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C9:
nP = 6,2/31 = 0,2 (mol)
nO2 = 6,4/32 = 0,2 (mol)
PTHH: 4P + 5O2 -> (t°) 2P2O5
LTL: 0,2/4 > 0,2/5 => P dư
nP (p/ư) = 0,2/5 . 4 = 0,16 (mol)
nP (dư) = 0,2 - 0,16 = 0,04 (mol)
nP2O5 = 0,2/5 . 2 = 0,08 (mol)
mP2O5 = 0,08 . 142 = 11,36 (g)
C10:
Áp dụng ĐLBTKL, ta có:
mR + mO2 = mRO
=> mO2 = 21,6 - 16,8 = 4,8 (g(
=> nO2 = 4,8/32 = 0,15 (mol)
PTHH: 2R + O2 -> (t°) 2RO
nR = 0,15 . 2 = 0,3 (mol)
M(R) = 16,8/0,3 = 56 (g/mol(
=> R là Fe
\(n_{Fe_2O_3}=\dfrac{3.2}{160}=0.02\left(mol\right)\)
\(n_{HCl}=\dfrac{2.19}{36.5}=0.06\left(mol\right)\)
\(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\)
\(1...........6\)
\(0.02...........0.06\)
Lập tỉ lệ : \(\dfrac{0.02}{1}>\dfrac{0.06}{6}\Rightarrow Fe_2O_3dư\)
\(n_{Fe_2O_3\left(dư\right)}=0.02-\dfrac{0.06}{6}=0.01\left(mol\right)\)
\(m_{Fe_2O_3\left(dư\right)}=0.01\cdot160=1.6\left(g\right)\)
\(m_{FeCl_3}=0.02\cdot162.5=3.25\left(g\right)\)
\(m_{H_2O}=0.03\cdot18=0.54\left(g\right)\)
a) Fe2O3 + 6HCl --> 2FeCl3 + 3H2O
\(n_{Fe_2O_3}=\dfrac{3,2}{160}=0,02\left(mol\right)\)
\(n_{HCl}=\dfrac{2,19}{36,5}=0,06\left(mol\right)\)
Xét tỉ lệ \(\dfrac{0,02}{1}>\dfrac{0,06}{6}\) => Fe2O3 dư, HCl hết
PTHH: Fe2O3 + 6HCl --> 2FeCl3 + 3H2O
0,01<--0,06------->0,02---->0,03
=> \(m_{Fe_2O_3\left(dư\right)}=\left(0,02-0,01\right).160=1,6\left(g\right)\)
b) \(m_{FeCl_3}=0,02.162,5=3,25\left(g\right)\)
\(m_{H_2O}=0,03.18=0,54\left(g\right)\)
a, Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
\(n_{O_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PT: \(2H_2+O_2\underrightarrow{t^o}2H_2O\)
Xét tỉ lệ: \(\dfrac{0,3}{2}< \dfrac{0,2}{1}\), ta được O2 dư.
Theo PT: \(n_{O_2\left(pư\right)}=\dfrac{1}{2}n_{H_2}=0,15\left(mol\right)\)
\(\Rightarrow n_{O_2\left(dư\right)}=0,05\left(mol\right)\Rightarrow m_{O_2\left(dư\right)}=0,05.32=1,6\left(g\right)\)
b, \(n_{H_2O}=n_{H_2}=0,3\left(mol\right)\)
\(\Rightarrow m_{H_2O}=0,3.18=5,4\left(g\right)\)
c, PT: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
_______0,3_______________________0,15 (mol)
\(\Rightarrow m_{KMnO_4}=0,3.158=47,4\left(g\right)\)
Bạn tham khảo nhé!
$a) CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O$
b) $n_{CH_4} = \dfrac{3,92}{22,4} = 0,175(mol)$
$n_{O_2} = \dfrac{3,84}{32} = 0,12(mol)$
Ta thấy : $n_{CH_4} : 1 > n_{O_2} : 2$ nên $CH_4$ dư
$n_{CH_4\ pư} = \dfrac{1}{2}n_{O_2} = 0,06(mol)$
$\Rightarrow m_{CH_4\ dư} = (0,175 - 0,06).16 = 1,84(gam)$
c) $2NaOH + CO_2 \to Na_2CO_3 + H_2O$
Theo PTHH :
$n_{Na_2CO_3} = n_{CO_2} = \dfrac{1}{2}n_{CH_4} = 0,06(mol)$
$m_{Na_2CO_3} = 0,06.106 = 6,36(gam)$
a, PTHH: S + O2 -> (t°) SO2
b, nS = 6,4/32 = 0,2 (mol)
nO2 = 6,72/22,4 = 0,3 (mol)
LTL: 0,2 < 0,3 => O2 dư
nO2 (pư) = nSO2 = nS = 0,2 (mol)
mO2 (dư) = (0,3 - 0,2) . 32 = 3,2 (g)
c, mSO2 = 64 . 0,2 = 12,8 (g)
a, \(S+O_2\underrightarrow{t^o}SO_2\)
\(nS=\dfrac{6,4}{32}=0,2\left(mol\right)\)
\(nO_2=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
\(\dfrac{0,2}{1}< \dfrac{0,3}{1}\) => oxi dư
\(nO_{2\left(dư\right)}=0,1\left(mol\right)\)
\(mO_{2\left(dư\right)}=0,1.32=3,2\left(g\right)\)
\(nSO_2=nS=0,2\left(mol\right)\)
\(mSO_2=0,2.64=12,8\left(g\right)\)
nZn = 6,5 / 65 = 0,1 (mol)
nO2 = 2,24 / 22,4 = 0,1 (mol)
2Zn + O2 --- > 2ZnO
0,1 0,05 0,1 (mol)
LTL : 0,1/2 < 0,1/1
= > O2 dư ; Zn đủ
mO2(dư) = (0,1-0,05 ) . 32 = 1,6 (g)
mZnO = 0,1 . 81 = 8,1 (g)
PTHH: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
Ta có: \(\left\{{}\begin{matrix}n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\n_{O_2}=\dfrac{12,8}{32}=0,4\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{3}< \dfrac{0,4}{2}\) \(\Rightarrow\) Oxi còn dư, Fe p/ứ hết
\(\Rightarrow n_{O_2\left(dư\right)}=0,4-\dfrac{2}{15}=\dfrac{4}{15}\left(mol\right)\)
+) Theo PTHH: \(\left\{{}\begin{matrix}n_{O_2}=\dfrac{2}{15}\left(mol\right)\\n_{Fe_3O_4}=\dfrac{1}{15}\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}V_{kk}=\dfrac{2}{15}\cdot22,4\cdot5\approx14,93\left(l\right)\\m_{Fe_3O_4}=\dfrac{1}{15}\cdot232\approx15,47\left(g\right)\end{matrix}\right.\)
\(n_{H_2O}=\dfrac{3,6}{18}=0,2\left(mol\right)\\ P_2O_5+3H_2O\rightarrow2H_3PO_4\\ a,n_{P_2O_5}=n_{H_2O}:3=0,2:3=\dfrac{1}{15}\left(mol\right)\\ \Rightarrow m_{P_2O_5}=\dfrac{142.1}{15}=\dfrac{142}{15}\left(g\right)\\ b,n_{H_3PO_4}=\dfrac{2}{3}.0,2=\dfrac{2}{15}\left(mol\right)\\ \Rightarrow m_{H_3PO_4}=98.\dfrac{2}{15}=\dfrac{196}{15}\left(g\right)\)
a) P2O5 + 3H2O --> 2H3PO4
b) \(n_{H_2O}=\dfrac{45}{18}=2,5\left(mol\right)\)
\(n_{P_2O_5}=\dfrac{14,2}{142}=0,1\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{2,5}{3}>\dfrac{0,1}{1}\) => P2O5 hết, H2O dư
PTHH: P2O5 + 3H2O --> 2H3PO4
0,1---->0,3------>0,2
=> \(m_{H_2O\left(dư\right)}=\left(2,5-0,3\right).18=39,6\left(g\right)\)
c) \(m_{H_3PO_4}=0,2.98=19,6\left(g\right)\)
a) P2O5 + 3H2O --> 2H3PO4