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`n_(H_2)=V/(22,4)=(3,36)/(22,4)=0,15(mol)`
\(PTHH:2Al+3H_2SO_4->Al_2\left(SO_4\right)_3+3H_2\)
tỉ lệ 2 ; 3 ; 1 ; 3
n(mol) 0,1<-------------------------------------0,15
`m_(Al)=n*M=0,1*27=2,7(g)`
`=>B`
a. Aluminium + Khí oxygen -> Aluminium oxide
b. \(m_{Al}+m_O=m_{Al_{2_{ }}O_3}\)
c. Từ câu b => \(m_{Al}=m_{Al_{2_{ }}O_3}-m_O=20.4-9.6=10.8\)
Phương trình chữ:
aluminium + oxygen \(\rightarrow\) aluminium oxide
Biểu thức khối lượng:
\(m_{Al}+m_{O_2}=m_{Al_2O_3}\)
Khối lượng aluminium:
\(m_{Al}=m_{Al_2O_3}-m_{O_2}=20,4-9,6=10,8g\)
Ta có: \(n_{H_2}=\dfrac{74,37}{24,79}=3\left(mol\right)\)
PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
a, \(n_{Al}=\dfrac{2}{3}n_{H_2}=2\left(mol\right)\)
\(\Rightarrow m_{Al}=2.27=54\left(g\right)\)
b, \(n_{H_2SO_4}=n_{H_2}=3\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4}=3.98=294\left(g\right)\)
a. \(PTHH:2Al+3H_2SO_4--->Al_2\left(SO_4\right)_3+3H_2\)
b. Áp dụng định luật bảo toàn khối lượng, ta có:
\(m_{Al}+m_{H_2SO_4}=m_{Al_2\left(SO_4\right)_3}+m_{H_2}\)
\(\Leftrightarrow m_{Al_2\left(SO_4\right)_3}=m_{Al}+m_{H_2SO_4}-m_{H_2}=5,4+29,4-0,6=34,2\left(g\right)\)
\(n_{Al}=\dfrac{10.8}{27}=0.4\left(mol\right)\)
\(n_{H_2SO_4}=\dfrac{22.4}{98}=\dfrac{8}{35}\left(mol\right)\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(2............3\)
\(0.4..........\dfrac{8}{35}\)
\(LTL:\dfrac{0.4}{2}>\dfrac{\dfrac{8}{35}}{3}\Rightarrow Aldư\)
\(m_{Al\left(dư\right)}=\left(0.4-\dfrac{8}{35}\cdot\dfrac{2}{3}\right)\cdot27=6.68\left(g\right)\)
\(m_{Al_2\left(SO_4\right)_3}=\dfrac{8}{35\cdot3}\cdot342=26.05\left(g\right)\)
\(V_{H_2}=\dfrac{8}{35}\cdot22.4=5.12\left(l\right)\)
\(a,PTHH:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ \Rightarrow\text{Số nguyên tử Al là }2\\ b,n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\\ \Rightarrow n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{3}n_{H_2}=0,2\left(mol\right)\\ \Rightarrow m_{Al_2\left(SO_4\right)_3}=0,2\cdot342=68,4\left(g\right)\\ c,C_1:n_{H_2SO_4}=n_{H_2}=0,6\left(mol\right)\\ \Rightarrow m_{H_2SO_4}=0,6\cdot98=58,8\left(g\right)\\ C_2:n_{Al}=\dfrac{2}{3}n_{H_2}=0,4\left(mol\right)\\ \Rightarrow m_{Al}=0,4\cdot27=10,8\left(g\right)\\ m_{H_2}=0,6\cdot2=1,2\left(g\right)\\ \text{Bảo toàn KL: }m_{H_2SO_4}=m_{Al_2\left(SO_4\right)_3}+m_{H_2}-m_{Al}=68,4+1,2-10,8=58,8\left(g\right)\)
\(n_{Al}=\dfrac{2,7}{27}=0,1mol\\ a.2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
0,1 0,15 0,05 0,15
\(b.V_{H_2}=0,15.24,79=3,7185l\\ c.m_{Al_2\left(SO_4\right)_3}=0,05.342=17,1g\\ d.C_{M_{H_2SO_4}}=\dfrac{0,15}{0,4}=0,375M\)
2Al+3H2SO4->Al2(SO4)3+3H2
Áp dụng định luật bảo toàn khối lg:
m H2SO4=34,2+0,6-5,4
=29,4g
nAl = 5,4 : 27 = 0,2 (mol)
pthh : 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
0,2->0,3 (mol)
=> mH2SO4 = 0,3 .98 = 29,4 (g)