Hòa tan 8,1 gam Al vào 100 gam H2SO4 73,5%. Tính nồng độ phần trăm của muối thu được.
A. 47,85%
B. 45,67%.
C. 43,57%
D. 44,95%.
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a, \(C\%_{KCl}=\dfrac{20}{20+60}.100\%=25\%\)
b, \(C\%=\dfrac{40}{40+150}.100\%\approx21,05\%\)
c, \(C\%_{NaOH}=\dfrac{60}{60+240}.100\%=20\%\)
d, \(C\%_{NaNO_3}=\dfrac{30}{30+90}.100\%=25\%\)
e, \(m_{NaCl}=150.60\%=90\left(g\right)\)
f, \(m_{ddA}=\dfrac{25}{10\%}=250\left(g\right)\)
g, \(n_{NaOH}=120.20\%=24\left(g\right)\)
Gọi: nNaOH (thêm vào) = a (g)
\(\Rightarrow\dfrac{a+24}{a+120}.100\%=25\%\Rightarrow a=8\left(g\right)\)
a, \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
b, Ta có: \(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=\dfrac{4}{15}\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{\dfrac{4}{15}.27}{10}.100\%=72\%\\\%m_{Cu}=28\%\end{matrix}\right.\)
c, Theo PT: \(n_{H_2SO_4}=n_{H_2}=0,4\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4}=0,4.98=39,2\left(g\right)\)
\(\Rightarrow C\%_{H_2SO_4}=\dfrac{39,2}{300}.100\%\approx13,067\%\)
\(n_{Al}=\dfrac{0,54}{27}=0,02\left(mol\right)\\ m_{H_2SO_4}=9,8\%.40=3,92\left(g\right)\\ n_{H_2SO_4}=\dfrac{3,92}{98}=0,04\left(mol\right)\)
PTHH: 2Al + 3H2SO4 ---> Al2(SO4)3 + 3H2
LTL: \(\dfrac{0,02}{2}< \dfrac{0,04}{3}\rightarrow\)H2SO4 dư
Theo pt: \(\left\{{}\begin{matrix}n_{H_2SO_4\left(pư\right)}=n_{H_2}=\dfrac{3}{2}n_{Al}=\dfrac{3}{2}.0,02=0,03\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=\dfrac{1}{2}.0,02=0,01\left(mol\right)\end{matrix}\right.\)
\(\rightarrow V_{H_2}=0,03.22,4=0,672\left(l\right)\\ m_{dd}=0,54+40=40,54\left(g\right)\\ \rightarrow\left\{{}\begin{matrix}C\%_{Al_2\left(SO_4\right)_3}=\dfrac{342.0,01}{40,54}=8,43\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{\left(0,04-0,03\right).98}{40,54}=2,41\%\end{matrix}\right.\)
\(n_{CuO}=\dfrac{1,6}{80}=0,02\left(mol\right)\)
Pt : \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O|\)
1 1 1 1
0,02 0,02
\(n_{CuSO4}=\dfrac{0,02.1}{1}=0,02\left(mol\right)\)
⇒ \(m_{CuSO4}=0,02,160=3,2\left(g\right)\)
\(m_{ddspu}=1,6+300=301,6\left(g\right)\)
\(C_{CuSO4}=\dfrac{3,2.100}{301,6}=1,6\)0/0
Chúc bạn học tốt
a) $2Al + 6HCl \to 2AlCl_3 + 3H_2$
b) n Al = 8,1/27 = 0,3(mol)
Theo PTHH :
n H2 = 3/2 n Al = 0,45(mol)
V H2 = 0,45.22,4 = 10,08(lít)
c) n AlCl3 = n Al = 0,3(mol)
m AlCl3 = 0,3.133,5 = 40,05(gam)
d) n HCl = 3n Al = 0,9(mol)
m dd HCl = 0,9.36,5/7,3% = 450(gam)
Sau phản ứng :
m dd = 8,1 + 450 -0,45.2 = 457,2(gam)
C% AlCl3 = 40,05/457,2 .100% = 8,76%
Khối lượng dung dịch:
\(m_{dd}=16+40=56g\)
\(\%m_{CuSO_4}=\dfrac{m_{ct}}{m_{dd}}\cdot100\%=\dfrac{16}{16+40}\cdot100\%=28,57\%\)
\(n_{Al}=0,3\left(mol\right);n_{H_2SO_4}=0,75\left(mol\right)\)
Dễ thấy \(H_2SO_4\) dư \(\Rightarrow n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=0,15\left(mol\right);n_{H_2}=0,45\left(mol\right)\)
\(m_{\text{dd sau pư}}=100+8,1-0,45.2=107,2\left(g\right)\)
\(\Rightarrow C\%=\dfrac{0,15.342}{107,2}.100\%=47,85\%\)
Cái này đúng ra là \(C\%=47,85447761\%\approx47,86\%\)
A