Cho 8,9 g hỗn hợp 2 kim loại Zn và Mg tác dụng với 200 l dung dịch HCl 1M và H2SO4 1M thu được 4,48 lít H2 (đktc). Tính % khối lượng mỗi kim loại
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Đặt \(\left\{{}\begin{matrix}n_{Zn}=x\left(mol\right)\\n_{Mg}=y\left(mol\right)\end{matrix}\right.\Rightarrow65x+24y=8,9\left(1\right)\)
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ \Rightarrow x+y=0,2\left(2\right)\\ \left(1\right)\left(2\right)\Rightarrow\left\{{}\begin{matrix}65x+24y=8,9\\x+y=0,2\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,1\left(mol\right)\\y=0,1\left(mol\right)\end{matrix}\right.\\ \Rightarrow\%_{Zn}=\dfrac{0,1\cdot65}{8,9}\cdot100\%\approx73\%\\ \Rightarrow\%_{Mg}=100\%-73\%=27\%\)
\(n_{HCl}=2x+2y=0,4\left(mol\right)\\ \Rightarrow m_{CT_{HCl}}=0,4\cdot36,5=14,6\left(g\right)\\ \Rightarrow m_{dd_{HCl}}=\dfrac{14,6\cdot100\%}{14,6\%}=100\left(g\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{Mg}=a;n_{Fe}=0,5a;n_{Zn}=b\\ a\left(24+28\right)+65b=52a+65b=44,2\\ 1,5a+b=\dfrac{24,64}{22,4}1,1\\ a=0,6;b=0,2\\ \%m_{Mg}=\dfrac{24a}{44,2}=32,58\%\\ \%m_{Fe}=\dfrac{28a}{44,2}=38\%\\ \%m_{Zn}=29,42\%\\ m_{ddacid}=\dfrac{98\left(1,5a+b\right)}{0,08}=1347,5g\\ m_{ddsau}=1389,5g\\ C\%_{MgCl_2}=\dfrac{95a}{1389,5}=4,10\%\\ C\%_{FeCl_2}=\dfrac{127.0,5a}{1389,5}=2,74\%\\ C\%_{ZnCl_2}=\dfrac{136b}{1389,5}=1,96\%\)
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\(a)n_{H_2}=\dfrac{7,55}{22,4}=\dfrac{151}{448}mol\\ n_{Mg}=n_{Zn}=a;n_{Fe}=c\\ Mg+H_2SO_4\rightarrow MgSO_4+H_2\\ a.....a\\ Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\ a.....a\\ Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ b.....b\\ \Rightarrow\left\{{}\begin{matrix}24a+65a+56b=16\\2a+b=\dfrac{151}{448}\end{matrix}\right.\\ \Rightarrow a=0,125;b=\dfrac{39}{448}\\ \%m_{Mg}=\dfrac{24.0,125}{16}\cdot100=18,75\%\\ \%m_{Zn}=\dfrac{65.0,125}{16}\cdot100=50,78\%\\ \%m_{Fe}=100-18,75-50,78=30,47\%\\ b)V_{ddH_2SO_4}=\dfrac{0,125.2+\dfrac{39}{448}}{1}\approx0,337l\)
![](https://rs.olm.vn/images/avt/0.png?1311)
Bài 4:
a) nH2= 6,72/22,4= 0,3(mol)
Đặt:nMg= x(mol); nZn=y(mol) (x,y>0)
PTHH: Mg + 2 HCl -> MgCl2 + H2
x_______2x________x_____x(mol)
Zn + 2 HCl -> ZnCl2 + H2
y____2y____y________y(mol)
Ta có hpt:
\(\left\{{}\begin{matrix}24x+65y=15,4\\x+y=0,3\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)
mMg=0,1.24=2,4(g)
=>%mMg = (2,4/15,4).100=15,584%
=>%mZn= 84,416%
b) nHCl(tổng)= 0,6(mol)
=> VddHCl=0,6/1=0,6(l)
Chúc em học tốt!
![](https://rs.olm.vn/images/avt/0.png?1311)
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Theo PT: \(n_{Zn}=n_{H_2}=0,2\left(mol\right)\)
⇒ mZn = 0,2.65 = 13 (g)
⇒ mCu = 19,4 - 13 = 6,4 (g)
Bạn tham khảo nhé!
![](https://rs.olm.vn/images/avt/0.png?1311)
a, \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH: Zn + 2HCl → ZnCl2 + H2
Mol: 0,2 0,2
(do Cu ko tác dụng với HCl loãng)
b, \(m_{Zn}=0,2.65=13\left(g\right)\)
\(m_{Cu}=19,4-13=6,4\left(g\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
Gọi số mol Al, Fe là a, b (mol)
=> 27a + 56b = 11,1 (1)
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
a----------------------->1,5a
Fe + 2HCl --> FeCl2 + H2
b------------------------>b
=> 1,5a + b = 0,3 (2)
(1)(2) => a = 0,1; b = 0,15
=> \(\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,1.27}{11,1}.100\%=24,32\%\\\%m_{Fe}=\dfrac{0,15.56}{11,1}.100\%=75,68\end{matrix}\right.\)
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\)
\(n_{HCl}=0,2mol\)
\(n_{H_2SO_4}=0,2mol\)
\(n_{H\left(axit\right)}=n_{HCl}+2n_{H_2SO_4}=0,2+0,2.2=0,6mol\)
\(\rightarrow\)\(n_{H\left(axit\right)}=0,6>2n_{H_2}=0,4\rightarrow\)axit dư
\(n_{Zn}=x;n_{Mg}=y\)
Ta có hệ: \(\left\{{}\begin{matrix}65x+24y=8,9\\x+y=0,2\end{matrix}\right.\)
Giải ra x=y=0,1
%Zn=\(\dfrac{65.0,1.100}{8,9}\approx73\%\)
%Mg=27%