Đốt cháy 1,4g sắt trong khí oxi thu được oxit sắt từ Fe3O4.
a/ Viết phương trình hóa học.
b/ Tính thể tích khí oxi đã tham gia phản ứng (ở đktc).
c/ Hãy tính khối lượng oxit sắt từ Fe3O4 thu được theo hai cách
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nFe = 33,6 : 56 = 0,6 (mol)
pthh : 3Fe + 2O2 -t--> Fe3O4
0,6--> 0,4------->0,2 (mol)
=> vO2 = 0,4.22,4 = 8,96 (mol)
=> mFe3O4 = 0,2.232 = 46,4 (g)
pthh : 2KClO3 -t--> 2KClO3 + 3O2
0,267<-----------------------0,4(mol)
mKClO3= 0,267 .122,5 = 32,67 (g)
a, \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b, Ta có: \(n_{Fe}=\dfrac{50,4}{56}=0,9\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=0,6\left(mol\right)\Rightarrow V_{O_2}=0,6.22,4=13,44\left(l\right)\)
c, \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,3\left(mol\right)\Rightarrow m_{Fe_3O_4}=0,3.232=69,6\left(g\right)\)
d, \(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
Theo PT: \(n_{KClO_3}=\dfrac{2}{3}n_{O_2}=0,4\left(mol\right)\Rightarrow m_{KClO_3}=0,4.122,5=49\left(g\right)\)
\(n_{Fe}=\dfrac{m}{M}=\dfrac{50,4}{56}=0,9\left(mol\right)\)
\(a.PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
3 2 1
0,9 0,6 0,3
\(b.V_{O_2}=n.24,79=0,6.24,79=14,874\left(l\right)\)
\(c.m_{Fe_3O_4}=n.M=0,3.\left(56.3+16.4\right)=69,6\left(g\right)\)
\(d.V_{O_2}=14,874\left(l\right)\\ \Rightarrow n_{O_2}=\dfrac{V}{24,79}=\dfrac{14,874}{24,79}=0,6\left(mol\right)\\ PTHH:2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
2 2 3
0,6 0,6 0,9
\(m_{KClO_3}=n.M=0,6.\left(39+35,5+16.3\right)=55,5\left(g\right).\)
a, \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b, \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=0,2\left(mol\right)\Rightarrow V_{O_2}=0,2.22,4=4,48\left(l\right)\)
\(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,1\left(mol\right)\Rightarrow m_{Fe_3O_4}=0,1.232=23,2\left(g\right)\)
c, \(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)
PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,3}{1}\), ta được H2 dư.
Theo PT: \(n_{Cu}=n_{CuO}=0,2\left(mol\right)\Rightarrow m_{Cu}=0,2.64=12,8\left(g\right)\)
a. \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
PTHH : 3Fe + 2O2 -to> Fe3O4
0,3 0,2 0,1
b. \(m_{Fe_3O_4}=0,1.232=23,2\left(g\right)\)
c. \(V_{O_2}=0,2.22,4=4,48\left(l\right)\)
a \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b \(\Rightarrow n_{Fe}=\dfrac{16,8}{56}=0,3mol\) \(\Rightarrow n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,1mol\Rightarrow m_{Fe_3O_4}=0,1\cdot232=2,32g\)
c \(\Rightarrow n_{O_2}=\dfrac{2}{3}n_{Fe}=0,2mol\Rightarrow V_{O_2}=0,2\cdot22,4=4,48l\)
\(n_{Fe}=\dfrac{6,8}{56}=0,12mol\)
3Fe + 2O2 \(\underrightarrow{t^o}\) Fe3O4
0,12 0,08 0,04 ( mol )
a, \(V_{O_2}=0,08.22,4=1,792l\)
b, mFe3O4 = 0,04.232 = 9,28g
\(n_{Fe}=\dfrac{6,8}{56}=\dfrac{17}{140}(mol)\\ PTHH:3Fe+2O_2\xrightarrow{t^o}Fe_3O_4\\ a,n_{O_2}=\dfrac{2}{3}n_{Fe}=\dfrac{17}{210}(mol)\\ \Rightarrow V_{O_2}=\dfrac{17}{210}.22,4=1,81(g)\\ b,n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=\dfrac{17}{420}(mol)\\ \Rightarrow m_{Fe_3O_4}=\dfrac{17}{420}.232=9,39(g)\)
\(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)
\(PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\\ Mol:0,4\rightarrow\dfrac{4}{15}\rightarrow\dfrac{2}{15}\)
\(\rightarrow\left\{{}\begin{matrix}V_{O_2}=\dfrac{4}{15}.22,4=\dfrac{448}{75}\left(l\right)\rightarrow V_{kk}=\dfrac{448}{75}.5=\dfrac{448}{15}\left(l\right)\\m_{Fe_3O_4}=\dfrac{2}{15}.232=\dfrac{464}{15}\left(g\right)\end{matrix}\right.\)
2KClO3 --to--> 2KCl + 3O2
\(\dfrac{8}{45}\) \(\dfrac{4}{15}\)
\(m_{KClO_3}=\dfrac{8}{45}.122,5=\dfrac{196}{9}\left(g\right)\)
a, \(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)
PTHH: 3Fe + 2O2 ---to---> Fe3O4
Mol: 0,4 \(\dfrac{0,8}{3}\) \(\dfrac{0,4}{3}\)
b, \(V_{O_2}=\dfrac{0,8}{3}.22,4=5,973\left(l\right)\)
c, \(V_{kk}=\dfrac{448}{75}.5=29,867\left(l\right)\)
d, \(m_{Fe_3O_4}=\dfrac{0,4}{3}.232=30,93\left(g\right)\)
e,
PTHH: 2KClO3 ---to---> 2KCl + 3O2
Mol: \(\dfrac{0,16}{9}\) \(\dfrac{0,8}{3}\)
\(m_{KClO_3}=\dfrac{0,16}{9}.122,5=2,178\left(g\right)\)
gọi số mol Fe là x
pthh : 3Fe + 2O2 --t---> Fe3O4
x---->\(\dfrac{2}{3}\)x----------> \(\dfrac{x}{3}\)
=> mFe3O4= \(\dfrac{x}{3}\) . 232 = \(\dfrac{232x}{3}\) (G)
=> VO2 = \(\dfrac{2x}{3}\) . 22,4 = \(\dfrac{224x}{15}\) (L)
a) \(n_{Fe}=\dfrac{3,36}{56}=0,06\left(mol\right)\)
PTHH: 3Fe + 2O2 --to--> Fe3O4
0,06->0,04------->0,02
=> mFe3O4 = 0,02.232 = 4,64 (g)
b) VO2 = 0,04.22,4 = 0,896 (l)
\(a/3Fe+2O_2\xrightarrow[]{t^0}Fe_3O_4\\ b/n_{Fe}=\dfrac{1,4}{56}=0,025mol\\ n_{O_2}=\dfrac{0,025.2}{3}=\dfrac{0,05}{3}mol\\ V_{O_2}=\dfrac{0,05}{3}\cdot22,4\approx0,37l\\ c/C_1\\ n_{Fe_3O_4}=\dfrac{0,025}{3}mol\\ m_{Fe_3O_4}=\dfrac{0,025}{3}\cdot232\approx1,93g\\ C_2\\ m_{O_2}=\dfrac{0,05}{3}\cdot32\approx0,53g\\ BTKL:m_{Fe}+m_{O_2}=m_{Fe_3O_4}\\ \Rightarrow m_{Fe_3O_4}=1,4+0,53=1,93g\)