2SO4}=\dfrac{9,8}{98}=0,1\left(mol\right)\)
a) Pt : \(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O|\)
1 2 1 2
0,1 0,2
b) \(n_{NaOH}=\dfrac{0,1.2}{1}=0,2\left(mol\right)\)
\(m_{NaOH}=0,2.40=8\left(g\right)\)
\(m_{ddNaOH}=\dfrac{8.100}{32}=25\left(g\right)\)
Chúc bạn học tốt
\(n_{CuSO_4}=\dfrac{200.16\%}{160}=0,2\left(mol\right)\)
PTHH :
\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2\downarrow+Na_2SO_4\)
0,2 0,4 0,2 0,2
\(m_{NaOH}=0,4.40=16\left(g\right)\)
\(m_{ddNaOH}=\dfrac{16.100}{10}=160\left(g\right)\)
\(c,m_{Na_2SO_4}=0,2.142=28,4\left(g\right)\)
\(m_{ddNa_2SO_4}=200+160-\left(0,2.98\right)=340,4\left(g\right)\)
\(C\%_{Na_2SO_4}=\dfrac{28,4}{240,4}.100\%\approx8,34\%\)
\(d,PTHH:\)
\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
0,2 0,2
\(m_{CuO}=0,2.80=16\left(g\right)\)
a, \(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
b, \(m_{CuSO_4}=200.16\%=32\left(g\right)\Rightarrow n_{CuSO_4}=\dfrac{32}{160}=0,2\left(mol\right)\)
\(n_{NaOH}=2n_{CuSO_4}=0,4\left(mol\right)\Rightarrow m_{ddNaOH}=\dfrac{0,4.40}{10\%}=160\left(g\right)\)
c, \(n_{Cu\left(OH\right)_2}=n_{Na_2SO_4}=n_{CuSO_4}=0,2\left(mol\right)\)
\(\Rightarrow C\%_{Na_2SO_4}=\dfrac{0,2.142}{200+160-0,2.98}.100\%\approx8,34\%\)
d, \(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
\(n_{CuO}=n_{Cu\left(OH\right)_2}=0,2\left(mol\right)\Rightarrow m_{CuO}=0,2.80=16\left(g\right)\)