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![](https://rs.olm.vn/images/avt/0.png?1311)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
0,3 0,3 0,3 0,3
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
\(m_{Fe}=0,3.56=16,8\left(g\right)\)
\(C_{M_{H_2SO_4}}=\dfrac{n}{V}=\dfrac{0,3}{0,2}=1,5M\)
\(C_{M_{FeSO_4}}=\dfrac{n}{V}=\dfrac{0,3}{0,2}=1,5M\)
PTHH: Fe + H₂SO₄ --> FeSO₄ + H₂
200ml = 0,2 lít.
a) Số mol H₂: nH₂ = 6,72 ÷ 22,4 = 0,3 mol
Theo PTHH => Số mol Fe: nFe = 0,3 mol
=> Khối lượng Fe: mFe = 16,8g
b) Số mol H₂SO₄: nH₂SO₄ = 0,3 mol
Nồng độ mol dd: CM = 0,3 ÷ 0,2 = 1,5M
![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{CO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
dd A chứa 2 muối là \(\left\{{}\begin{matrix}Na_2CO_3:a\left(mol\right)\\NaHCO_3:b\left(mol\right)\end{matrix}\right.\)
nHCl = 0,3.1 = 0,3 (mol)
\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH: \(Na_2CO_3+HCl\rightarrow NaHCO_3+NaCl\)
a------->a-------->a
\(NaHCO_3+HCl\rightarrow NaCl+CO_2+H_2O\)
0,1<-----0,1<---------------0,1
=> a + 0,1 = 0,3
=> a = 0,2 (mol)
\(n_{NaHCO_3\left(B\right)}=a+b-0,1\left(mol\right)\)
\(n_{BaCO_3}=\dfrac{78,8}{197}=0,4\left(mol\right)\)
PTHH: Ba(OH)2 + 2NaHCO3 --> BaCO3 + Na2CO3 + 2H2O
(a+b-0,1)->(0,5a+0,5b-0,05)->(0,5a+0,5b-0,05)
Na2CO3 + Ba(OH)2 --> BaCO3 + 2NaOH
(0,5a+0,5b-0,05)----->(0,5a+0,5b-0,05)
=> \(n_{BaCO_3}=a+b-0,1=0,4\)
=> b = 0,3 (mol)
Bảo toàn Na: x + 2y = 2a + b = 0,7
Bảo toàn C: y + 0,3 = a + b = 0,5
=> x = 0,3 ; y = 0,2
![](https://rs.olm.vn/images/avt/0.png?1311)
a) \(\left\{{}\begin{matrix}n_{HCl}=0,5\\n_{H_2SO_4}=0,19\end{matrix}\right.\)
Gọi công thức chung của 2 axit là HX
=> nHX = 0,5 + 0,19.2 = 0,88 (mol)
\(n_{H_2}=\dfrac{8,736}{22,4}=0,39\left(mol\right)\)
Do nHX > 2.nH2 => axit còn dư sau pư
b) bài này s tính riêng đc mỗi muối :v
![](https://rs.olm.vn/images/avt/0.png?1311)
a) $Fe + 2HCl \to FeCl_2 + H_2$
b) $n_{HCl} = 0,2.0,3 = 0,06(mol)$
Theo PTHH :
$n_{Fe} = n_{H_2} = \dfrac{1}{2}n_{HCl} = 0,03(mol)$
Suy ra :
$m = 0,03.56 = 1,68(gam)$
$V = 0,03.22,4 = 0,672(lít)$
b) $n_{FeCl_2} = \dfrac{1}{2}n_{HCl} = 0,03$
$C_{M_{FeCl_2}} = \dfrac{0,03}{0,2} = 0,15M$
![](https://rs.olm.vn/images/avt/0.png?1311)
a)
\(\left\{{}\begin{matrix}n_{Na_2CO_3}=0,3.1,5=0,45\left(mol\right)\\n_{NaHCO_3}=1.0,3=0,3\left(mol\right)\end{matrix}\right.\)
PTHH: Na2CO3 + HCl --> NaCl + NaHCO3
0,45-->0,45-------------->0,45
NaHCO3 + HCl --> NaCl + CO2 + H2O
0,15<----0,15---------->0,15
=> VCO2 = 0,15.22,4 = 3,36 (l)
b)
nNaHCO3 = 0,6 (mol)
Bảo toàn C: nBaCO3 = 0,6 (mol)
=> mBaCO3 = 0,6.197 = 118,2 (g)
Câu 2
a)
\(m_{CuO\left(pư\right)}=10-6=4\left(g\right)\)
=> \(n_{CuO\left(pư\right)}=\dfrac{4}{80}=0,05\left(mol\right)\)
\(n_{H_2SO_4\left(bd\right)}=0,2.2=0,4\left(mol\right)\)
PTHH: CuO + H2SO4 --> CuSO4 + H2O
0,05--->0,05------->0,05
=> nH2SO4(pư) < nH2SO4(bd)
=> CuO tan hết
=> mCuO = 4 (g)
\(\%m_{CuO}=\dfrac{4}{10}.100\%=40\%\)
\(\%m_{Cu}=100\%-40\%=60\%\)
b) \(\left\{{}\begin{matrix}n_{CuSO_4}=0,05\left(mol\right)\\n_{H_2SO_4\left(dư\right)}=0,35\left(mol\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}C_{M\left(CuSO_4\right)}=\dfrac{0,05}{0,2}=0,25M\\C_{M\left(H_2SO_4.dư\right)}=\dfrac{0,35}{0,2}=1,75M\end{matrix}\right.\)
![](https://rs.olm.vn/images/avt/0.png?1311)
a, Ta có: \(n_{CO_2}=\dfrac{0,84}{22,4}=0,0375\left(mol\right)\)
PT: \(CO_2+2KOH\rightarrow K_2CO_3+H_2O\)
\(n_{K_2CO_3}=n_{CO_2}=0,0375\left(mol\right)\)
\(\Rightarrow m_{K_2CO_3}=0,0375.138=5,175\left(g\right)\)
b, \(n_{KOH}=2n_{CO_2}=0,075\left(mol\right)\)
\(\Rightarrow C_{M_{KOH}}=\dfrac{0,075}{0,2}=0,375\left(M\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
Dung dịch A chứa CO32- (x mol) và HCO3- (y mol)
CO32- + H+ —> HCO3-
x…………x………….x
HCO3- + H+ —> CO2 + H2O
x+y…….0,15-x
Dung dịch B tạo kết tủa với Ba(OH)2 nên HCO3- dư, vậy nCO2 = 0,15 – x = 0,045 —> x = 0,105
HCO3- + OH- + Ba2+ —> BaCO3 + H2O
—> nBaCO3 = (x + y) – (0,15 – x) = 0,15 —> y = 0,09
—> a = 20,13 gam
![](https://rs.olm.vn/images/avt/0.png?1311)
TN1:
\(C_{M\left(E\right)}=\dfrac{2x+y}{3}M\)
10ml dd E chứa \(0,01.\dfrac{2x+y}{3}\) mol H2SO4
\(n_{H_2}=\dfrac{0,05824}{22,4}=0,0026\left(mol\right)\)
PTHH: Zn + H2SO4 --> ZnSO4 + H2
=> 2x + y = 0,78 (1)
TN2:
\(C_{M\left(F\right)}=\dfrac{x+3y}{4}M\)
50ml dd F chứa \(0,05\dfrac{x+3y}{4}\) mol H2SO4
\(n_{NaOH}=\dfrac{16,8.5\%}{40}=0,021\left(mol\right)\)
PTHH: 2NaOH + H2SO4 --> Na2SO4 + 2H2O
=> x + 3y = 0,84 (2)
(1)(2) => x = 0,3; y = 0,18
\(1.3NaOH+H_3PO_4\rightarrow Na_3PO_4+3H_2O\\ a=n_{H_3PO_4}=\dfrac{1}{3}n_{NaOH}=\dfrac{1}{3}\cdot0,9=0,3mol\\ \Rightarrow A\\ 2.n_{Ba\left(OH\right)_2}=0,2.0,4=0,08mol\\ n_{H_2SO_4}=0,25.0,3=0,075mol\\ Ba\left(OH\right)_2+H_2SO_4\rightarrow BaSO_4+2H_2O\\ \Rightarrow\dfrac{0,08}{1}>\dfrac{0,075}{1}\Rightarrow Ba\left(OH\right)_2.dư\\ n_{BaSO_4}=n_{H_2SO_4}=0,075mol\\ m_{\uparrow}=m_{BaSO_4}=0,075.233=16,725g\\ \Rightarrow?:))\\ 3.n_{KOH}=0,2.1=0,2mol\\ n_{H_2SO_4}=0,2.1=0,2mol\\ 2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\\ \Rightarrow\dfrac{0,2}{2}< \dfrac{0,2}{1}\Rightarrow H_2SO_4.dư\\ n_{H_2SO_4.pư}=\dfrac{1}{2}n_{KOH}=\dfrac{1}{2}\cdot0,2=0,1mol\\ n_{H_2SO_4_4.dư}=0,2-0,1mol\\ H_2SO_4+Mg\rightarrow MgSO_4+H_2\\ n_{H_2}=n_{H_2SO_4.dư}=0,1mol\\ V_{H_2}=0,1.24,79=2,479l\\ \Rightarrow A\)