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\(a,C\%_A=\dfrac{12,5}{12,5+87,5}.100\%=12,5\%\)
\(b,PTHH:\)
\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2\downarrow+Na_2SO_4\)
trc p/u : 0,05 0,15
p/u : 0,05 0,1 0,05 0,05
sau: 0 0,05 0,05 0,05 (mol)
-> sau p/ư NaOH dư .
\(n_{NaOH}=\dfrac{40.15\%}{40}=0,15\left(mol\right)\)
\(n_{CuSO_4}=\dfrac{12,5}{250}=0,05\left(mol\right)\)
\(m_{Cu\left(OH\right)_2}=0,05.98=4,9\left(g\right)\)
\(m_{ddB}=100+40=140\left(g\right)\)
\(C\%_B=\dfrac{4,9}{140}.100\%=3,5\%\)
\(n_{Na_2O}=\dfrac{15,5}{62}=0,25\left(mol\right)\\ PTHH:Na_2O+H_2O\rightarrow2NaOH\\ n_{NaOH}=2.0,25=0,5\left(mol\right)\\ a,C_{MddNaOH}=\dfrac{0,5}{0,5}=1\left(M\right)\\ b,2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\\ n_{H_2SO_4}=n_{Na_2SO_4}=\dfrac{0,5}{2}=0,25\left(mol\right)\\ m_{H_2SO_4}=0,25.98=24,5\left(g\right)\\ m_{ddH_2SO_4}=\dfrac{24,5.100}{20}=122,5\left(g\right)\\ V_{ddH_2SO_4}=\dfrac{122,5}{1,14}\approx107,456\left(ml\right)\\ c,V_{ddsau}=V_{ddNaOH}+V_{ddH_2SO_4}\approx0,5+0,107456=0,607456\left(l\right)\\C_{MddNa_2SO_4}\approx\dfrac{ 0,25}{0,607456}\approx0,411552\left(M\right)\)
Ta có: \(n_{HCl}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\) \(\Rightarrow C_{M_{HCl}}=\dfrac{0,25}{0,1}=2,5\left(M\right)\)
mH2O = 0,1 (kg) = 100 (g)
mHCl = 0,25.36,5 = 9,125 (g)
\(\Rightarrow C\%_{HCl}=\dfrac{9,125}{9,125+100}.100\%\approx8,36\%\)
1)
$n_{Na_2O} = \dfrac{6,2}{62} = 0,1(mol)$
$Na_2O + H_2O \to 2NaOH$
$n_{NaOH} = 2n_{Na_2O} = 0,2(mol)$
$m_{dd} = 6,2 + 193,8 = 200(gam) \Rightarrow C\%_{NaOH} = \dfrac{0,2.40}{200}.100\% = 4\%$
2)
$n_{K_2O} = \dfrac{23,5}{94} = 0,25(mol)$
$K_2O + H_2O \to 2KOH$
$n_{KOH} = 2n_{K_2O} = 0,5(mol) \Rightarrow C_{M_{KOH}} = \dfrac{0,5}{0,5} = 1M$
3) $n_{Na_2O} = \dfrac{12,4}{62} = 0,2(mol)$
$Na_2O + H_2O \to 2NaOH$
$n_{NaOH} = 2n_{Na_2O} = 0,4(mol)$
$C_{M_{NaOH}} = \dfrac{0,4}{0,5} =0,8M$
4)
$Na_2SO_3 + 2HCl \to 2NaCl +S O_2 + H_2O$
Theo PTHH :
$n_{SO_2} = n_{Na_2SO_3} = \dfrac{12,6}{126} = 0,1(mol)$
$V_{SO_2} = 0,1.22,4 = 2,24(lít)$
5) $n_{CaO} = \dfrac{5,6}{56} = 0,1(mol)$
$CaO + 2HCl \to CaCl_2 + H_2O$
Theo PTHH :
$n_{HCl} = 2n_{CaO} = 0,2(mol) \Rightarrow m_{dd\ HCl} = \dfrac{0,2.36,5}{14,6\%} = 50(gam)$
Bài1:
a,Vì dd A là dd bazo nên làm cho quỳ tím đổi thành màu xanh
b,\(n_{Na_2O}=\dfrac{21,7}{62}=0,35\left(mol\right)\)
PTHH: Na2O + H2O → 2NaOH
Mol: 0,35 0,7
\(\Rightarrow C_{M_{ddNaOH}}=\dfrac{0,7}{0,4}=1,75M\)
Bài 2:
a,\(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: Zn + 2HCl → ZnCl2 + H2
Mol: 0,15 0,3 0,15
⇒ a=mZn = 0,15.65 = 9,75 (g)
b,\(V_{HCl}=\dfrac{0,3}{1,5}=0,2\left(l\right)=200\left(ml\right)\)
\(n_{CuSO_4.5H_2O}=n_{CuSO_4}=\dfrac{12,5}{250}=0,05mol\)
\(\Rightarrow C_{MddCuSO_4}=\dfrac{0,05}{0,0875}\approx0,57M\)
Đổi:87,5 ml=0,0875 l
nCuSO4=12,5/250=0,05(mol)
=>CM=0,05/0,0875=0,57 M.